Organic functionalization of group IV semiconductor surfaces: Principles, examples, applications, and prospects

Surface Science

Volumn 500, Issue 1-3, 2002, Pages 879-903

  Bent, Stacey F ^a  

^a Stanford University   (United States)

Author keywords

Alkenes; Chemisorption; Diamond; Germanium; Infrared absorption spectroscopy; Scanning tunneling microscopy; Silicon; Single crystal surfaces

Indexed keywords

ABSORPTION SPECTROSCOPY; CHEMICAL SENSORS; CHEMISORPTION; DIAMONDS; INFRARED SPECTROSCOPY; INTERFACES (MATERIALS); OLEFINS; SCANNING TUNNELING MICROSCOPY; SEMICONDUCTING GERMANIUM; SEMICONDUCTING SILICON; SINGLE CRYSTALS;

ORGANIC FUNCTIONALIZATION;

SURFACE PHENOMENA;

EID: 0037051030     PISSN: 00396028     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0039-6028(01)01553-9     Document Type: Article

References (101)

1. Molecular beam epitaxy
2. Epitaxy: The motion picture
3. The surface science of semiconductor processing
4. A new opportunity in silicon-based microelectronics
5. Organometallic chemistry on silicon surfaces: Formation of functional monolayers bound through Si-C bonds
6. Controlled molecular adsorption on silicon: Laying a foundation for molecular devices
7. Cycloaddition chemistry of organic molecules with semiconductor surfaces
8. Attaching organic layers to semiconductor surfaces
9. The importance of structure and bonding in semiconductor surface chemistry: Hydrogen on the Si(1 1 1)-7 × 7 surface
10. Semiconductor surface reconstruction: The structural chemistry of two-dimensional surface compounds
11. Surface chemistry of silicon
12. Electronic and geometric structure of Si(1 1 1)-(7 × 7) and Si(0 0 1) surfaces
13. Scanning tunneling microscopy of the interaction of hydrogen with silicon surfaces
14. Ideal hydrogen termination of the Si(1 1 1) surface
15. Theoretical prediction of a facile Diels-Alder reaction on the Si(1 0 0)-2 × 1 surface
16. Cycloaddition reactions of unsaturated hydrocarbons on the Si(1 0 0)-(2 × 1) surface: Theoretical predictions
17. A theoretical study of the structure and thermochemistry of 1,3-butadiene on the Ge/Si(1 0 0)-2 × 1 surface
18. Vibrational spectroscopic studies of Diels-Alder reactions with the Si(1 0 0)-2 × 1 surface as a dienophile
19. Diels-Alder reactions of butadienes with the Si(1 0 0)-2 × 1 surface as a dienophile: Vibrational spectroscopy, thermal desorption and NEXAFS studies
20. NEXAFS studies of adsorption and reaction of benzene on Si(1 0 0)-2 × 1
21. Cycloaddition of cyclopentadiene and dicyclopentadiene on Si(1 0 0)-2 × 1: Comparison of monomer and dimer adsorption
22. Interaction of C6 cyclic hydrocarbons with a Si(1 0 0)-2 × 1 surface: Adsorption and hydrogenation reactions
23. Stereoselectivity in molecule-surface reactions: Adsorption of ethylene on the Si(0 0 1) surface
24. Formation of ordered, anisotropic organic monolayers on the Si(0 0 1) surface
25. Structure and bonding of ordered organic monolayers of 1,5-cyclooctadiene on the Si(1 0 0) surface
26. Cycloaddition chemistry of 1,3-dienes on the silicon(0 0 1) surface: Competition between [4 + 2] and [2 + 2] reactions
27. Cycloaddition chemistry and formation of ordered organic monolayers on silicon(0 0 1) surfaces
28. Structure and bonding of ordered organic monolayers of 1,3,5,7-cyclooctatetraene on the Si(0 0 1) surface: Surface cycloaddition chemistry of an antiaromatic molecule
29. Multiple bonding geometries and binding state conversion of benzene/Si(1 0 0)
30. Determination of the absolute chirality of individual molecules using the scanning tunneling microscope
31. Asymmetric induction at a silicon surface
32. Electronic structure of benzene adsorbed on single-domain Si(0 0 1)-2 × 1: A combined experimental and theoretical study
33. Metastable adsorption of benzene on the Si(0 0 1) surface
34. Geometrical structure of benzene absorbed on Si(0 0 1)
35. Scanning tunneling microscopy study of benzene adsorption on Si(1 0 0)-2 × 1
36. Ultrahigh-vacuum scanning tunneling microscope-based nanolithography and selective chemistry on silicon surfaces
37. Nanopatterning organic monolayers on Si(1 0 0) by selective chemisorption of norbornadiene
38. 4 on Si(1 0 0)(2 × 1)
39. Adsorption of ethylene on the Si(1 0 0)-2 × 1 surface
40. Adsorption and thermal behavior of ethylene on Si(1 0 0)-(2 × 1)
41. Coadsorption of hydrogen with ethylene and acetylene on Si(1 0 0)-(2 × 1)
