Localized surface plasmon resonance spectroscopy and sensing

Annual Review of Physical Chemistry

Volumn 58, Issue , 2007, Pages 267-297

  Willets, Katherine A ^a   Van Duyne, Richard P ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

Molecular plasmonics; Nanoparticles; Nanosphere lithography; Refractive index sensing; Surface enhanced raman scattering

Indexed keywords

LOCALIZED SURFACE PLASMON RESONANCE (LSPR); MOLECULAR PLASMONICS; REFRACTIVE-INDEX SENSING; SURFACE-ENHANCED SPECTROSCOPY;

BIOSENSORS; CHEMICAL SENSORS; ELECTROMAGNETIC FIELD EFFECTS; LITHOGRAPHY; NANOSPHERES; REFRACTIVE INDEX; SPECTROSCOPIC ANALYSIS; SURFACE PLASMON RESONANCE;

NANOPARTICLES;

NANOMATERIAL;

CHEMISTRY; INSTRUMENTATION; METHODOLOGY; REVIEW; SPECTROSCOPY; SURFACE PLASMON RESONANCE; ULTRASTRUCTURE;

NANOSTRUCTURES; SPECTRUM ANALYSIS; SURFACE PLASMON RESONANCE;

EID: 34249950754     PISSN: 0066426X     EISSN: None     Source Type: Book Series    
DOI: 10.1146/annurev.physchem.58.032806.104607     Document Type: Article

References (122)

