-
1
-
-
38149134253
-
-
For general reviews dealing with transition-metal complexes of Group 13 elements, see: a H. Wadepohl, Angew. Chem. 1997, 109, 2547-2550;
-
For general reviews dealing with transition-metal complexes of Group 13 elements, see: a) H. Wadepohl, Angew. Chem. 1997, 109, 2547-2550;
-
-
-
-
2
-
-
0031470418
-
-
Angew. Chem. Int. Ed. 1997, 36, 2441-2444;
-
(1997)
Angew. Chem. Int. Ed
, vol.36
, pp. 2441-2444
-
-
-
4
-
-
0032479754
-
-
Angew. Chem. Int. Ed. 1998, 37, 1786-1801;
-
(1998)
Angew. Chem. Int. Ed
, vol.37
, pp. 1786-1801
-
-
-
5
-
-
0001008441
-
-
c) G. J. Irvine, M.J. Lesley, T. B. Marder, N. C. Norman, C. R. Rice. E. G. Robins, W R. Roper, G. R. Whittell, L.J. Wright, Chem. Rev. 1998, 98, 2685-2722;
-
(1998)
Chem. Rev
, vol.98
, pp. 2685-2722
-
-
Irvine, G.J.1
Lesley, M.J.2
Marder, T.B.3
Norman, N.C.4
Rice, C.R.5
Robins, E.G.6
Roper, W.R.7
Whittell, G.R.8
Wright, L.J.9
-
7
-
-
0344603834
-
-
Angew. Chem. Int. Ed. 1999, 38, 2830-2850;
-
(1999)
Angew. Chem. Int. Ed
, vol.38
, pp. 2830-2850
-
-
-
14
-
-
33747883138
-
-
Angew. Chem. Int. Ed. 2006, 45, 5254-5274.
-
(2006)
Angew. Chem. Int. Ed
, vol.45
, pp. 5254-5274
-
-
-
15
-
-
33845559671
-
-
a) J. M. Burlitch, M. E. Leonowicz, R. B. Petersen, R. E. Hughes. Inorg. Chem. 1979, 18, 1097-1105;
-
(1979)
Inorg. Chem
, vol.18
, pp. 1097-1105
-
-
Burlitch, J.M.1
Leonowicz, M.E.2
Petersen, R.B.3
Hughes, R.E.4
-
17
-
-
35348984066
-
-
Angew. Chem. Int. Ed. 2007, 46, 7782-7784.
-
(2007)
Angew. Chem. Int. Ed
, vol.46
, pp. 7782-7784
-
-
-
18
-
-
0032515440
-
-
J. T. Golden. T. H. Peterson, P. L. Holland. R. G. Bergman. R. A. Andersen. J. Am. Chem. Soc. 1998, 120, 223-224.
-
(1998)
J. Am. Chem. Soc
, vol.120
, pp. 223-224
-
-
Golden, J.T.1
Peterson, T.H.2
Holland, P.L.3
Bergman, R.G.4
Andersen, R.A.5
-
19
-
-
0001541297
-
-
The borane analogue of complex A has only been spectroscopically characterized: J. M. Burlitch. J. H. Burk. M. E. Leonowicz. R. E. Hughes. Inorg. Chem. 1979, 18, 1702-1709.
-
The borane analogue of complex A has only been spectroscopically characterized: J. M. Burlitch. J. H. Burk. M. E. Leonowicz. R. E. Hughes. Inorg. Chem. 1979, 18, 1702-1709.
-
-
-
-
20
-
-
0003207633
-
-
Early claims for transition metal-borane complexes a D. F. Shriver. J. Am. Chem. Soc. 1963, 85, 3509-3510:
-
Early claims for transition metal-borane complexes a) D. F. Shriver. J. Am. Chem. Soc. 1963, 85, 3509-3510:
-
-
-
-
22
-
-
33947336070
-
-
were not supported by structural authentication and their real identity has been strongly questioned by Braunschweig et al
-
c) M. P. Johnson, D. F. Shriver. J. Am. Chem. Soc. 1966, 88, 301-304 were not supported by structural authentication and their real identity has been strongly questioned by Braunschweig et al.
