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It should be noted parenthetically that I have generally found it difficult to isolate X-ray suitable crystals of five-coordinate (salen)-CrX complexes. That is, these molecules have a propensity to crystallize with a second axial ligand, (salen)Cr(X)L, where L can be adventitious water.
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This study was performed in a similar manner to that employed for the related investigation involving cyclohexene oxide and CO2, except that it was necessary to add a cosolvent (toluene) due to the insolubility of poly(propylene carbonate) in neat propylene oxide
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