1. Jeanmarie DL, Van Duyne RP. 1977. Surface Raman spectroelectrochemistry, part I: heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode. J. Electroanal. Chem. 84:1-20
2. Haynes CL, Yonzon CR, Zhang X. 2005. Surface-enhanced Raman sensors: early history and the development of sensors for quantitative biowarfare agent and glucose detection. J. Raman Spectrosc. 36:471-84
3. Schatz GC, Young MA, Van Duyne RP. 2006. Electromagnetic mechanism of SERS. In Surface-Enhanced Raman Scattering: Physics and Applications, ed. K Kneipp, M Moskovits, H Kneipp, pp. 19-46. Berlin: Springer-Verlag
4. Yonzon CR, Haynes CL, Zhang X, Walsh JT, Van Duyne RP. 2004. A glucose biosensor based on surface-enhanced Raman scattering: improved partition layer, temporal stability, reversibility, and resistance to serum protein interference. Anal. Chem. 76:78-85
5. Zeman EJ, Schatz GC. 1987. An accurate electromagnetic theory study of surface enhancement factors for silver, gold, copper, lithium, sodium, aluminum, gallium, indium, zinc, and cadmium. J. Phys. Chem. 91:634-43
6. Emory SR, Nie S. 1997. Probing single molecules and single nanoparticles by surface-enhanced Raman scattering. Science 275:1102-6
7. Kneipp K, Wang Y, Kneipp H, Perelman LT, Itzkan I, et al. 1997. Single molecule detection using surface-enhanced Raman scattering (SERS). Phys. Rev. Lett. 78:1667-70
8. Haller KL, Bumm LA, Altkorn RI, Zeman EJ, Schatz GC, Van Duyne RP. 1989. Spatially resolved surface enhanced second harmonic generation: theoretical and experimental evidence for electromagnetic enhancement in the near infrared on a laser microfabricated platinum surface. J. Chem. Phys. 90:1237-52
9. Pipino ACR, Schatz GC, Van Duyne RP. 1994. Surface-enhanced second-harmonic diffraction: selective enhancement by spatial harmonics. Phys. Rev. 549:8320-30
10. Pipino ACR, Van Duyne RP, Schatz GC. 1996. Surface-enhanced second-harmonic diffraction: experimental investigation of selective enhancement. Phys. Rev. 553:4162-69
11. Yang W, Hulteen J, Schatz GC, Van Duyne RP. 1996. A surface-enhanced hyper-Raman and surface-enhanced Raman scattering study of trans-1,2-bis(4- pyridyl)ethylene adsorbed onto silver film over nanosphere electrodes. Vibrational assignments: experiment and theory. J. Chem. Phys. 104:4313-23
12. Geddes CD, AsianK, Gryczynski I, Malicka J, Lakowicz JR. 2004. Noble-metal surfaces for metal enhanced fluorescence. Rev. Fluoresc. 1:365-401
13. Goulet PJG, Aroca RF. 2005. Surface-enhancement of fluorescence near noble metal nanostructures. Top. Fluoresc. Spectrosc. 8:223-47
14. Golab JT, SpragueJR, Carron KT, Schatz GC, Van Duyne RP. 1988. A surface-enhanced hyper-Raman scattering study of pyridine adsorbed onto silver: experiment and theory. J. Chem. Phys. 88:7942-51
15. Jensen TR, Van Duyne RP, Johnson SA, Maroni VA. 2000. Surface-enhanced infrared spectroscopy: a comparison of metal island films with discrete and nondiscrete surface plasmons. Appl. Spectrosc. 54:371-77
16. Shimizu KT, Woo WK, Fisher BR, Eisler HJ, Bawendi MG. 2002. Surface-enhanced emission from single semiconductor nanocrystals. Phys. Rev. Lett. 89:117401
17. Haes AJ, Chang L, Klein WL, Van Duyne RP. 2005. Detection of a biomarker for Alzheimer's disease from synthetic and clinical samples using a nanoscale optical biosensor. J, Am. Chem. Soc. 127:2264-71
18. Haes AJ, Hall WP, Chang L, Klein WL, Van Duyne RP. 2004. A localized surface plasmon resonance biosensor: first steps toward an assay for Alzheimer's disease. Nano Lett. 4:1029-34
19. Haes AJ, Stuart DA, Nie SM, Van Duyne RP. 2004. Using solution-phase nanoparticles, surface-confined nanoparticle arrays and single nanoparticles as biological sensing platforms. J. Fluoresc. 14:355-67
20. McFarland AD, Van Duyne RP. 2003. Single silver nanoparticles as real-time optical sensors with zeptomole sensitivity. Nano Lett. 3:1057-62
21. Yonzon CR, Jeoung E, Zou S, Schatz GC, Mrksich M, Van Duyne RP. 2004. A comparative analysis of localized and propagating surface plasmon resonance sensors: the binding of concanavalin A to a monosaccharide functionalized self-assembled monolayer. J. Am. Chem. Soc. 126:12669-76