-
(1966)
J. Am. Chem. Soc
, vol.88
, pp. 301-304
-
-
Johnson, M.P.1
Shriver, D.F.2
-
25
-
-
0038928798
-
-
H. Braunschweig.C.Kollann. Z. Naturforsch. B 1999, 54, 839-842.
-
f) H. Braunschweig.C.Kollann. Z. Naturforsch. B 1999, 54, 839-842.
-
-
-
-
26
-
-
0003129061
-
-
A. F. Hill, G. R. Owen, A. J. P. White, D. J. Williams, Angew. Chem. 1999, 111, 2920-2923;
-
(1999)
Angew. Chem
, vol.111
, pp. 2920-2923
-
-
Hill, A.F.1
Owen, G.R.2
White, A.J.P.3
Williams, D.J.4
-
27
-
-
0033578646
-
-
Angew. Chem. Int. Ed. 1999, 38, 2759-2761.
-
(1999)
Angew. Chem. Int. Ed
, vol.38
, pp. 2759-2761
-
-
-
30
-
-
3042809517
-
-
c) D. J. Mihalcik. J. L. White. J. M. Tanski, L. N. Zakharov. G. P. A. Yap. C. D. Incarvito. A. L. Rheingold. D. Rabinovitch, Dalton Trans. 2004, 1626- 1634;
-
(2004)
Dalton Trans
, pp. 1626-1634
-
-
Mihalcik, D.J.1
White, J.L.2
Tanski, J.M.3
Zakharov, L.N.4
Yap, G.P.A.5
Incarvito, C.D.6
Rheingold, A.L.7
Rabinovitch, D.8
-
34
-
-
33645526008
-
-
g) V. K. Landry. J. G. Melnick. D. Buccella, K. Pang, J. C. Ulichny, G. Parkin. Inorg. Chem. 2006, 45, 2588-2597;
-
(2006)
Inorg. Chem
, vol.45
, pp. 2588-2597
-
-
Landry, V.K.1
Melnick, J.G.2
Buccella, D.3
Pang, K.4
Ulichny, J.C.5
Parkin, G.6
-
39
-
-
19944431360
-
-
Metal →boron interactions have also been proposed to account for the bent structure of metallocenylboranes. and the delocalized through-space nature of such M→B interactions has been recently established theoretically for ferrocenylboranes: see a M. Scheibitz, M. Bolte, J. W. Bats, H.-W. Lerner. I. Nowik. R. H. Herber. A. Krapp. M. Lein, M. C. Holthausen, M. Wagner. Chem. Eur. J. 2005, 11, 584-603
-
Metal →boron interactions have also been proposed to account for the bent structure of metallocenylboranes. and the delocalized through-space nature of such M→B interactions has been recently established theoretically for ferrocenylboranes: see a) M. Scheibitz, M. Bolte, J. W. Bats, H.-W. Lerner. I. Nowik. R. H. Herber. A. Krapp. M. Lein, M. C. Holthausen, M. Wagner. Chem. Eur. J. 2005, 11, 584-603:
-
-
-
-
40
-
-
33746300360
-
-
b) K. Venkatasubbaiah. L. N. Zakharov. WS. Kassel, A. L. Rheingold, F. Jäkle. Angew. Chem. 2005, 117, 5564-5569;
-
(2005)
Angew. Chem
, vol.117
, pp. 5564-5569
-
-
Venkatasubbaiah, K.1
Zakharov, L.N.2
Kassel, W.S.3
Rheingold, A.L.4
Jäkle, F.5
-
41
-
-
24644509786
-
-
and references therein
-
Angew. Chem. Int. Ed. 2005, 44, 5428-5433 and references therein.
-
(2005)
Angew. Chem. Int. Ed
, vol.44
, pp. 5428-5433
-
-
-
42
-
-
38149139971
-
-
3]: J. B. Bonanno, T. P. Henry, P. T. Wolczanski, A. W. Pierpont. T. R. Cundari, Inorg. Chem. 2001, 46, 1222-1232.
