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5344223930
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note
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Values of 200-300 W for the X-ray source power, operated at source-sample distances smaller than that used in the present study, are common. See for example refs 5, 7, 9, 10, 17, 20, 21, 24, 25, and 29.
-
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42
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2842607626
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5344251537
-
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note
-
Assuming that all paraffinic tails of an ordered monolayer are perpendicular to the substrate surface and that the C-H bonds are parallel to it with random in-plane orientation, half of the C-H bonds should be statistically available for interaction with the electric field of the incoming IR beam in the normal incidence geometry. Upon three-dimensional randomization of the paraffinic tails, 1/3 of the C-H bonds will point in the direction of propagation of the IR beam, so that the measured absorbance should decrease by a factor of 2/3 compared to that of a perfectly ordered monolayer.
-
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44
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0003168767
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85088542657
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note
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34 can interact with the out-of-plane C-H vibrations of disordered paraffinic tails, which is not possible in the case of a perfectly ordered monolayer where all C-H vibrations are parallel to the layer plane.
-
-
-
-
47
-
-
5344233918
-
-
note
-
-1) upon adsorption of a compact monolayer of the latter.
-
-
-
-
49
-
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0002662629
-
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36,42 depend on the refractive index of each of the respective substrates (see, for example: Umemura, J.; Kamata, T.; Kawai, T.; Takenaka, T. J. Phys. Chem. 1990, 94, 62).
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50
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85088543377
-
-
note
-
2+ carboxylate salt (see also refs 42 and 45).
-
-
-
-
52
-
-
5344233275
-
-
note
-
The intensity of the XPS carbon line arising from the carboxylic carbon is lower than its expected stoichiometric contribution (5%, i.e. one out of the 20 carbon atoms of the AA molecule) because of the COOH groups' location at the monolayer-substrate interface and the consequent attenuation of the carboxyl carbon signal by the monolayer hydrocarbon core extending away from this interface. Since the expected decrease in thickness of the depleted monolayer following irradiation should cause a relative enhancement of the XPS signals contributed by bottom-located atoms, the actual loss of carboxylic carbon may be even somewhat larger than that directly deduced from the experimental data.
-
-
-
-
56
-
-
85088544601
-
-
note
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34 with the ZnSe surface.
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57
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0029855348
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59
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5344230555
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note
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2 groups, which take place in the film without a net loss of material from the surface or major degradation of its hydrocarbon core.
-
-
-
-
60
-
-
85088541975
-
-
note
-
7
-
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63
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33751155891
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64
-
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5344231934
-
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note
-
9 might also be strongly influenced by surface-charging effects.
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-
-
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