Tuning the Structure and Reactivity of the [Cu2(μ-O)2]2+ Core: Characterization of a New Bis(μ-oxo)dicopper Complex Stabilized by a Sterically Hindered Dinucleating Bis(triazacyclononane) Ligand

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 1-2, 1997, Pages 130-133

  Mahapatra, Samiran ^b   Young Jr , Victor G ^b   Kaderli, Susan ^a   Zuberbühler, Andreas D ^a   Tolman, William B ^b  

^a UNIVERSITY OF BASEL   (Switzerland)

^b University of Minnesota   (United States)

Author keywords

Copper; Enzyme mimetics; N ligands; O o activation

Indexed keywords

EID: 0030848960     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199701301     Document Type: Article

References (31)

1. Recent reviews: a) K. D. Karlin, Y Gultneh, Prog. Inorg. Chem. 1987, 35, 219-328; b) K. D. Karlin, Z. Tyeklár, Adv. Inorg. Biochem. 1994, 9, 123- 172; N. Kitajima, Y. Moro-oka, Chem. Rev. 1994, 94, 737; S. Fox, K. D. Karlin, in Active Oxygen in Biochemistry (Eds.: J. S. Valentine, C. S. Foote, A. Greenberg, J. F. Liebman), Biackie Academic & Professional. Chapman & Hall, Glasgow, Scotland 1995, pp. 188-231.
2. Recent reviews: a) K. D. Karlin, Y Gultneh, Prog. Inorg. Chem. 1987, 35, 219-328; b) K. D. Karlin, Z. Tyeklár, Adv. Inorg. Biochem. 1994, 9, 123- 172; N. Kitajima, Y. Moro-oka, Chem. Rev. 1994, 94, 737; S. Fox, K. D. Karlin, in Active Oxygen in Biochemistry (Eds.: J. S. Valentine, C. S. Foote, A. Greenberg, J. F. Liebman), Biackie Academic & Professional. Chapman & Hall, Glasgow, Scotland 1995, pp. 188-231.
3. Recent reviews: a) K. D. Karlin, Y Gultneh, Prog. Inorg. Chem. 1987, 35, 219-328; b) K. D. Karlin, Z. Tyeklár, Adv. Inorg. Biochem. 1994, 9, 123- 172; N. Kitajima, Y. Moro-oka, Chem. Rev. 1994, 94, 737; S. Fox, K. D. Karlin, in Active Oxygen in Biochemistry (Eds.: J. S. Valentine, C. S. Foote, A. Greenberg, J. F. Liebman), Biackie Academic & Professional. Chapman & Hall, Glasgow, Scotland 1995, pp. 188-231.
4. Recent reviews: a) K. D. Karlin, Y Gultneh, Prog. Inorg. Chem. 1987, 35, 219-328; b) K. D. Karlin, Z. Tyeklár, Adv. Inorg. Biochem. 1994, 9, 123- 172; N. Kitajima, Y. Moro-oka, Chem. Rev. 1994, 94, 737; S. Fox, K. D. Karlin, in Active Oxygen in Biochemistry (Eds.: J. S. Valentine, C. S. Foote, A. Greenberg, J. F. Liebman), Biackie Academic & Professional. Chapman & Hall, Glasgow, Scotland 1995, pp. 188-231.
5. a) Z. Tyeklár, R. R. Jacobson, N. Wei, N. N. Murthy, J. Zubieta, K. D. Karlin, J. Am. Chem. Soc. 1993, 115, 2677-2689;
6. b) N. Kitajima, K. Fujisuwa, C. Fujimoto, Y. Moro-oka, S. Hashimoto, T. Kitagawa, K. Toriumi, K. Tatsumi, A. Nakamura. ibid. 1992, 114, 1277-1291;
7. c) K. Fujisawa, M. Tanaka, Y. Moro-oka, N. Kitajima, ibid. 1994, 116, 12079-12080;
8. d) J. Reim, B. Krebs, Angew. Chem. 1994, 106, 2040-2042; Angew. Chem. Int. Ed. Engl. 1994, 33, 1969-1971;
9. d) J. Reim, B. Krebs, Angew. Chem. 1994, 106, 2040-2042; Angew. Chem. Int. Ed. Engl. 1994, 33, 1969-1971;
10. e) A. P. Cole, D. E. Root, P. Mukherjee, E. I. Solomon, T. D. P. Stack. Science 1996, 273, 1848-1850.
11. a) J. A. Halfen, S. Mahapatra, E. C. Wilkinson, S. Kaderli, V. G. Young, Jr., L. Que, Jr., A. D. Zuberbühler, W. B. Tolman, Science 1996, 271, 1397-1400;
12. b) S. Mahapatra, J. A. Halfen, E. C. Wilkinson, G. Pan, C. J. Cramer, L. Que, Jr., W. B. Tolman, J. Am. Chem. Soc. 1995, 117, 8865-8866;
13. c) S. Mahapatra, J. A. Hallen, E. C. Wilkinson, G. Pan, X. Wang, V. G. Young, Jr., C. J. Cramer, L. Que, Jr., W. B. Tolman, ibid. 1996, 118, 11555-11574;
14. d) S. Mahapatra, J. A. Halfen, E. C. Wilkinson, L. Que, Jr., W. B. Tolman, ibid. 1994, 116, 9785- 9786.
15. S. Mahapatra, J. A. Halfen, W. B. Tolman, J. Am. Chem. Soc. 1996, 118, 11575-11586.