-
3]: J. B. Bonanno, T. P. Henry, P. T. Wolczanski, A. W. Pierpont. T. R. Cundari, Inorg. Chem. 2001, 46, 1222-1232.
-
-
-
-
43
-
-
24944447372
-
-
For recent examples of M→B interactions within borylene complexes and metalloborylenes. see: a
-
For recent examples of M→B interactions within borylene complexes and metalloborylenes. see: a) H. Braunschweig. D. Rais. K. Uttinger. Angew. Chem. 2005, 117, 3829-3832:
-
(2005)
Angew. Chem
, vol.117
, pp. 3829-3832
-
-
Braunschweig, H.1
Rais, D.2
Uttinger, K.3
-
44
-
-
20644455544
-
-
Angew. Chem. Int. Ed. 2005, 44, 3763-3766;
-
(2005)
Angew. Chem. Int. Ed
, vol.44
, pp. 3763-3766
-
-
-
46
-
-
33746249524
-
-
Angew. Chem. Int. Ed. 2006, 45, 1066- 1069;
-
(2006)
Angew. Chem. Int. Ed
, vol.45
, pp. 1066-1069
-
-
-
47
-
-
33750316081
-
-
c) H. Braunschweig. C. Burschka, M. Burzler, S. Metz. K. Radacki. Angew. Chem. 2006, 118, 4458-4461;
-
(2006)
Angew. Chem
, vol.118
, pp. 4458-4461
-
-
Braunschweig, H.1
Burschka, C.2
Burzler, M.3
Metz, S.4
Radacki, K.5
-
48
-
-
33746291638
-
-
Angew. Chem. Int. Ed. 2006, 45, 4352-4355.
-
(2006)
Angew. Chem. Int. Ed
, vol.45
, pp. 4352-4355
-
-
-
49
-
-
0037093986
-
-
The contribution of M→B interactions has also been pointed out in the bonding description of tantalocene-borataalkene η2-complexes a K. S. Cook. W. E. Piers. R. McDonald. J. Am. Chem. Soc. 2002, 124, 5411-5418 and references therein and of boryl-bridged complexes
-
2-complexes a) K. S. Cook. W. E. Piers. R. McDonald. J. Am. Chem. Soc. 2002, 124, 5411-5418 and references therein and of boryl-bridged complexes
-
-
-
-
51
-
-
8644269538
-
-
c) S. A. Westcott, T. B. Marder. R. T. Baker, R. L. Harlow, J. C. Calabrese. K.C.Lam. Z. Lin. Polyhedron 2004, 23, 2665-2677;
-
(2004)
Polyhedron
, vol.23
, pp. 2665-2677
-
-
Westcott, S.A.1
Marder, T.B.2
Baker, R.T.3
Harlow, R.L.4
Calabrese, J.C.5
Lam, K.C.6
Lin, Z.7
-
52
-
-
17044420518
-
-
d) H. Braunschweig. K. Radacki, D. Rais, G. R. Whittell, Angew. Chem. 2005, 117, 1217-1219
-
(2005)
Angew. Chem
, vol.117
, pp. 1217-1219
-
-
Braunschweig, H.1
Radacki, K.2
Rais, D.3
Whittell, G.R.4
-
53
-
-
34250744136
-
-
MnKPW, Chem. Int. Ed. 2005, 44, 1192-1193.