22. Yonzon CR, Stuart DA, Zhang X, McFarland AD, Haynes CL, Van Duyne RP. 2005. Towards advanced chemical and biological nanosensors: an overview. Talanta 67:438-48
23. Yonzon CR, Zhang X, Van Duyne RP. 2003. Localized surface plasmon resonance immunoassay and verification using surface-enhanced Raman spectroscopy. Proc. SPIE 5224:78-85
24. Malinsky MD, Kelly KL, Schatz GC, Van Duyne RP. 2001. Chain length dependence and sensing capabilities of the localized surface plasmon resonance of silver nanoparticles chemically modified with alkanethiol self-assembled monolayers. J. Am. Chem. Soc. 123:1471-82
25. Jung LS, Campbell CT, Chinowsky TM, Mar MN, Yee SS. 1998. Quantitative interpretation of the response of surface plasmon resonance sensors to adsorbed films. Langmuir 14:5636-48
26. Smith EA, Corn RM. 2003. Surface plasmon resonance imaging as a tool to monitor biomolecular interactions in an array based format. Appl. Spectrosc. 57:A320-22
27. 7. Brockman JM, Nelson BP, Corn RM. 2 000. Surface plasmon resonance imaging measurements of ultrathin organic films. Annu. Rev. Phys. Chem. 51:41-63
28. Giebel KF, Bechinger C, Herminghaus S, Riedel M, Leiderer P, et al. 1999. Imaging of cell/substrate contacts of living cells with surface plasmon resonance microscopy. Biophys. J. 76:509-16
29. Berger GEH, Beumer TAM, Kooyman RPH, Greve J. 1998. Surface plasmon resonance multisensing. Anal. Chem. 70:703-6
30. Endo T, Kerman K, Nagatani N, Takamura Y, Tamiya E. 2005. Label-free detection of peptide nucleic acid-DNA hybridization using localized surface plasmon resonance based optical biosensor. Anal. Chem. 77:6976-84
31. Endo T, Yamamura S, Nagatani N, Morita Y, Takamura Y, Tamiya E. 2005. Localized surface plasmon resonance based optical biosensor using surface modified nanoparticle layer for label free monitoring of antigen-antibody reaction. Sci. Technol. Adv. Mater. 6:491-500
32. Englebienne P. 1998. Use of colloidal gold surface plasmon resonance peak shift to infer affinity constants from the interactions between protein antigens and antibodies specific for single or multiple epitopes. Analyst 123:1599-603
33. Raschke G, Kowarik S, Franzl T, Soennichsen C, Klar TA, et al. 2003. Biomolecular recognition based on single gold nanoparticle light scattering. Nano Lett. 3:935-38
34. Srituravanich W, Fang N, Sun C, Luo Q, Zhang X. 2004. Plasmonic nanolithography. Nano Lett. 4:1085-88
35. Kik PG, Maier SA, Atwater HA. 2004. Surface plasmons for nanofabrication. Proc. SPIE 5347:215-23
36. Sundaramurthy A, Schuck PJ, Conley NR, Fromm DP, Kino GS, Moerner WE. 2006. Toward nanometer-scale optical photolithography: utilizing the near-field of bowtie optical nanoantennas. Nano Lett. 6:355-60
37. Malmqvist M. 1993. Biospecific interaction analysis using biosensor technology. Nature 361:186-87
38. Van Duyne RP. 2004. Molecular plasmonics. Science 306:985-86
39. Knoll W. 1998. Interfaces and thin films as seen by bound electromagnetic waves. Annu. Rev. Phys. Chem. 49:569-638
40. Haes AJ, Van Duyne RP. 2004. A unified view of propagating and localized surface plasmon resonance biosensors. Anal. Bioanal. Chem. 379:920-30
41. Haes AJ, Haynes CL, McFarland AD, Zou S, Schatz GC, Van Duyne RP. 2005. Plasmonic materials for surface-enhanced sensing and spectroscopy. MRS Bull. 30:368-75
42. Zhang X, Young MA, Lyandres O, Van Duyne RP. 2005. Rapid detection of an anthrax biomarker by surface-enhanced Raman spectroscopy. J. Am. Chem. Soc. 127:4484-89
43. Kelly KL, Coronado E, Zhao L, Schatz GC. 2003. The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment. J. Phys. Chem. E 107:668-77
44. Knobloch H, Brunner H, Leitner A, Aussenegg F, Knoll W. 1993. Probing the evanescent field of propagating plasmon surface polaritons by fluorescence and Raman spectroscopies. J. Chem. Phys. 98:10093-95
45. Miller MM, Lazarides AA. 2005. Sensitivity of metal nanoparticle surface plasmon resonance to the dielectric environment. J- Phys. Chem. B 109:21556-65
46. Jensen TR, Duval ML, Kelly L, Lazarides A, Schatz GC, Van Duyne RP. 1999. Nanosphere lithography: effect of the external dielectric medium on the surface plasmon resonance spectrum of a periodic array of silver nanoparticles. J. Phys. Chem. B 103:9846-53
