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Volumn 119, Issue 35, 1997, Pages 8217-8227

Synthetic models of the inactive Copper(II)-tyrosinate and active Copper(II)-tyrosyl radical forms of galactose and glyoxal oxidases

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPLEX; GALACTOSE OXIDASE; GLYOXAL; LIGAND; TYROSINE; ZINC COMPLEX;

EID: 0030818539     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9700663     Document Type: Article
Times cited : (210)

References (76)
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    • (1993) Bioinorganic Chemistry of Copper , pp. 447-458
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    • II-phenolate complexes have appeared: (a) Wang, Y.; Stack, T. D. P. J. Am. Chem. Soc. 1996, 118, 13097-13098.
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    • Wang, Y.1    Stack, T.D.P.2
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    • note
    • Repeated attempts to isolate the oxidized products as pure solids have yet to be successful.
  • 66
    • 0001579370 scopus 로고
    • For example, see: (a) Kahn, O.; Prins, R.; Reedijk, J.; Thompson, J. S. Inorg. Chem. 1987, 26, 3557-3561. (b) Benelli, C.; Dei, A.; Gatteschi, D.; Pardi, L. Inorg. Chem. 1990, 29, 3409-3415. (c) Dei, A.; Gatteschi, D.; Pardi, L.; Barra, A. L.; Brunel, L. C. Chem. Phys. Lett. 1990, 175, 589-592.
    • (1987) Inorg. Chem. , vol.26 , pp. 3557-3561
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  • 67
    • 0000352803 scopus 로고
    • For example, see: (a) Kahn, O.; Prins, R.; Reedijk, J.; Thompson, J. S. Inorg. Chem. 1987, 26, 3557-3561. (b) Benelli, C.; Dei, A.; Gatteschi, D.; Pardi, L. Inorg. Chem. 1990, 29, 3409-3415. (c) Dei, A.; Gatteschi, D.; Pardi, L.; Barra, A. L.; Brunel, L. C. Chem. Phys. Lett. 1990, 175, 589-592.
    • (1990) Inorg. Chem. , vol.29 , pp. 3409-3415
    • Benelli, C.1    Dei, A.2    Gatteschi, D.3    Pardi, L.4
  • 68
    • 0006548053 scopus 로고
    • For example, see: (a) Kahn, O.; Prins, R.; Reedijk, J.; Thompson, J. S. Inorg. Chem. 1987, 26, 3557-3561. (b) Benelli, C.; Dei, A.; Gatteschi, D.; Pardi, L. Inorg. Chem. 1990, 29, 3409-3415. (c) Dei, A.; Gatteschi, D.; Pardi, L.; Barra, A. L.; Brunel, L. C. Chem. Phys. Lett. 1990, 175, 589-592.
    • (1990) Chem. Phys. Lett. , vol.175 , pp. 589-592
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    • note
    • tBu4M complexes that show a difference between the relative geometries of these ligands compared to the proteins a corresponding divergence in the CT bands would not be surprising.
  • 73
    • 1842326688 scopus 로고    scopus 로고
    • Unpublished results
    • Presumably, this decomposition is facilitated by the presence of unpaired spin density at the unprotected benzylic position (where the phenolate is linked to the macrocycle). The design and synthesis of new ligands protected at this position is underway (Jazdzewski, B. A., Tolman, W. B. Unpublished results).
    • Jazdzewski, B.A.1    Tolman, W.B.2
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    • note
    • II-phenoxyl radical complexes described herein with alcohols, but have yet to observe significant yields of aldehydes.
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    • Siemens Energy & Automation, Inc., Madison, WI 53719-1173
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.