42. 4 chemisorbed on Si(1 0 0) reveals a new bonding configuration
43. Theoretical study of the adsorption of acetylene on the Si(1 0 0) surface
44. Adsorption of ethylene on the Ge(1 0 0)-2 × 1 surface: Coverage and time-dependent behavior
45. Evidence for a retro-Diels-Alder reaction on a single crystalline surface: Butadienes on Ge(1 0 0)
46. Scanning tunneling microscopy of organic molecules and monolayers on silicon and germanium (0 0 1) surfaces
47. Reaction of 1,3-cyclohexadiene with the Ge(1 0 0) surface
48. Functionalization of diamond(1 0 0) by Diels-Alder chemistry
49. Cycloaddition chemistry at surfaces: Reaction of alkenes with the diamond(0 0 1)-2 × 1 surface
50. Diels-Alder reaction on the clean diamond(1 0 0) 2 × 1 surface
51. Reaction chemistry at the Si(1 0 0) surface-control through active-site manipulation
52. The adsorption and thermal-decomposition of acetylene on Si(1 0 0) and vicinal Si(1 0 0)9-degrees
53. The adsorbed states of ethylene on Si(1 0 0)c(4 × 2), Si(1 0 0)(2 × 1), and vicinal Si(1 0 0): Electron energy loss spectroscopy and low-energy electron diffraction studies
54. 4 on Si(1 0 0)
55. Adsorption and decomposition of acetylene on Si(1 0 0)-(2 × 1)
56. The bare and acetylene chemisorbed Si(1 0 0) surface, and the mechanism of acetylene chemisorption
57. Structures of small hydrocarbons adsorbed on Si(0 0 1) and Si terminated Beta-SiC(0 0 1)
58. Hydrocarbon Adsorption on Si(0 0 1): When does the Si dimer bond break?
59. First-principles study of the structural and electronic properties of ethylene adsorption on Si(1 0 0)-(2 × 1) surface
60. Structure of chemisorbed acetylene on the Si(0 0 1)-(2 × 1) surface and the effect of coadsorbed atomic hydrogen
61. How stereoselective are alkene addition reactions on Si(1 0 0)?
62. High-speed Si/SiGe technology for next generation wireless system applications
63. Silicon:germanium-based mixed-signal technology for technology for optimization of wired and wireless telecommunications
64. Tunneling microscopy of Ge(0 0 1)
65. High resolution infrared spectroscopy of adsorbates on semiconductor surfaces: Hydrogen on Si(1 0 0) and Ge(1 0 0)
66. The structure of the Ge(0 0 1)-(2 × 1) reconstruction investigated with X-ray diffraction
67. HREELS and LEED of H/C(1 0 0): The 2 × 1 monohydride dimer row reconstruction
68. Surface state transitions on the reconstructed diamond C(1 0 0) surface
69. Functionalization of diamond(1 0 0) by cycloaddition of butadiene: First-principles theory
70. Alkyl monolayers covalently bonded to silicon surfaces
71. Alkyl monolayers on silicon prepared from 1-alkenes and hydrogen-terminated silicon
72. Lewis acid mediated functionalization of porous silicon with substituted alkenes and alkynes
73. Lewis acid mediated hydrosilylation on porous silicon surfaces
74. Alkylation of Si surfaces using a two-step halogenation/Grignard route
75. Functionalization of nanocrystalline porous silicon surfaces with aryllithium reagents: Formation of silicon-carbon bonds by cleavage of silicon-silicon bonds
76. Derivatization of porous silicon by grignard reagents at room temperature
77. Improved polypyrrole/silicon junctions by surfacial modification of hydrogen-terminated silicon using organolithium reagents
78. Olefin additions on H-Si(1 1 1): Evidence for a surface chain reaction initiated at isolated dangling bonds
79. Atomic-scale desorption through electronic and vibrational excitation mechanisms
80. Breaking individual chemical bonds via STM-induced excitations
81. Self-directed growth of molecular nanostructures on Si(1 0 0)
82. Determination of the bonding of alkyl monolayers to the Si(1 1 1) surface using chemical-shift, scanned-energy photoelectron diffraction
83. Alkyl-terminated Si(1 1 1) surfaces: A high-resolution core-level photoelectron spectroscopy study
84. Photopatterned hydrosilylation on porous silicon
85. Electronically configurable molecular-based logic gates
86. Biological surface engineering: A simple system for cell pattern formation
87. Surface micropatterning to regulate cell functions
88. Growth cone guidance and neuron morphology on micropatterned laminim surfaces
89. Aligned microcontact printing of micrometer-scale poly-L-lysine structures for controlled growth of cultured neurons on planar microelectrode arrays
90. Route for controlled growth of ultrathin polyimide films with Si-C bonding to Si(1 0 0)-2 × 1