47. Hamamoto K, Micheletto R, Oyama M, Umar AA, Kawai S, Kawakami Y. 2006. An original planar multireflection system for sensing using the local surface plasmon resonance of gold nanospheres. J. Opt. A 8:268-71
48. Albrecht MG, Creighton JA. 1977. Anomalously intense Raman spectra of pyridine at a silver electrode. J. Am. Chem. Soc. 99:5215-17
49. Otto A, Mrozek I, Grabhorn H, Akemann W. 1992. Surface-enhanced Raman scattering. J. Phys. Condens. Matter 4:1143-212
50. Moskovits M. 1978. Surface roughness and the enhanced intensity of Raman scattering by molecules adsorbed on metals. J. Chem. Phys. 69:4159-61
51. Gersten J, Nitzan A. 1980. Electromagnetic theory of enhanced Raman scattering by molecules adsorbed on rough surfaces. J. Chem. Phys. 73:3023-37
52. Metiu H, Das P. 1984. The electromagnetic theory of surface enhanced spectroscopy. Annu. Rev. Phys. Chem. 35:507-36
53. Schatz GC. 1984. Theoretical studies of surface enhanced Raman scattering. Acc. Chem. Res. 17:370-76
54. Wokaun A. 1985. Surface enhancement of optical fields: mechanism and applications. Mol. Phys. 56:1-33
55. Wokaun A. 1984. Surface-enhanced electromagnetic processes. Solid State Phys. 38:223-94
56. Haynes CL, Van Duyne RP. 2001. Nanosphere lithography: a versatile nanofabrication tool for studies of size-dependent nanoparticle optics. J. Phys. Chem. B 105:5599-611
57. Sherry LJ, Chang SH, Schatz GC, Van Duyne RP, Wiley BJ, Xia Y. 2005. Localized surface plasmon resonance spectroscopy of single silver nanocubes. Nano Lett. 5:2034-38
58. Mock JJ, Barbic M, Smith DR, Schultz DA, Schultz S. 2002. Shape effects in plasmon resonance of individual colloidal silver nanoparticles. J. Chem. Phys. 116:6755-59
59. Haynes CL, McFarland AD, Smith MT, Hulteen JC, Van Duyne RP. 2002. Angle-resolved nanosphere lithography: manipulation of nanoparticle size, shape, and interparticle spacing. J. Phys. Chem. B 106:1898-902
60. Haynes CL, McFarland AD, Van Duyne RP. 2005. Surface-enhanced Raman spectroscopy. Anal. Chem. 77:A338-46
61. Moran AM, Sung J, Hicks EM, Van Duyne RP, Spears KG. 2005. Second harmonic excitation spectroscopy of silver nanoparticle arrays. J. Phys. Chem. B 109:4501-6
62. Whitney AV, Elam JW, Zou S, Zinovev AV, Stair PC, et al. 2005. Localized surface plasmon resonance nanosensor: a high-resolution distance-dependence study using atomic layer deposition. J. Phys. Chem. B 109:20522-28
63. Haes AJ, Zou S, Schatz GC, Van Duyne RP. 2004. Ananoscale optical biosensor: the long range distance dependence of the localized surface plasmon resonance of noble metal nanoparticles. J. Phys. Chem. B 108:109-16
64. Nehl CL, Liao H, Hafner JH. 2006. Optical properties of star-shaped gold nanoparticles. Nano Lett. 6:683-88
65. Xia Y, Halas NJ. 2005. Shape-controlled synthesis and surface plasmonic properties of metallic nanostructures. MRS Bull. 30:338-48
66. Wiley B, Sun Y, Mayers B, Xia Y. 2005. Shape-controlled synthesis of metal nanostructures: the case of silver. Chem. A Eur. J. 11:454-63
67. Sun Y, Xia Y. 2002. Shape-controlled synthesis of gold and silver nanoparticles. Science 298:2176-79
68. ZhangX, Hicks EM, Zhao J, Schatz GC, Van Duyne RP. 2005. Electrochemical tuning of silver nanoparticles fabricated by nanosphere lithography. Nano Lett. 5:1503-7
69. Jin R, Cao YC, Hao E, Metraux GS, Schatz GC, Mirkin CA. 2003. Controlling anisotropic nanoparticle growth through plasmon excitation. Nature 425:487-90
70. Jin R, Cao Y, Mirkin CA, Kelly KL, Schatz GC, ZhengJG. 2001. Photoinduced conversion of silver nanospheres to nanoprisms. Science 294:1901-3
71. Haynes CL, McFarland AD, Zhao L, Van Duyne RP, Schatz GC, et al. 2003. Nanoparticle optics: the importance of radiative dipole coupling in two-dimensional nanoparticle arrays. J. Phys. Chem. B 107:7337-42
72. Athawale AA, Katre PP, Majumdar MB. 2005. Nonaqueous phase synthesis of copper nanoparticles. J. Nanosci. Nanotech. 5:991-93
73. Bohren CF, Huffman DR. 1983. Absorption and Scattering of Light by Small Particles. New York: Wiley. 530 pp.
