Enantioselective palladium-catalyzed dearomative cyclization for the efficient synthesis of terpenes and steroids

Angewandte Chemie - International Edition

Volumn 54, Issue 10, 2015, Pages 3033-3037

  Du, Kang ^a   Guo, Pan ^a   Chen, Yuan ^a   Cao, Zhen ^a   Wang, Zheng ^b   Tang, Wenjun ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b ASTRAZENECA   (United Kingdom)

Author keywords

Asymmetric cyclization; Palladium; Phosphine ligands; Total synthesis; Transition metal catalysis

Indexed keywords

CATALYSIS; CHELATION; ENANTIOSELECTIVITY; LIGANDS; LIPIDS; ORGANIC COMPOUNDS; PALLADIUM; PHOSPHORUS COMPOUNDS; SYNTHESIS (CHEMICAL); TERPENES; TRANSITION METALS;

EFFICIENT CONSTRUCTION; EFFICIENT SYNTHESIS; ENANTIOSELECTIVE TOTAL SYNTHESIS; PALLADIUM-CATALYZED; PHOSPHINE LIGANDS; QUATERNARY CENTERS; TOTAL SYNTHESIS; TRANSITION METAL CATALYSIS;

CYCLIZATION;

PALLADIUM; STEROID; TERPENE;

CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; STEREOISOMERISM; SYNTHESIS;

CATALYSIS; CYCLIZATION; MODELS, MOLECULAR; PALLADIUM; STEREOISOMERISM; STEROIDS; TERPENES;

EID: 84923354484     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201411817     Document Type: Article

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