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Volumn 122, Issue 24, 2000, Pages 5775-5787

A systematic K-edge X-ray absorption spectroscopic study of Cu(III) sites

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COPPER DERIVATIVE;

EID: 0034697659     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja993134p     Document Type: Article
Times cited : (206)

References (84)
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    • note
    • K-edge: the electronic absorption spectrum of the Is electron, extending to and beyond the Is electron binding energy.
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    • The EXAFSPAK programs (including EDG_FIT) were written by Dr. Graham N. George, SSRL. They may be obtained free at the following web site: http://www-ssrl.slac.stanford.edu/exafspak.html.
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    • note
    • Such an intensity distribution was also typical of the range of Cu(II) K-edges included in ref 27.
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    • Because of the extreme temperature sensitivity of the complex, it was important to demonstrate that the trinuclear sample on which the edge was measured was intact. To this end, the EXAFS for the trinuclear cluster was fit, with good agreement between the EXAFS results and crystallographic structure. Both short Cu(III)-ligand and longer Cu(II)-ligand distances were determined.
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    • unpublished results
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