Rough surfaces by design: Gold colloids tethered to gold surfaces as substrates for CaCO3 crystallization

Advanced Materials

Volumn 10, Issue 5, 1998, Pages 401-404

  Küther, Jörg ^a   Seshadri, Ram ^a   Nelles, Gabriele ^a   Butt, Hans Jürgen ^a   Knoll, Wolfgang ^b   Tremel, Wolfgang ^a  

^a JOHANNES GUTENBERG UNIVERSITY   (Germany)

^b MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC FORCE MICROSCOPY; CALCITE; COLLOIDS; CRYSTAL GROWTH; CRYSTALLIZATION; MONOLAYERS; SCANNING ELECTRON MICROSCOPY; SUBSTRATES; SURFACE ROUGHNESS; SURFACE TREATMENT;

BIOMINERALS; SELF ASSEMBLED MONOLAYERS;

GOLD;

EID: 0042597739     PISSN: 09359648     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-4095(199803)10:5<401::AID-ADMA401>3.0.CO;2-T     Document Type: Article

References (29)

1. Two recent examples: a) G. Schmid, G. L. Hornyak, Curr. Opin. Solid State Mater. Sci. 1997, 2, 204. b) G. Schmid, S. Peschel, T. Sawitowski, Z. Anorg. Allg. Chem. 1997, 623, 719.
2. Two recent examples: a) G. Schmid, G. L. Hornyak, Curr. Opin. Solid State Mater. Sci. 1997, 2, 204. b) G. Schmid, S. Peschel, T. Sawitowski, Z. Anorg. Allg. Chem. 1997, 623, 719.
3. J. G. A. Dubois, J. W. Gerrittsen, S. E. Shafranjuk, E. F. G. Boon, G. Schmid, H. Van Kempen, Europhys. Lett. 1996, 33, 279.
4. M. Dorogi, J. Gomez, R. G. Osifchin, R. P. Andres, R. Reifenberger, Phys. Rev. B 1995, 52, 9071.
5. R. P. Andres, J. D. Beilefeld, J. I. Henderson, D. B. Janes, V. R. Kolagunta, C. R. Kubiak, W. J. Mahoney, R. G. Osifchin, Science 1996, 273, 1690.
6. M. D. Musick, C. D. Keating, M. H. Keefe, M. J. Natan, Chem. Mater. 1997, 9, 1499.
7. J. I. Henderson, S. Feng, G. M. Ferrence, T. Bein, C. P. Kubiak, Inorg. Chim. Acta 1996, 242, 115.
8. T. Sato, D. Brown, B. F. G. Johnson, Chem. Commun. 1997, 1007.
9. T. Vossmeyer, E. DeIonno, J. R. Heath, Angew. Chem. 1997, 109, 1123; Angew. Chem. Int. Ed. Engl. 1997, 36, 1080.
10. T. Vossmeyer, E. DeIonno, J. R. Heath, Angew. Chem. 1997, 109, 1123; Angew. Chem. Int. Ed. Engl. 1997, 36, 1080.
11. J. Israelachvili, Intermolecular and Surface Forces, Academic Press, London 1992.
12. C. J. Adkins, in Metal-Insulator Transitions Revisited (Eds: P. P. Edwards, C. N. R. Rao), Taylor and Francis, London 1995, pp. 191-210.
13. W. P. Halperin, Rev. Mod. Phys. 1986, 58, 533.
14. R. Seshadri, G. N. Subbanna, V. Vijayakrishnan, G. U. Kulkarni, G. Ananthakrishna, C. N. R. Rao, J. Phys. Chem. 1995, 99, 5639.
15. We do not expect the absorption spectra of the modified surfaces to exhibit features associated with their granular nature because the roughness is at a scale that is much smaller than the wavelength of light.
16. C. Odin, J. P. Aimé, Z. El Kaakour, T. Bouhacina, Surf. Sci. 1994, 317, 321.
17. a) M. Brust, M. Walker, D. Bethell, D. J. Schiffrin, R. Whyman, J. Chem. Soc., Chem. Commun. 1994, 801.
18. b) M. Brust, D. Bethell, D. J. Schiffrin, C. J. Kiely, Adv. Mater. 1995, 795.
19. R. Emch, J. Nogami, M. M. Dovek, C. A. Lang, C. F. Quate, J. Microsc. (Oxford) 1988, 152, 129.
20. Three recent examples: a) J. Küther, W. Tremel, Chem. Commun., 1997, 2029.
21. b) J. Küther, W. Tremel, Thin Solid Films, in press.
22. c) J. Küther. R. Seshadri, W. Knoll, W. Tremel, J. Mater. Chem., in press.
23. H. M. Rietveld, J. Appl. Crystallogr. 1992, 2, 65.
24. The calcite crystals are few and hidden. While they are not easily observed in the SE micrographs, they considerably influence the weight fraction as determined from profile analysis because they are dense and well formed.
25. J. L. Wray, F. Daniels, J. Am. Chem. Soc. 1957, 79, 2031.
26. D. Beruto, M. Giordani, J. Chem. Soc., Faraday Trans. 1993, 89, 2457.
27. 3 from the promotion of another since the two are complementary. Thus the effect observed here is also consistent with calcite and vaterite inhibition on the colloid-covered surface. However, the high nucleation density on the colloid-covered surface suggests that aragonite induction might be important.
28. J. Spinke, M. Liley, F. J. Schmitt, H. J. Guder, L. Angermaier, W. Knoll, J. Chem. Phys. 1993, 99, 7012.
29. XND version 1.11, J.-F. Bérar, ESRF, Grenoble, France 1996.