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Volumn 11, Issue 1, 1999, Pages 55-61

Nanoelectrochemical patterning of monolayer surfaces: toward spatially defined self-assembly of nanostructures

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; ELECTROCHEMISTRY; MONOLAYERS; NANOTECHNOLOGY; OXIDATION; SURFACE STRUCTURE;

EID: 0033531053     PISSN: 09359648     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-4095(199901)11:1<55::AID-ADMA55>3.0.CO;2-8     Document Type: Article
Times cited : (249)

References (84)
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    • For the combined use of topographic and friction scanning-probe modes in the imaging of organic monolayers, see a) E. Meyer, R. Overney, R. Lüthi, D. Brodbeck, L. Howald, J. Frommer, H.-J, Güntherodt, O. Wolter, M. Fujihira, H. Takano, Y. Gotoh, Thin Solid Films 1992, 220, 132. b) S. Jacobi, L. F. Chi, H. Fuchs, J. Vac. Sci. Technol. B 1996, 14, 1503. c) J. Fang, C. M. Knobler, Langmuir 1996, 12, 1368.
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    • The imaging of these chemically patterned surfaces was done by Dr. Sophie Matlis, Chemical Services Unit, The Weizmann Institute of Science
    • The imaging of these chemically patterned surfaces was done by Dr. Sophie Matlis, Chemical Services Unit, The Weizmann Institute of Science.
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    • Note the reversal of the hydrophilic-hydrophobic character of the two surface regions on going from operation 2 to operation 4 (Fig. 2).
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    • The role of atmospheric humidity in this tip-induced surface oxidation (by analogy with previously reported processes of scanning-probe anodization [26,33]) remains to be elucidated
    • The role of atmospheric humidity in this tip-induced surface oxidation (by analogy with previously reported processes of scanning-probe anodization [26,33]) remains to be elucidated.
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    • eo generated in this manner appears to be the enolate of a hydroxy carbonyl (ketone/aldehyde) species. Examples of some related enolic carbonyls may be found in a) S. Forsén, M. Nilsson, in The Chemistry of the Carbonyl Group, Vol. 2 (Ed: J. Zabicky), Interscience Publishers, London 1970, p. 228. b) S. Wolfe, C. F. Ingold, R. U. Lemieux, J. Am. Chem. Soc. 1981, 103, 938. c) B. E. Hanson, L. F. Wieserman, G. W. Wagner, R. A. Kaufman, Langmuir 1987, 3, 549. d) L. J. Bellamy, R. F. Branch, J. Chém. Soc. 1954, 4491.
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    • eo generated in this manner appears to be the enolate of a hydroxy carbonyl (ketone/aldehyde) species. Examples of some related enolic carbonyls may be found in a) S. Forsén, M. Nilsson, in The Chemistry of the Carbonyl Group, Vol. 2 (Ed: J. Zabicky), Interscience Publishers, London 1970, p. 228. b) S. Wolfe, C, F. Ingold, R. U. Lemieux, J. Am. Chem. Soc. 1981, 103, 938. c) B. E. Hanson, L. F. Wieserman, G. W. Wagner, R. A. Kaufman, Langmuir 1987, 3, 549. d) L. J. Bellamy, R. F. Branch, J. Chém. Soc. 1954, 4491.
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    • eo generated in this manner appears to be the enolate of a hydroxy carbonyl (ketone/aldehyde) species. Examples of some related enolic carbonyls may be found in a) S. Forsén, M. Nilsson, in The Chemistry of the Carbonyl Group, Vol. 2 (Ed: J. Zabicky), Interscience Publishers, London 1970, p. 228. b) S. Wolfe, C, F. Ingold, R. U. Lemieux, J. Am. Chem. Soc. 1981, 103, 938. c) B. E. Hanson, L. F. Wieserman, G. W. Wagner, R. A. Kaufman, Langmuir 1987, 3, 549. d) L. J. Bellamy, R. F. Branch, J. Chém. Soc. 1954, 4491.
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    • Attempts to adsorb a top OTS monolayer on such surfaces resulted in the apparent growth of irregular multilayer islands, possibly because of heavy hydration of the uncovered silicon oxide patches.
    • Attempts to adsorb a top OTS monolayer on such surfaces resulted in the apparent growth of irregular multilayer islands, possibly because of heavy hydration of the uncovered silicon oxide patches.


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