Catalyst-Directed Diastereoselective Isomerization of Allylic Alcohols for the Stereoselective Construction of C(20) in Steroid Side Chains: Scope and Topological Diversification

Journal of the American Chemical Society

Volumn 137, Issue 33, 2015, Pages 10720-10727

  Li, Houhua ^a   Mazet, Clément ^a  

^a UNIVERSITY OF GENEVA   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CHAINS; CHEMICAL REACTIONS; IRIDIUM; ISOMERIZATION; ISOMERS; REACTION INTERMEDIATES; SCAFFOLDS; SULFUR COMPOUNDS; TOPOLOGY;

DIASTEREOSELECTIVE; DIASTEREOSELECTIVITIES; NEGISHI CROSS-COUPLING; OPTIMIZED REACTION CONDITIONS; STEREOSELECTIVE CONSTRUCTION; STEROID SCAFFOLDS; STRUCTURAL ANALOGUE; STRUCTURAL DIVERSITY;

STEREOSELECTIVITY;

ALCOHOL DERIVATIVE; ALDEHYDE; IRIDIUM; IRIDIUM COMPLEX; PREGNENOLONE; STEROID; ALLYL ALCOHOL; CARBON; PROPANOL;

ANTINEOPLASTIC ACTIVITY; ARTICLE; BIOLOGICAL ACTIVITY; CATALYST; CROSS COUPLING REACTION; CRYSTAL STRUCTURE; CYCLOADDITION; DESILYLATION; ELECTRON; HUMAN; ISOMERIZATION; MEDICINE; STEREOCHEMISTRY; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; STEREOISOMERISM;

CARBON; CATALYSIS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PROPANOLS; STEREOISOMERISM; STEROIDS;

EID: 84941653827     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b06281     Document Type: Article

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