-
(2005)
Chem. Int. Ed
, vol.44
, pp. 1192-1193
-
-
MnKPW1
-
54
-
-
38149041474
-
-
For the synthesis, structure and coordination properties of PB and PBP systems, sec: a S. Bontcmps, H. Gornitzka. G. Bouhadir. K. Miqueu, D. Bourissou, Angew. Chem. 2006, 118, 1641 -1644;
-
For the synthesis, structure and coordination properties of PB and PBP systems, sec: a) S. Bontcmps, H. Gornitzka. G. Bouhadir. K. Miqueu, D. Bourissou, Angew. Chem. 2006, 118, 1641 -1644;
-
-
-
-
55
-
-
33744485927
-
-
Angew. Chem. Int. Ed. 2006, 45, 1611-1614;
-
(2006)
Angew. Chem. Int. Ed
, vol.45
, pp. 1611-1614
-
-
-
56
-
-
33748774699
-
-
b) S. Bontemps, G. Bouhadir, K. Miqueu. D. Bourissou. J. Am. Chem. Soc. 2006, 128, 12056-12057;
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 12056-12057
-
-
Bontemps, S.1
Bouhadir, G.2
Miqueu, K.3
Bourissou, D.4
-
57
-
-
34447324381
-
-
c)S. Bontemps. G. Bouhadir. P.W. Dyer. K. Miqueu, D. Bourissou, Inorg. Chem. 2007, 46, 5149-5151:
-
(2007)
Inorg. Chem
, vol.46
, pp. 5149-5151
-
-
Bontemps, S.1
Bouhadir, G.2
Dyer, P.W.3
Miqueu, K.4
Bourissou, D.5
-
59
-
-
38149049738
-
-
DOI: 10.1002/ange.20() 73518;
-
e) M. Sircoglou, S. Bontemps. M. Mercy, N. Saffon, M. Takahashi. G. Bouhadir, L. Maron, D. Bourissou, Angew. Chem. DOI: 10.1002/ange.20() 73518;
-
Angew. Chem
-
-
Sircoglou, M.1
Bontemps, S.2
Mercy, M.3
Saffon, N.4
Takahashi, M.5
Bouhadir, G.6
Maron, L.7
Bourissou, D.8
-
60
-
-
38149081085
-
-
Angew. Chem. Int. Ed. DOI: 10.1002/ anie.200703518. For the synthesis, structure and coordination properties of a related NB system, see
-
Angew. Chem. Int. Ed. DOI: 10.1002/ anie.200703518. For the synthesis, structure and coordination properties of a related NB system, see
-
-
-
-
61
-
-
34250011741
-
-
f) J. Vergnaud. T. Ayed. K. Hussein. L. Vendier. M. Grellier. G. Bouhadir. J.-C. Barthelat. S. Sabo-Etienne. D. Bourissou. Dalton Trans. 2007, 2370-2372.
-
(2007)
Dalton Trans
, pp. 2370-2372
-
-
Vergnaud, J.1
Ayed, T.2
Hussein, K.3
Vendier, L.4
Grellier, M.5
Bouhadir, G.6
Barthelat, J.-C.7
Sabo-Etienne, S.8
Bourissou, D.9
-
62
-
-
2542473311
-
-
A few transition-metal complexes of PBP systems with borane moieties free of interaction with any basic site have also been reported: a L. Turculet, J. D. Feldman, T. D. Tilley, Organometallics 2004, 23, 2488-2502
-
A few transition-metal complexes of PBP systems with borane moieties free of interaction with any basic site have also been reported: a) L. Turculet, J. D. Feldman, T. D. Tilley, Organometallics 2004, 23, 2488-2502:
-
-
-
-
64
-
-
36549009061
-
-
For the derivatization of PB compounds into photoisomerizable systems, see
-
For the derivatization of PB compounds into photoisomerizable systems, see: M. W. P. Bebbington, S. Bontemps, G. Bouhadir. D. Bourissou. Angew. Chem. 2007, 119, 3397-3400:
-
(2007)
Angew. Chem
, vol.119
, pp. 3397-3400
-
-
Bebbington, M.W.P.1
Bontemps, S.2
Bouhadir, G.3
Bourissou, D.4
-
65
-
-
34249996418
-
-
Angew. Chem. Int. Ed. 2007, 46, 3333-3336.
-
(2007)
Angew. Chem. Int. Ed
, vol.46
, pp. 3333-3336
-
-
-
67
-
-
33845902303
-
-
b) S. R. Oakley. K. D. Parker, D. J. H. Emslie, I. Vargas-Baca, C. M. Robertson. L. E. Harrington. J. F. Britten. Organometallics 2006, 25, 5835-5838.
