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4243108049
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note
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-1 in a bulk solid spectrum in KBr. Possible explanations are that this mode would be nearly parallel to the surface and hence forbidden by surface selection rules or that the thiols oxidized to disulfides when the sample was transferred from the inert atmosphere where the SAMs were prepared to the RAIR chamber.
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4243160548
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note
-
In making this estimate, we assumed a dielectric constant for the XYL dithiol of 1.5.
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27
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4243101342
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-
note
-
This research was funded in part by the Army Research Office under grant DAAL03-G-0144. S.F. and J.I.H. acknowledge Purdue Research Foundation graduate fellowships. T.B., R.P.A., and R.R. received funding from the National Science Foundation. The visit of J. Gomez from Universidad Autonoma de Madrid proved pivotal in acquiring reliable l(V,z) data. We also thank S. Datta and D. Janes for many useful discussions and T. Henderson for preparing figures.
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