메뉴 건너뛰기




Volumn 32, Issue 22, 2013, Pages 6804-6811

A tris(triphenylphosphine)aluminum ambiphilic precatalyst for the reduction of carbon dioxide with catecholborane

Author keywords

[No Author keywords available]

Indexed keywords

CATECHOLATE; FRUSTRATED LEWIS PAIRS; PRECATALYSTS; REACTION MIXTURE; REDUCTION CATALYST; REDUCTION OF CO; TRIPHENYL PHOSPHINES;

EID: 84888624717     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om400645s     Document Type: Article
Times cited : (108)

References (101)
  • 93
    • 4444304979 scopus 로고    scopus 로고
    • One reviewer raises the point that such coupling could arise from long-range through-space coupling rather than scalar coupling. This possibility was considered and cannot be excluded, but several observations go against it. First, the low symmetry of 3 in the optimized structure (P1-P2 and P2 - P3 bond lengths of 4.39 and 5.03 Å respectively) would suggest a different coupling constant between the phosphorus atoms. Also, long-range coupling would be possible if electronic communication between the nuclei is present, but we did not observe any orbital suggesting that the three phosphorus atoms are able to communicate through space. See
    • One reviewer raises the point that such coupling could arise from long-range through-space coupling rather than scalar coupling. This possibility was considered and cannot be excluded, but several observations go against it. First, the low symmetry of 3 in the optimized structure (P1-P2 and P2 - P3 bond lengths of 4.39 and 5.03 Å, respectively) would suggest a different coupling constant between the phosphorus atoms. Also, long-range coupling would be possible if electronic communication between the nuclei is present, but we did not observe any orbital suggesting that the three phosphorus atoms are able to communicate through space. See: Hierso, J.-C.; Fihri, A.; Ivanov, V. V.; Hanquet, B.; Pirio, N.; Donnadieu, B.; Rebière, B.; Amardeil, R.; Meunier, P. J. Am. Chem. Soc. 2004, 126, 11077-11087
    • (2004) J. Am. Chem. Soc. , vol.126 , pp. 11077-11087
    • Hierso, J.-C.1    Fihri, A.2    Ivanov, V.V.3    Hanquet, B.4    Pirio, N.5    Donnadieu, B.6    Rebière, B.7    Amardeil, R.8    Meunier, P.9
  • 97
    • 84888620016 scopus 로고    scopus 로고
    • Bruker AXS Inc. Madison, WI.
    • APEX2; Bruker AXS Inc., Madison, WI, 2007.
    • (2007) APEX2
  • 98
    • 84888604998 scopus 로고    scopus 로고
    • Bruker AXS Inc. Madison, WI.
    • SAINT; Bruker AXS Inc., Madison, WI, 2007.
    • (2007) SAINT
  • 99
    • 34547259244 scopus 로고    scopus 로고
    • Bruker AXS Inc. Madison, WI.
    • Sheldrick, G. M. SADABS; Bruker AXS Inc., Madison, WI, 2007.
    • (2007) SADABS
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.