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(d) For a related β-diketiminate Ni(III) iminyl radical complex with 57% spin density on the N, see: Kogut, E.; Wiencko, H. L.; Zhang, L.; Cordeau, D. E.; Warren, T. H. J. Am. Chem. Soc. 2005, 127, 11248-11249.
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note
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Density functional theory calculations were performed with the Amsterdam Density Functional (ADF 2005.01) package. Details are given in the Supporting Information.
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16
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0037861063
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There is a vast quantity of literature on this topic, which is impossible to provide here; see the selected recent references and literature cited therein: (a) Ray, K.; Weyhermüller, T.; Goossens, A.; Crajé, M. W. J.; Wieghardt, K. Inorg. Chem. 2003, 42, 4082-4087.
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(b) Beloglazkina, E. K.; Moiseeva, A. A.; Chizhevskii, A. A.; Tarasevich, B. N.; Zyk, N. V.; Butin, K. P. Russ. Chem. Bull., Int. Ed. 2003, 52, 1990-2004.
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(c) See ref 1 in: Breher, F.; Böhler, C.; Frison, G.; Harmer, J.; Liesum, L.; Schweiger, A.; Grützmacher, H. Chem.-Eur. J. 2003, 9, 3859-3866.
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