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Volumn , Issue 1, 1999, Pages 163-172

Stabilization of copper(III) ions with deprotonated hydroxyiminoamide ligands: Syntheses, structures, and electronic properties of copper(II) and copper(III) complexes

Author keywords

Copper; Deprotonated amide ligands; High valent metal ions; Oxime ligands; Redox chemistry

Indexed keywords

ACETONITRILE; AMIDES; ATOMS; COPPER COMPOUNDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC PROPERTIES; LIGANDS; OXIDATION; REDOX REACTIONS; SPECTROSCOPIC ANALYSIS; SYNTHESIS (CHEMICAL);

EID: 0032796548     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1099-0682(199901)1999:1<163::aid-ejic163>3.0.co;2-x     Document Type: Article
Times cited : (52)

References (54)
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    • II redox potential shifts by maximally +10 mV upon changing the temperature from -30 to +30°C. If preferential axial coordination of solvent molecules to the copper(II) ion occurs, shifts of -30 to -50 mV are expected: [19a] M. P. Youngblood, D. W. Margerum, Inorg. Chem. 1980, 19, 3068-3072. [19b] E. Kimura, T. Koike, R. Machida, R. Nagai, M. Kodama, Inorg. Chem. 1984, 23, 4181-4188.
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    • II redox potential shifts by maximally +10 mV upon changing the temperature from -30 to +30°C. If preferential axial coordination of solvent molecules to the copper(II) ion occurs, shifts of -30 to -50 mV are expected: [19a] M. P. Youngblood, D. W. Margerum, Inorg. Chem. 1980, 19, 3068-3072. [19b] E. Kimura, T. Koike, R. Machida, R. Nagai, M. Kodama, Inorg. Chem. 1984, 23, 4181-4188.
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    • note
    • The absorption bands in the spectra of the copper(III) complexes vanish over time without new characteristic absorption bands appearing. The resulting spectra do not resemble those of the respective original copper(II) complexes indicating, that decomposition of the complexes has occurred.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.