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Volumn 130, Issue 46, 2008, Pages 15448-15459

Defining the electronic and geometric structure of one-electron oxidized copper-bis-phenoxide complexes

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CHEMICAL OXYGEN DEMAND; COORDINATION REACTIONS; COPPER; COPPER COMPOUNDS; CRYSTALLOGRAPHY; CYCLOHEXANE; DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; FULLERENES; LIGANDS; MAGNETIC PROPERTIES; MAGNETIC SUSCEPTIBILITY; NANOSTRUCTURES; NICKEL ALLOYS; NITROGEN COMPOUNDS; OXIDATION; SOLID SOLUTIONS; SPIN DYNAMICS; X RAY CRYSTALLOGRAPHY; X RAY SPECTROSCOPY;

EID: 84961979073     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja804339m     Document Type: Article
Times cited : (163)

References (151)
  • 84
    • 0037118880 scopus 로고    scopus 로고
    • Ribas, X.; Jackson, D. A.; Donnadieu, B.; Mahia, J.; Parella, Xifra, R; Hedman, B; Hodgson, K. O.; Llobet, A; Stack, T. D. P. Angew. Chem., Int. Ed. 2002, 41, 2991.
    • (d) Ribas, X.; Jackson, D. A.; Donnadieu, B.; Mahia, J.; Parella, Xifra, R; Hedman, B; Hodgson, K. O.; Llobet, A; Stack, T. D. P. Angew. Chem., Int. Ed. 2002, 41, 2991.
  • 87
    • 53849146749 scopus 로고    scopus 로고
    • Company, A.; Palavicini, S.; Garcia-Bosch, I.; Mas-Balleste, R.; Que, L.; Rybak-Akimova, E. V.; Casella, L.; Ribas, X.; Costas, M. Chem. Eur. J. 2008, 14, 3535.
    • (b) Company, A.; Palavicini, S.; Garcia-Bosch, I.; Mas-Balleste, R.; Que, L.; Rybak-Akimova, E. V.; Casella, L.; Ribas, X.; Costas, M. Chem. Eur. J. 2008, 14, 3535.
  • 100
    • 84962389674 scopus 로고    scopus 로고
    • The net polarization of the ligand and the metal is ca. 5-10% of the net charge transfer in all ECDA analyses in these complexes, and thus the contribution of polarization of the L→Cu and Cu→L as quantified here is ignored.
    • The net polarization of the ligand and the metal is ca. 5-10% of the net charge transfer in all ECDA analyses in these complexes, and thus the contribution of polarization of the L→Cu and Cu→L as quantified here is ignored.
  • 103
    • 84962357369 scopus 로고    scopus 로고
    • See Supporting Information
    • See Supporting Information.
  • 104
    • 84962357385 scopus 로고    scopus 로고
    • EXAFS analysis typically cannot distinguish between atoms that differ in Z by 1 (e.g., O and N). Scott, R. A. Methods Enzymol. 1985, 117, 414.
    • EXAFS analysis typically cannot distinguish between atoms that differ in Z by 1 (e.g., O and N). Scott, R. A. Methods Enzymol. 1985, 117, 414.
  • 113
    • 14944352006 scopus 로고    scopus 로고
    • University of Ottawa: Ottawa, Canada
    • Gorelsky, S. I. SWizard program; University of Ottawa: Ottawa, Canada, 2008; http://www.sg-chem.net/.
    • (2008) SWizard program
    • Gorelsky, S.I.1
  • 125
    • 84962389628 scopus 로고    scopus 로고
    • + at 4 K do not exhibit any half-field signals that would be associated with a triplet species.
    • + at 4 K do not exhibit any half-field signals that would be associated with a triplet species.
  • 126
    • 84962389459 scopus 로고    scopus 로고
    • Large zero-field splitting results in EPR transitions outside of the energy range of X-band EPR. (a) Dei, A.; Gatteschi, D.; Pardi, L.; Barra, A. L.; Brunel, L. C. Chem. Phys. Lett. 1990, 175, 589.
    • Large zero-field splitting results in EPR transitions outside of the energy range of X-band EPR. (a) Dei, A.; Gatteschi, D.; Pardi, L.; Barra, A. L.; Brunel, L. C. Chem. Phys. Lett. 1990, 175, 589.
  • 132
    • 84962347516 scopus 로고    scopus 로고
    • + (frozen DCM solution) is 8979.2 eV, suggesting that it is a Cu(II)-ligand- radical complex.
    • + (frozen DCM solution) is 8979.2 eV, suggesting that it is a Cu(II)-ligand- radical complex.
  • 137
    • 2142729115 scopus 로고    scopus 로고
    • Miller, J. S, Drillon, M, Eds, Wiley-VCH: Weinheim
    • Shultz, D. A. In Magnetism: Molecules to Materials II; Miller, J. S., Drillon, M., Eds.; Wiley-VCH: Weinheim, 2001; p 281.
    • (2001) Magnetism: Molecules to Materials II , pp. 281
    • Shultz, D.A.1
  • 142
    • 84962405608 scopus 로고    scopus 로고
    • + at 295 or 196 K, to probe the effect of axial ligation on the spin equilibrium, results in rapid decomposition of the sample.
    • + at 295 or 196 K, to probe the effect of axial ligation on the spin equilibrium, results in rapid decomposition of the sample.
  • 146
    • 3242758605 scopus 로고    scopus 로고
    • Stanford Synchrotron Radiation Laboratory, Stanford Linear Accelerator Center, Stanford University: Stanford, CA
    • George, G. N. EXAFSPAK & EDG_FIT; Stanford Synchrotron Radiation Laboratory, Stanford Linear Accelerator Center, Stanford University: Stanford, CA, 2000.
    • (2000) EXAFSPAK & EDG_FIT
    • George, G.N.1
  • 147
    • 84962358028 scopus 로고    scopus 로고
    • Gaussian, Inc, Wallingford, CT
    • Frisch, M. J. T.; et al. Gaussian 03, Revision C.02; Gaussian, Inc.: Wallingford, CT, 2004.
    • (2004) Gaussian 03, Revision , Issue.C.02
    • Frisch, M.J.T.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.