Turning on resonant SERRS using the chromophore-plasmon coupling created by host-guest complexation at a plasmonic nanoarray

Journal of the American Chemical Society

Volumn 132, Issue 17, 2010, Pages 6099-6107

  Witlicki, Edward H ^a   Andersen, Sissel S ^b   Hansen, Stinne W ^b   Jeppesen, Jan O ^b   Wong, Eric W ^c   Jensen, Lasse ^d   Flood, Amar H ^a  

^a INDIANA UNIVERSITY   (United States)

^b UNIVERSITY OF SOUTHERN DENMARK   (Denmark)

^c Etamota Corporation   (United States)

^d PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BINDING EVENTS; CYCLOBIS(PARAQUAT-P-PHENYLENE); ENHANCEMENT FACTOR; GOLD SUBSTRATES; GUEST MOLECULES; HOST-GUEST COMPLEXATIONS; HOST-GUESTS; LOCALIZED SURFACE PLASMON RESONANCE; MOLECULAR SENSING; NANOARRAYS; NANODISCS; PLASMON COUPLING; PLASMON RESONANCES; PLASMON WAVELENGTH; PLASMONIC DEVICES; PLASMONICS; RESONANCE SURFACE; SPECTRAL OVERLAP; SURFACE ADSORPTION; SURFACE-ENHANCED RESONANCE RAMAN SCATTERING; TETRATHIAFULVALENES;

ADSORPTION; ELECTRIC FIELDS; GOLD; GOLD COMPOUNDS; LASER EXCITATION; PLASMONS; RAMAN SCATTERING; SUBSTRATES; SURFACE PLASMON RESONANCE; TITRATION; TURNING;

CHROMOPHORES;

NANODISC; TETRATHIAFULVALENE DERIVATIVE;

ADSORPTION KINETICS; ARTICLE; CHROMATOPHORE; COMPLEX FORMATION; CONTROLLED STUDY; ELECTRIC FIELD; ENZYME SUBSTRATE; MOLECULAR MECHANICS; NANOARRAY; RAMAN SPECTROMETRY; SIMULATION; SURFACE CHARGE; SURFACE PLASMON RESONANCE; TITRIMETRY; TRANSPORT KINETICS;

EID: 77951691285     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja910155b     Document Type: Article

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166. Sandroff, C. J., Weltz, D. A., Chung, J. C., and Herschbach, D. R. J. Phys. Chem. 1983, 87, 2127-2133
167. Joy, V. T. and Srinivasan, T. K. K. Chem. Phys. Lett. 2000, 328, 221-226
168. -1 band. While this band is weakly enhanced in the SERRS spectrum, it is not even observed in the solution resonance Raman spectrum (Figure 7 d).
169. Jang, S. S., Jang, Y. H., Kim, Y.-H., Goddard, W. A., Flood, A. H., Laursen, B. W., Tseng, H.-R., Stoddart, J. F., Jeppesen, J. O., Choi, J. W., Steuerman, D. W., DeIonno, E., and Heath, J. R. J. Am. Chem. Soc. 2005, 127, 1563-1575
170. Jang, S. S., Jang, Y. H., Kim, Y.-H., Goddard, W. A., Choi, J. W., Heath, J. R., Laursen, B. W., Flood, A. H., Stoddart, J. F., Norgaard, K., and Bjornholm, T. J. Am. Chem. Soc. 2005, 127, 14804-14816
171. Nørgaard, K., Laursen, B. W., Nygaard, S., Kjaer, K., Tseng, H.-R., Flood, A. H., Stoddart, J. F., and Bjørnholm, T. Angew. Chem., Int. Ed. 2005, 44, 7035-7039
172. -1, MeCN, 298 K), which merely dictates that, for this titration, more molar equivalents of DNP were used to achieve the same level of complexation for comparative purposes.
173. 63MeCN (see ref 33a), suggesting they will have similar surface affinities.
174. Dotz, K. H. and Popall, M. Chem. Ber. 1988, 121, 665-672