74. Mie G. 1908. Contributions to the optics of turbid media, especially colloidal metal solutions. Ann. Phys. 25:377-445
75. Link S, El-Sayed MA. 1999. Spectral properties and relaxation dynamics of surface plasmon electronic oscillations in gold and silver nano-dots and nano-rods. J. Phys. Chem. B 103:8410-26
76. Draine BT, Flatau PJ. 1994. Discrete-dipole approximation for scattering calculations. J. Opt. Soc. Am. A 11:1491-99
77. Jensen TR, Kelly KL, Lazarides A, Schatz GC. 1999. Electrodynamics of noble metal nanoparticles and nanoparticle clusters. J. Cluster Sci. 10:295-317
78. Yang W, Schatz GC, Van Duyne RP. 1995. Discrete dipole approximation for calculating extinction and Raman intensities for small particles with arbitrary shapes. J. Chem. Phys. 103:869-75
79. Novotny L, Bian RX, Xie XS. 1997. Theory of nanometric optical tweezers. Phys. Rev. Lett. 79:645-48
80. Bian RX, Dunn RC, Xie XS, Leung PT. 1995. Single molecule emission characteristics in near-field microscopy. Phys. Rev. Lett. 75:4772-75
81. Taflove A. 1995. Computational Electrodynamics: The Finite-Difference Time Domain Method. Boston: Artech House
82. Haes AJ, Van Duyne RP. 2002. A nanoscale optical biosensor: sensitivity and selectivity of an approach based on the localized surface plasmon resonance of triangular silver nanoparticles. J. Am. Chem. Soc. 124:10596-604
83. Van Duyne RP. 1979. Laser excitation of Raman scattering from adsorbed molecules on electrode surfaces. Chem. Biochem. Appl. Lasers 4:101-85
84. McFarland AD, Young MA, Dieringer JA, Van Duyne RP. 2005. Wavelength-scanned surface-enhanced Raman excitation spectroscopy. J. Phys. Chem. B 109:11279-85
85. Haynes CL, Haes AJ, Van Duyne RP. 2001. Nanosphere lithography: synthesis and application of nanoparticles with inherently anisotropic structures and surface chemistry. In Anisotropic Nanoparticles: Synthesis, Characterization, Applications, ed. LA Lyon, S Stranick, CD Keating, P Searson, pp. C.6.3.1-6.3. Warrendale, PA: MRS
86. Hulteen JC, Van Duyne RP. 1995. Nanosphere lithography: a materials general fabrication process for periodic particle array surfaces. J. Vac. Sci. Technol. A 13:1553-58
87. Stuart DA, Yonzon CR, Zhang X, Lyandres O, Shah NC, et al. 2005. Glucose sensing using near-infrared surface-enhanced Raman spectroscopy: gold surfaces, 10-day stability, and improved accuracy. Anal. Chem. 77:4013-19
88. Hicks EM, Zhang XY, Zou SL, Lyandres O, Spears KG, et al. 2005. Plasmonic properties of film over nanowell surface fabricated by nanosphere lithography. J. Phys. Chem. B 109:22351-58
89. Hicks EM, Zou S, Schatz GC, Spears KG, Van Duyne RP, et al. 2005. Controlling plasmon line shapes through diffractive coupling in linear arrays of cylindrical nanoparticles fabricated by electron beam lithography. Nano Lett. 5:1065-70
90. Lamprecht B, Schider G, Lechner RT, Ditlbacher H, Krenn JR, et al. 2000. Metal nanoparticle gratings: influence of dipolar particle interaction on the plasmon resonance. Phys. Rev. Lett. 84:4721-24
91. Fromm DP, Sundaramurthy A, Schuck PJ, Kino G, Moerner WE. 2004. Gapdependent optical coupling of single "bowtie" nanoantennas resonant in the visible. Nano Lett. 4:957-61
92. Wiley B, Sun Y, Xia Y. 2005. Polyol synthesis of silver nanostructures: control of product morphology with Fe(II) or Fe(III) species. Langmuir 21:8077-80
93. Im Sang H, Lee Yun T, Wiley B, Xia Y. 2005. Large-scale synthesis of silver nanocubes: the role of HCl in promoting cube perfection and monodispersity. Angew. Chem. 44:2154-57
94. Jun Y, ChoiJ, Cheon J. 2006. Shape control of semiconductor and metal oxide nanocrystals through nonhydrolytic colloidal routes. Angew. Chem. 45:3414-39
95. Xu Q, Bao J, Capasso F, Whitesides GM. 2006. Surface plasmon resonances of free-standing gold nanowires fabricated by nanoskiving. Angew. Chem. 45:3631-35
96. Haes AJ, Zhao J, Zou S, Own CS, Marks LD, et al. 2005. Solution-phase, triangular Agnanotriangles fabricated by nanosphere lithography. J. Phys. Chem. B 109:11158-62
97. Jensen TR, Malinsky MD, Haynes CL, Van Duyne RP. 2000. Nanosphere lithography: tunable localized surface plasmon resonance spectra of silver nanoparticles. J. Phys. Chem. B 104:10549-56
