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Volumn 5, Issue 1, 2004, Pages 111-116

The metastability of an electrochemically controlled nanoscale machine on gold surfaces

Author keywords

Electrochemistry; Kinetics; Metastable states; Molecular switches; Self assembled monolayers; Surfaces

Indexed keywords

ELECTROCHEMISTRY; ENZYME KINETICS; SELF ASSEMBLED MONOLAYERS; SOLID STATE DEVICES; SURFACES;

EID: 1642314562     PISSN: 14394235     EISSN: None     Source Type: Journal    
DOI: 10.1002/cphc.200300992     Document Type: Article
Times cited : (193)

References (76)
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    • a) In solution, the metastability of a bistable [2]catenane has been reported. See: M. Asakawa, P. R. Ashton, V. Balzani, A. Credi, C. Hamers, G. Mattersteig, M. Montalti, A. N. Shipway, N. Spencer, J. F. Stoddart, M. S. Tolley, M. Venturi, A. J. P. White, D. J. Williams, Angew. Chem. 1998, 110, 357-361; Angew. Chem. Int. Ed. 1998, 37, 333-337;
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    • note
    • 1H NMR timescale at room temperature and so only averaged signal information is available. At low temperature, where the isomerism becomes "frozen out", it would appear that the major translational isomer is overwhelmingly preferred at equilibrium and so no evidence for the minor isomer can be found.
  • 67
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    • note
    • 4+ ring following the oxidation of the TTF unit.
  • 69
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    • note
    • 2.
  • 73
    • 2442564750 scopus 로고    scopus 로고
    • note
    • 0 is the equilibrium population (10%) of the ground state at the beginning of the experiment.
  • 74
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    • note
    • BT).
  • 75
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    • note
    • 4+ confined on a gold surface.
  • 76
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    • note
    • -1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.