-
(2006)
Organometallics
, vol.25
, pp. 5835-5838
-
-
Oakley, S.R.1
Parker, K.D.2
Emslie, D.J.H.3
Vargas-Baca, I.4
Robertson, C.M.5
Harrington, L.E.6
Britten, J.F.7
-
68
-
-
38149068783
-
-
3 dehydrogenative oligomerization in the presence of an ambiphilic PAl system: F-G. Fontaine. D. Zargarian. J. Am. Chem. Soc 2004, 126, 8786-8794.
-
3 dehydrogenative oligomerization in the presence of an ambiphilic PAl system: F-G. Fontaine. D. Zargarian. J. Am. Chem. Soc 2004, 126, 8786-8794.
-
-
-
-
69
-
-
0027527226
-
-
Anchoring substrates by interaction with pendant Lewis acid moieties has been investigated with boron analogues of the DIOP ligand: a A. Borner. J. Ward. K. Kortus. H. B. Kagan. Tetrahedron: Asymmetry 1993, 4, 2219-2228
-
Anchoring substrates by interaction with pendant Lewis acid moieties has been investigated with boron analogues of the DIOP ligand: a) A. Borner. J. Ward. K. Kortus. H. B. Kagan. Tetrahedron: Asymmetry 1993, 4, 2219-2228:
-
-
-
-
71
-
-
38149009417
-
-
2} complex reported by Grobe et al. revealed large RhB distances of (2.94-2.97 Å) and an almost planar environment around the boron atoms, suggesting a very weak, if any. Rh→B interaction: a) J. Grobe. R. Martin. Z. Anorg. Chem. 1992, 607, 146-152;
-
2} complex reported by Grobe et al. revealed large RhB distances of (2.94-2.97 Å) and an almost planar environment around the boron atoms, suggesting a very weak, if any. Rh→B interaction: a) J. Grobe. R. Martin. Z. Anorg. Chem. 1992, 607, 146-152;
-
-
-
-
72
-
-
85055727452
-
-
b)J. Grobe. K. Lütz-Brotchrup. B. Krebs. M. Läge. H.-H. Niemeyer. E.-U. Würthwein. Z. Naturforsch. 2006, 61b, 882-895.
-
(2006)
Z. Naturforsch
, vol.61 b
, pp. 882-895
-
-
Grobe, J.1
Lütz-Brotchrup, K.2
Krebs, B.3
Läge, M.4
Niemeyer, H.-H.5
Würthwein, E.-U.6
-
74
-
-
0002138516
-
-
For general reviews, see for example a
-
For general reviews, see for example a) D. Bourissou. O. Guerret. F.P. Gabbaï. G. Bertrand. Chem. Rev. 2000, 100, 39-91;
-
(2000)
Chem. Rev
, vol.100
, pp. 39-91
-
-
Bourissou, D.1
Guerret, O.2
Gabbaï, F.P.3
Bertrand, G.4
-
76
-
-
0037090932
-
-
Angew. Chem. Int. Ed. 2002, 41, 1290-1309.