98. Mock JJ, Smith DR, Schultz S. 2003. Local refractive index dependence of plasmon resonance spectra from individual nanoparticles. Nano Lett. 3:485-91
99. Michaels AM, Nirmal M, Brus LE. 1999. Surface enhanced Raman spectroscopy of individual rhodarm'ne 6G molecules on large Ag nanocrystals. J. Am. Chem. Soc. 121:9932-39
100. Sherry LJ, Jin R, Mirkin CA, Schatz GC, Van Duyne RP. 2006. Localized surface plasmon resonance spectroscopy of single silver triangular nanoprisms. Nano Lett. In press
101. Haes AJ, Zou S, Schatz GC, Van Duyne RP. 2004. A nanoscale optical biosensor: the short range distance dependence of the localized surface plasmon resonance of silver and gold nanoparticles. J. Phys. Chem. B 108:6961-68
102. 3 films grown by atomic layer deposition on silicon and various metal substrates. Thin So lid Films 413:186-97
103. Ritala M, Leskela M. 2002. Atomic layer deposition. In Handbook of Thin Film Materials, ed. HS Nalwa, Vol. 1, pp. 103-59. San Diego: Academic
104. 3 thin film growth on Si(100) using binary reaction sequence chemistry. Thin Solid Films 292:135-44
105. Dieringer JA, McFarland AD, Shah NC, Stuart DA, Whitney AV, et al. 2005. Surface enhanced Raman spectroscopy: new materials, concepts, characterization tools, and applications. Faraday Discuss. 132:9-26
106. Kennedy BJ, Spaeth S, Dickey M, Carron KT. 1999. Determination of the distance dependence and experimental effects for modified SERS substrates based on self-assembled monolayers formed using alkanethiols. J. Phys. Chem. B 103:3640-46
107. Haynes CL, Van Duyne RP. 2003. Plasmon-sampled surface-enhanced Raman excitation spectroscopy. J. Phys. Chem. B 107:7426-33
108. Zou S, Schatz GC. 2005. Silver nanoparticle array structures that produce giant enhancements in electromagnetic fields. Chem. Phys. Lett. 403:62-67
109. Haes AJ, Zou S, Zhao J, Schatz GC, Van Duyne RP. 2006. Localized surface plasmon resonance spectroscopy near molecular resonances. J. Am. Chem. Soc. 128:10905-14
110. Reinhard BM, Siu M, Agarwal H, Alivisatos AP, Liphardt J. 2005. Calibration of dynamic molecular rulers based on plasmon coupling between gold nanoparticles. Nano Lett. 5:2246-52
111. Soennichsen C, Reinhard BM, Liphardt J, Alivisatos AP. 2005. A molecular ruler based on plasmon coupling of single gold and silver nanoparticles. Nat. Biotech. 23:741-45
112. Riboh JC, Haes AJ, McFarland AD, Yonzon CR, Van Duyne RP. 2003. A nanoscale optical biosensor: real-time immunoassay in physiological buffer enabled by improved nanoparticle adhesion. J. Phys. Chem. B 107:1772-80
113. Gong Y, Chang L, Viola KL, Lacor PN, Lambert MP, et al. 2003. Alzheimer's disease-affected brain: presence of oligomeric AB ligands (ADDLs) suggests a molecular basis for reversible memory loss. Proc. Natl. Acad. Sci. USA 100:10417-22
114. 1-42 are potent central nervous system neurotoxins. Proc. Natl. Acad. Sci. USA 95:6448-53
115. Lambert MP, Viola KL, Chromy BA, Chang L, Morgan TE, et al. 2001. Vaccination with soluble Aβ oligomers generates toxicity-neutralizing antibodies. J. Neurochem. 79:595-605
116. Chapman SC, Kenny HA, Woodruff TK. 2004. Activin, inhibin, and follistatin in ovarian physiology. In The Ovary, ed. PCK Leung, EY Adashi, pp. 273-87. San Diego: Elsevier
117. Zhao J, Das A, Zhang X, Schatz GC, Sligar SG, Van Duyne RP. 2006. Resonance surface plasmon spectroscopy: low molecular weight substrate binding to cytochrome P450. 128:11004-5
118. 3 overlayers fabricated by atomic layer deposition yield improved anthrax biomarker detection. J. Am. Chem. Soc. 128:10304-9
119. Shafer-Peltier KE, Haynes CL, Glucksberg MR, Van Duyne RP. 2003. Toward a glucose biosensor based on surface-enhanced Raman scattering. J. Am. Chem. Soc. 125:588-93
120. Lyandres O, Shah NC, Yonzon CR, Walsh JT, Glucksberg MR, Van Duyne RP. 2005. Real-time glucose sensing by surface-enhanced Raman spectroscopy in bovine plasma facilitated by a mixed decanethiol/mercaptohexanol partition layer. Anal. Chem. 77:6134-39
121. 2 nanosphere surfacesj. Phys. Chem. B 105:6907-15
122. Stuart DA, Biggs KB, Van Duyne RP. 2006. Surface-enhanced Raman spectroscopy of half-mustard agent. Analyst 131:568-72