Photocontrolled formation of hydroxyl-bearing monolayers and multilayers

Langmuir

Volumn 12, Issue 23, 1996, Pages 5509-5511

  Collins, Rochael J ^a   Bae, In Tae ^a   Scherson, Daniel A ^a   Sukenik, Chaim N ^a,b  

^a CASE WESTERN RESERVE UNIVERSITY   (United States)

^b BAR ILAN UNIVERSITY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001767677     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la9601566     Document Type: Article

References (15)

1. Netzer, L.; Sagiv, J. A New Approach to Construction of Artificial Monolayer Assemblies. J. Am. Chem. Soc. 1983, 105, 674.
2. (b) Sagiv, J. Organized Monolayers by Adsorption. 1. Formation and Structure of Oleophobic Mixed Monolayers on Solid Surfaces. J. Am. Chem. Soc. 1980, 102, 92.
3. (c) A recent, improved, re-examination of Sagiv's "olefin to alcohol" multilayer construction approach can be found in: Heid, S.; Effenberger, F. Self-Assembled Mono- and Multilayers of Terminally Functionalized Organosilyl Compounds on Silicon Substrates. Langmuir 1996, 12, 2118-2120.
4. (a) Pomerantz, M.; Segmuller, A.; Netzer, L.; Sagiv, J. Coverage of Si by Self-Assembling Monolayers and Multilayers as Measured by IR, Wettability and X-ray Diffraction. Thin Solid Films 1985, 132, 153-162.
5. (b) Tillman, N.; Ulman, A.; Penner, T. L. Formation of Multilayers by Self-Assembly. Langmuir 1989, 5, 101.
6. For some recent examples of SAM photochemistry see: (a) Dulcey, C. S.; Georger, J. H.; Chen, M. S.; McElvany, S. W.; O'Ferrall, C. E.; Benezra, V. I.; Calvert, J. M. Photochemistry and Patterning of Self-Assembled Monolayer Films Containing Aromatic Hydrocarbon Functional Groups. Langmuir 1996, 12, 1638-1650. (b) Delamarche, E.; Sundarababu, G.; Biebuyck, H.; Michel, B.; Gerber, Ch.; Sigirist, H.; Wolf, H.; Ringsdorf, H.; Xanthopoulos, N.; Mathieu, H. J. Immobilization of Antibodies on a Photoactive Self-Assembled Monolayer on Gold. Langmuir 1996, 12, 1997-2006. (c) Rozsnyai, L. F.; Wrighton, M. S. Seletive Deposition of Conducting Polymers via Monolayer Photopatterning. Langmuir 1995, 11, 3913.
7. For some recent examples of SAM photochemistry see: (a) Dulcey, C. S.; Georger, J. H.; Chen, M. S.; McElvany, S. W.; O'Ferrall, C. E.; Benezra, V. I.; Calvert, J. M. Photochemistry and Patterning of Self-Assembled Monolayer Films Containing Aromatic Hydrocarbon Functional Groups. Langmuir 1996, 12, 1638-1650. (b) Delamarche, E.; Sundarababu, G.; Biebuyck, H.; Michel, B.; Gerber, Ch.; Sigirist, H.; Wolf, H.; Ringsdorf, H.; Xanthopoulos, N.; Mathieu, H. J. Immobilization of Antibodies on a Photoactive Self-Assembled Monolayer on Gold. Langmuir 1996, 12, 1997-2006. (c) Rozsnyai, L. F.; Wrighton, M. S. Seletive Deposition of Conducting Polymers via Monolayer Photopatterning. Langmuir 1995, 11, 3913.
8. For some recent examples of SAM photochemistry see: (a) Dulcey, C. S.; Georger, J. H.; Chen, M. S.; McElvany, S. W.; O'Ferrall, C. E.; Benezra, V. I.; Calvert, J. M. Photochemistry and Patterning of Self-Assembled Monolayer Films Containing Aromatic Hydrocarbon Functional Groups. Langmuir 1996, 12, 1638-1650. (b) Delamarche, E.; Sundarababu, G.; Biebuyck, H.; Michel, B.; Gerber, Ch.; Sigirist, H.; Wolf, H.; Ringsdorf, H.; Xanthopoulos, N.; Mathieu, H. J. Immobilization of Antibodies on a Photoactive Self-Assembled Monolayer on Gold. Langmuir 1996, 12, 1997-2006. (c) Rozsnyai, L. F.; Wrighton, M. S. Seletive Deposition of Conducting Polymers via Monolayer Photopatterning. Langmuir 1995, 11, 3913.
9. Balachander, N.; Sukenik, C. N. Monolayer Transformation by Nucleophilic Substitution. Langmuir 1990, 6, 1621.
10. Bertilsson, L.; Liedberg, L. Infrared Study of Thiol Monolayer Assemblies on Gold: Preparation, Characterization, and Functionalization of Mixed Monolayers. Langmuir 1993, 9, 141.
11. Analogous to that described in: Cheng, S. S.; Scherson, D. A.; Sukenik, C. N. In Situ FTIR-ATR Spectroscopy of Carboxylate-Bearing, Siloxane-Anchored, Self-Assembled Monolayers: A Study of Carboxylate Reactivity and Acid-Base Properties. Langmuir 1995, 11, 1190-1195.
12. Binkley, R. W.; Koholic, D. J. Photolysis of Nitrate Esters. Photochemically Initiated Inversion of Configuration. J. Org. Chem. 1979, 44, 2047.
13. Octyl nitrate was prepared from octyl bromide as described above for ω-hexadecenyl nitrate. Photolyses were done on 2.8 mM solutions in HPLC grade isopropyl alcohol. Analyses were done using a HP-Model 5890-5971A GC-MS using a 12 m HP1 (methylsilicone) capillary column and using hexadecane as an internal standard.
14. 3. The water contact angle of this sample remained unchanged and analysis by XPS showed the nitrate N(1s) signal at 408 eV and no signal in the P(1s) region.
15. Lopez, G. P.; Biebuyck, H. A.; Whitesides, G. M. Scanning Electron Microscopy Can Form Images of Patterns in Self-Assembled Monolayers. Langmuir 1993, 9, 1513.