16. N. Tanaka, Y. Kobayashi, S. Takamoto, Chem. Left. 1977, 107-108; K. Wieghardt, I. Tolksdorf, W. Herrmann, Inorg. Chem. 1985, 24, 1230-1235; A. Geilenkirchen, K. Wieghardt, Z. Naturforch. B 1989, 44, 1333-1335; D. Hanke, K. Wieghardt, B. Nuber, R.-S. Lu, R. K. McMullan, T. F. Koetzle, R. Bau, Inorg. Chem. 1993, 32, 4300-4305; A. J. Blake, T. M. Donlevy, P. A. England, I. A. Fallis, S. Parsons, S. A. Ross, M. Schröder, J. Chem. Soc. Chem. Commun. 1994, 1981-1982.
17. N. Tanaka, Y. Kobayashi, S. Takamoto, Chem. Left. 1977, 107-108; K. Wieghardt, I. Tolksdorf, W. Herrmann, Inorg. Chem. 1985, 24, 1230-1235; A. Geilenkirchen, K. Wieghardt, Z. Naturforch. B 1989, 44, 1333-1335; D. Hanke, K. Wieghardt, B. Nuber, R.-S. Lu, R. K. McMullan, T. F. Koetzle, R. Bau, Inorg. Chem. 1993, 32, 4300-4305; A. J. Blake, T. M. Donlevy, P. A. England, I. A. Fallis, S. Parsons, S. A. Ross, M. Schröder, J. Chem. Soc. Chem. Commun. 1994, 1981-1982.
18. N. Tanaka, Y. Kobayashi, S. Takamoto, Chem. Left. 1977, 107-108; K. Wieghardt, I. Tolksdorf, W. Herrmann, Inorg. Chem. 1985, 24, 1230-1235; A. Geilenkirchen, K. Wieghardt, Z. Naturforch. B 1989, 44, 1333-1335; D. Hanke, K. Wieghardt, B. Nuber, R.-S. Lu, R. K. McMullan, T. F. Koetzle, R. Bau, Inorg. Chem. 1993, 32, 4300-4305; A. J. Blake, T. M. Donlevy, P. A. England, I. A. Fallis, S. Parsons, S. A. Ross, M. Schröder, J. Chem. Soc. Chem. Commun. 1994, 1981-1982.
19. N. Tanaka, Y. Kobayashi, S. Takamoto, Chem. Left. 1977, 107-108; K. Wieghardt, I. Tolksdorf, W. Herrmann, Inorg. Chem. 1985, 24, 1230-1235; A. Geilenkirchen, K. Wieghardt, Z. Naturforch. B 1989, 44, 1333-1335; D. Hanke, K. Wieghardt, B. Nuber, R.-S. Lu, R. K. McMullan, T. F. Koetzle, R. Bau, Inorg. Chem. 1993, 32, 4300-4305; A. J. Blake, T. M. Donlevy, P. A. England, I. A. Fallis, S. Parsons, S. A. Ross, M. Schröder, J. Chem. Soc. Chem. Commun. 1994, 1981-1982.
20. N. Tanaka, Y. Kobayashi, S. Takamoto, Chem. Left. 1977, 107-108; K. Wieghardt, I. Tolksdorf, W. Herrmann, Inorg. Chem. 1985, 24, 1230-1235; A. Geilenkirchen, K. Wieghardt, Z. Naturforch. B 1989, 44, 1333-1335; D. Hanke, K. Wieghardt, B. Nuber, R.-S. Lu, R. K. McMullan, T. F. Koetzle, R. Bau, Inorg. Chem. 1993, 32, 4300-4305; A. J. Blake, T. M. Donlevy, P. A. England, I. A. Fallis, S. Parsons, S. A. Ross, M. Schröder, J. Chem. Soc. Chem. Commun. 1994, 1981-1982.
21. -1.
22. -3). Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-179-133. Copies of the data can be obtained free of charge on application to The Director, CCDC. 12 Union Road, Cambridge CB2 1EZ, UK (fax: Int. code + (1223) 336-033: e-mail: deposit@chemcrys.eam.ac.uk).
23. a) K. Wieghardt, U. Bossek, L. Zsolnai, G. Huttner, G. Blondin, J.- J. Girerd, F. Bubonneau, J. Chem. Soc., Chem. Commun. 1987, 651-653;
24. b) J. S. Bashkin, A. R. Schake, J. B. Vincent, H.-R. Chang, Q. Li, J. C. Huffman, G. Christou, D. N. Hendrickson, ibid. 1988, 700-702;
25. c) U. Bossek, T. Weyhermüller, K. Wieghardt, B. Nuber, J. Weiss, J. Am. Chem. Soc. 1990, 112, 6387-6388;
26. d) S. Pal, M. M. Olmstead, W. H. Armstrong, Inorg. Chem. 1995, 34, 4708-4715.
27. For methods used, see ref. [3a]and: K. D. Karlin, N. Wei, B. Jung, S. Kaderli, P. Niklaus, A. D. Zuberbühler, J. Am. Chem. Soc. 1993, 115, 9506-9514.
28. H. Kwart, Acc. Chem. Res. 1982, 15, 408-415.
29. K. D. Karlin, M. S. Haka, R. W. Cruse, G. J. Meyer, A. Farooq, Y. Gulneh. J. C. Hayes, J. Zubieta, J. Am. Chem. Soc. 1988, 110, 1196-1207.
30. a) R. P. Houser, J. A. Halfen, V. G. Young, Jr., N. J. Blackburn, W. B. Tolman, J. Am. Chem. Soc. 1995, 117, 10745-10746;
31. b) J. A. Halfen, W. B. Tolman, Inorg, Synth. in press.