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Volumn , Issue 16, 2007, Pages 1552-1566

Joint spectroscopic and theoretical investigations of transition metal complexes involving non-innocent ligands

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; AMINES; DENSITY FUNCTIONAL THEORY; DICHROISM; PARAMAGNETIC RESONANCE; TRANSITION METAL COMPOUNDS; X RAY ABSORPTION SPECTROSCOPY;

EID: 34147114271     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b700096k     Document Type: Article
Times cited : (284)

References (103)
  • 51
    • 34147092462 scopus 로고    scopus 로고
    • E. I. Stiefel, (Ed.), Prog. Inorg. Chem.
    • Dithiolene Chemistry, E. I. Stiefel, (Ed.), Prog. Inorg. Chem., 2004, Vol 52
    • (2004) Dithiolene Chemistry , vol.52
  • 96
    • 0000522465 scopus 로고
    • As we move across the d-block from left to right, we are successively adding a proton and an electron at each step. The proton increases the nuclear charge by +1 e. The electron is added to one of the 3d orbitals. The d-orbitals have two nodes and therefore d-electrons shield the nuclear-charge rather poorly. Hence, the effective nuclear charge will rise steadily over the d-block and therefore d-orbitals will be stabilized. On moving down a group, again the increasing nuclear charge is not fully shielded by the d- or f-electrons and hence the outer d-orbitals are stabilized
    • M. D. Carducci C. Brown E. I. Solomon J. H. Enemark J. Am. Chem. Soc. 1994 116 11856
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 11856
    • Carducci, M.D.1    Brown, C.2    Solomon, E.I.3    Enemark, J.H.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.