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73
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57549111324
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The essentially pure σ-donor character of the phosphine buttresses (compared with the σ- and π-basic character of imazolyl ligands) allows for a clear unambiguous focus on σ-effects in the complexes deriving from TPB
-
The essentially pure σ-donor character of the phosphine buttresses (compared with the σ- and π-basic character of imazolyl ligands) allows for a clear unambiguous focus on σ-effects in the complexes deriving from TPB.
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75
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57549089725
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See Supporting Information
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See Supporting Information.
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76
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57549118032
-
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8,9
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8,9
-
-
-
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77
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0141507877
-
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This parameter has been introduced to quantify the chiral twist in C3-symmetric complexes of hydrotris(imazolyl)borate ligands: Foreman, M. R. St.-J, Hill, A. F, White, A. J. P, Williams, D. J. Organometallics 2003, 22, 3831-3840
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3-symmetric complexes of hydrotris(imazolyl)borate ligands: Foreman, M. R. St.-J.; Hill, A. F.; White, A. J. P.; Williams, D. J. Organometallics 2003, 22, 3831-3840.
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Brown, N.M.D.1
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80
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57549113746
-
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According to Cambridge Database searches, the CuCl (resp. AgCl) bond length in tris(phosphine) complexes range from 2.28 to 2.38 Å (resp. 2.47 to 2.59 Å).
-
According to Cambridge Database searches, the CuCl (resp. AgCl) bond length in tris(phosphine) complexes range from 2.28 to 2.38 Å (resp. 2.47 to 2.59 Å).
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82
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85153021708
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3 CuCl] (R = tBu, iPr): Sue, T.; Sunada, Y.; Nagashima, H. Eur. J. Inorg. Chem. 2007, 2897-2908.
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3 CuCl] (R = tBu, iPr): Sue, T.; Sunada, Y.; Nagashima, H. Eur. J. Inorg. Chem. 2007, 2897-2908.
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83
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29044433052
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For recent experimental and theoretical investigations on boryl complexes of group 11 metals, see: a
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For recent experimental and theoretical investigations on boryl complexes of group 11 metals, see: (a) Laitar, D. S.; Müller, P.; Sadighi, J. P. J. Am. Chem. Soc. 2005, 127, 17196-17197.
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34249931967
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34548646273
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84961980701
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(h) Dang, L.; Zhao, H.; Lin, Z.; Marder, T. B. J. Am. Chem. Soc. 2008, 130, 5586-5594.
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Dang, L.1
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(i) Dang, L.; Lin, Z.; Marder, T. B. Organometallics 2008, 27, 4443-4454.
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43749110500
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Cordero, B.; Gómez, V.; Pletro-Prats, A. E.; Revés, M.; Echeverría, J.; Cremades, E.; Barragán, F.; Alvarez, S. Dalton Trans. 2008, 2832-2838.
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Cordero, B.1
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93
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57549084681
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20
-
20
-
-
-
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94
-
-
57549083691
-
-
NBO calculations deleting the identified M→B interaction led to energy contributions of 59 kcal mol-1 Ni, Pt
-
-1 (Pt).
-
-1
-
-
-
95
-
-
34249939356
-
-
A similar trend (3d,5d > 4d) is observed in π-backdonation within carbonyl complexes: Hocking, R. K.; Hambley, T. W Organometallics 2007, 26, 2815-2823.
-
A similar trend (3d,5d > 4d) is observed in π-backdonation within carbonyl complexes: Hocking, R. K.; Hambley, T. W Organometallics 2007, 26, 2815-2823.
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-
-
-
98
-
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34548257293
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Pd is known to form boryl complexes significantly less stable than those with Pt: (a) Braunschweig, H.; Radacki, K.; Rais, D.; Schneider, A.; Seeler, F. J. Am. Chem. Soc. 2007, 129, 10350-10351.
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Pd is known to form boryl complexes significantly less stable than those with Pt: (a) Braunschweig, H.; Radacki, K.; Rais, D.; Schneider, A.; Seeler, F. J. Am. Chem. Soc. 2007, 129, 10350-10351.
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99
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45749111403
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(b) Braunschweig, H.; Gruss, K.; Radacki, K.; Uttinger, K. Eur. J. Inorg. Chem. 2008, 1462-1466.
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Braunschweig, H.1
Gruss, K.2
Radacki, K.3
Uttinger, K.4
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100
-
-
57549086303
-
-
-1 (AuCl).
-
-1 (AuCl).
-
-
-
-
101
-
-
4544365854
-
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For recent reviews on gold chemistry, see: a
-
For recent reviews on gold chemistry, see: (a) Pyykkö, P. Angew. Chem., Int. Ed. 2004, 43, 4412-4456.
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Pyykkö, P.1
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14544273229
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(b) Schmidbaur, H.; Cronje, S.; Djordjevic, B.; Schuster, O. Chem. Phys. 2005, 311, 151-161.
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Schmidbaur, H.1
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Schuster, O.4
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103
-
-
57549116928
-
-
2, in which Z is the full nuclear charge.
-
2, in which Z is the full nuclear charge.
-
-
-
-
104
-
-
0000394187
-
-
2 compared to the related Cr and Mo complexes: Jacobsen, H.; Ziegler, T. Inorg. Chem. 1996, 35, 775-783.
-
2 compared to the related Cr and Mo complexes: Jacobsen, H.; Ziegler, T. Inorg. Chem. 1996, 35, 775-783.
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-
-
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105
-
-
57549100668
-
-
-1.
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-1.
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-
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106
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-
0001469721
-
-
For leading reviews, see: a
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For leading reviews, see: (a) Keyes, M. C.; Tolman, W. B. Adv. Catal. Processes 1997, 2, 189-219.
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Keyes, M.C.1
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110
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33750147845
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3X-type triphosphine ligands, see: (a) Siclosi, M.; Llort, J.; Estevan, F.; Lahuerta, P.; Sanau, M.; Pérez-Prieto, J. Angew. Chem., Int. Ed. 2006, 45, 6741-6744.
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3X-type triphosphine ligands, see: (a) Siclosi, M.; Llort, J.; Estevan, F.; Lahuerta, P.; Sanau, M.; Pérez-Prieto, J. Angew. Chem., Int. Ed. 2006, 45, 6741-6744.
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34547470503
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(b) Mankad, N. P.; Whited, M. T.; Peters, J. C. Angew. Chem., Int. Ed. 2007, 46, 5768-5771.
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Mankad, N.P.1
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28844445644
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Bailey, P. J.; Dawson, A.; McCormack, C.; Moggach, S. A.; Oswald, I. D. H.; Parsons, S.; Rankin, D. W. H.; Turner, A. Inorg. Chem. 2005, 44, 8884-8898.
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Bailey, P.J.1
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Turner, A.8
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