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4+ and its corresponding dumbbell are reported in the Supporting Information.
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[16] we employed the term "co-conformer" to the two states. See, especially Figure 1 in reference [16]. In other words, in proposing our original mechanism, we appreciated correctly that the ON and OFF states are both isomeric and, of course, isoelectronic.
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SAMs of copper catenates have been prepared; however, the electrochemically-triggered circumrotations are either significantly slower than the corresponding motions in solution or completely frozen out; see: L. Raehm, J.-M. Kern, J.-P. Sauvage, C. Hamann, S. Palacin, J.-P. Bourgoin, Chem. Eur. J. 2002, 8, 2153-2162.
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Electrochromic devices have been developed out of a variety of different materials; for examples of molecular systems, see: R. J. Mortimer, Electrochim. Acta 1999, 44, 2971-2981, and, for an example in which an electrochromic molecule that has been attached to a solid support, see: R. Cinnsealach, G. Boschloo, S. Nagaraja Rao, D. Fitzmaurice, Sol. Energy Mater. Sol. Cells 1999, 57, 107-125; for examples of polymers, see: F. Fungo, S. A. Jenekhe, A. J. Bard, Chem. Mater. 2003, 15, 1264-1272, and, for a very recent report on polymeric systems, see: G. Sonmez, C. K. F. Shen, Y. Rubin, F. Wudl, Angew. Chem. 2004, 116, 1524-1528; Angew. Chem. Int. Ed. 2004, 43, 1498-1502; for examples of metal-oxide thin films, see: S. Papaefthimiou, G. Leftheriotis, P. Yianoulis, Electrochim. Acta 2001, 46, 2145-2150;
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Cinnsealach, R.1
Boschloo, G.2
Nagaraja Rao, S.3
Fitzmaurice, D.4
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Electrochromic devices have been developed out of a variety of different materials; for examples of molecular systems, see: R. J. Mortimer, Electrochim. Acta 1999, 44, 2971-2981, and, for an example in which an electrochromic molecule that has been attached to a solid support, see: R. Cinnsealach, G. Boschloo, S. Nagaraja Rao, D. Fitzmaurice, Sol. Energy Mater. Sol. Cells 1999, 57, 107-125; for examples of polymers, see: F. Fungo, S. A. Jenekhe, A. J. Bard, Chem. Mater. 2003, 15, 1264-1272, and, for a very recent report on polymeric systems, see: G. Sonmez, C. K. F. Shen, Y. Rubin, F. Wudl, Angew. Chem. 2004, 116, 1524-1528; Angew. Chem. Int. Ed. 2004, 43, 1498-1502; for examples of metal-oxide thin films, see: S. Papaefthimiou, G. Leftheriotis, P. Yianoulis, Electrochim. Acta 2001, 46, 2145-2150;
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Chem. Mater.
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Fungo, F.1
Jenekhe, S.A.2
Bard, A.J.3
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Electrochromic devices have been developed out of a variety of different materials; for examples of molecular systems, see: R. J. Mortimer, Electrochim. Acta 1999, 44, 2971-2981, and, for an example in which an electrochromic molecule that has been attached to a solid support, see: R. Cinnsealach, G. Boschloo, S. Nagaraja Rao, D. Fitzmaurice, Sol. Energy Mater. Sol. Cells 1999, 57, 107-125; for examples of polymers, see: F. Fungo, S. A. Jenekhe, A. J. Bard, Chem. Mater. 2003, 15, 1264-1272, and, for a very recent report on polymeric systems, see: G. Sonmez, C. K. F. Shen, Y. Rubin, F. Wudl, Angew. Chem. 2004, 116, 1524-1528; Angew. Chem. Int. Ed. 2004, 43, 1498-1502; for examples of metal-oxide thin films, see: S. Papaefthimiou, G. Leftheriotis, P. Yianoulis, Electrochim. Acta 2001, 46, 2145-2150;
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Angew. Chem.
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Sonmez, G.1
Shen, C.K.F.2
Rubin, Y.3
Wudl, F.4
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53
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Electrochromic devices have been developed out of a variety of different materials; for examples of molecular systems, see: R. J. Mortimer, Electrochim. Acta 1999, 44, 2971-2981, and, for an example in which an electrochromic molecule that has been attached to a solid support, see: R. Cinnsealach, G. Boschloo, S. Nagaraja Rao, D. Fitzmaurice, Sol. Energy Mater. Sol. Cells 1999, 57, 107-125; for examples of polymers, see: F. Fungo, S. A. Jenekhe, A. J. Bard, Chem. Mater. 2003, 15, 1264-1272, and, for a very recent report on polymeric systems, see: G. Sonmez, C. K. F. Shen, Y. Rubin, F. Wudl, Angew. Chem. 2004, 116, 1524-1528; Angew. Chem. Int. Ed. 2004, 43, 1498-1502; for examples of metal-oxide thin films, see: S. Papaefthimiou, G. Leftheriotis, P. Yianoulis, Electrochim. Acta 2001, 46, 2145-2150;
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Angew. Chem. Int. Ed.
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, pp. 1498-1502
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54
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Electrochromic devices have been developed out of a variety of different materials; for examples of molecular systems, see: R. J. Mortimer, Electrochim. Acta 1999, 44, 2971-2981, and, for an example in which an electrochromic molecule that has been attached to a solid support, see: R. Cinnsealach, G. Boschloo, S. Nagaraja Rao, D. Fitzmaurice, Sol. Energy Mater. Sol. Cells 1999, 57, 107-125; for examples of polymers, see: F. Fungo, S. A. Jenekhe, A. J. Bard, Chem. Mater. 2003, 15, 1264-1272, and, for a very recent report on polymeric systems, see: G. Sonmez, C. K. F. Shen, Y. Rubin, F. Wudl, Angew. Chem. 2004, 116, 1524-1528; Angew. Chem. Int. Ed. 2004, 43, 1498-1502; for examples of metal-oxide thin films, see: S. Papaefthimiou, G. Leftheriotis, P. Yianoulis, Electrochim. Acta 2001, 46, 2145-2150;
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for the use of polymer-gel electrolytes in electrochromic devices, see: J. Vondrák, M. Sedlarikova, J. Reiter, T. Hodal, Electrochim. Acta 1999, 44, 3067-3073.
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