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This chemical shift suggests some degree of P→In interaction, something that is supported computationally. A closed form featuring a short P→In contact (2.827 Å) is found as the global energy minimum. (17)
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This chemical shift suggests some degree of P→In interaction, something that is supported computationally. A closed form featuring a short P→In contact (2.827 Å) is found as the global energy minimum. (17)
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53
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79951887685
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See the Supporting Information for details
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See the Supporting Information for details.
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54
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79951873536
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3 clusters. (2f, 2g)
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3 clusters. (2f, 2g)
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56-Due to its larger size compared to that of boron, indium may not accommodate the pyramidalized environment observed in the related triphosphine-borane palladium complex (-(CBC) = 341.8°). (9)
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Due to its larger size compared to that of boron, indium may not accommodate the pyramidalized environment observed in the related triphosphine-borane palladium complex (-(CBC) = 341.8°). (9)
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57
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