-
(2002)
Angew. Chem. Int. Ed
, vol.41
, pp. 1290-1309
-
-
-
77
-
-
3242657915
-
-
For selected recent examples, see: a
-
For selected recent examples, see: a) V Lavallo. J. Mafhouz. Y. Canac. B. Donnadieu, W. W. Schoellcr. G. Bertrand. J. Am. Chem. Soc. 2004, 126, 8670-8671;
-
(2004)
J. Am. Chem. Soc
, vol.126
, pp. 8670-8671
-
-
Lavallo, V.1
Mafhouz, J.2
Canac, Y.3
Donnadieu, B.4
Schoellcr, W.W.5
Bertrand, G.6
-
78
-
-
27744501123
-
-
b) D. Martin, A. Baceiredo. H. Gornitzka. W.W. Schoeller. G. Bertrand, Angew. Chem. 2005, 117, 1728-1731:
-
(2005)
Angew. Chem
, vol.117
, pp. 1728-1731
-
-
Martin, D.1
Baceiredo, A.2
Gornitzka, H.3
Schoeller, W.W.4
Bertrand, G.5
-
79
-
-
17044385038
-
-
Angew. Chem. Int. Ed. 2005, 44, 1700-1703;
-
(2005)
Angew. Chem. Int. Ed
, vol.44
, pp. 1700-1703
-
-
-
80
-
-
27844547982
-
-
c) V. Lavallo. Y. Canac,C.Prasang, B. Donnadieu. G. Bertrand, Angew. Chem. 2005, 117, 5851-5855;
-
(2005)
Angew. Chem
, vol.117
, pp. 5851-5855
-
-
Lavallo, V.1
Canac, Y.2
Prasang, C.3
Donnadieu, B.4
Bertrand, G.5
-
81
-
-
24944490141
-
-
Angew. Chem. Int. Ed. 2005, 44, 5705-5709;
-
(2005)
Angew. Chem. Int. Ed
, vol.44
, pp. 5705-5709
-
-
-
82
-
-
14944342193
-
-
d) M. Alcarazo. S. J. Roseblade, A. R. Cowley. R. Fernández, J. M. Brown. J. M. Lassaletta. J. Am. Chem. Soc. 2005, 127, 3290-3291:
-
(2005)
J. Am. Chem. Soc
, vol.127
, pp. 3290-3291
-
-
Alcarazo, M.1
Roseblade, S.J.2
Cowley, A.R.3
Fernández, R.4
Brown, J.M.5
Lassaletta, J.M.6
-
83
-
-
19744363825
-
-
e) Y. Canac. S. Conejero, B. Donnadieu. W. W. Schoeller, G. Bertrand. J. Am. Chem. Soc. 2005, 127, 7312-7313:
-
(2005)
J. Am. Chem. Soc
, vol.127
, pp. 7312-7313
-
-
Canac, Y.1
Conejero, S.2
Donnadieu, B.3
Schoeller, W.W.4
Bertrand, G.5
-
85
-
-
33845929780
-
-
g) M. D. Sanderson, J. W. Kamplain, C. W. Bielawski, J. Am. Chem. Soc 2006, 128, 16514-16515;
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 16514-16515
-
-
Sanderson, M.D.1
Kamplain, J.W.2
Bielawski, C.W.3
-
87
-
-
34250841727
-
-
Angew. Chem. Int. Ed. 2007, 46, 3729-3731:
-
(2007)
Angew. Chem. Int. Ed
, vol.46
, pp. 3729-3731
-
-
-
88
-
-
33947160691
-
-
i) S. Gómez-Bujedo. M. Alcarazo, C. Pichon, E. Alvarez, R. Fernández, J. M. Lassaletta, Chem. Commun. 2007, 1180-1182;
-
(2007)
Chem. Commun
, pp. 1180-1182
-
-
Gómez-Bujedo, S.1
Alcarazo, M.2
Pichon, C.3
Alvarez, E.4
Fernández, R.5
Lassaletta, J.M.6
-
89
-
-
34249947919
-
-
j)P. Bazinet, T.-G. Ong. J. S. O'Brien. N. Lavoie, E. Bell, G. P. A. Yap, I. Korobkov, D. S. Richeson, Organometallics 2007, 26, 2885-2895.
-
(2007)
Organometallics
, vol.26
, pp. 2885-2895
-
-
Bazinet, P.1
Ong, T.-G.2
O'Brien, J.S.3
Lavoie, N.4
Bell, E.5
Yap, G.P.A.6
Korobkov, I.7
Richeson, D.S.8
-
90
-
-
0001752768
-
-
A Cambridge Structural Database (F. H. Allen. Ada Crystallogr. 2002, B58, 380-388) search revealed only a few structurally authenticated ds-[Rh(CO)Cl(diphos)[ complexes: a)
-
A Cambridge Structural Database (F. H. Allen. Ada Crystallogr. 2002, B58, 380-388) search revealed only a few structurally authenticated ds-[Rh(CO)Cl(diphos)[ complexes: a)
-
-
-
-
91
-
-
0012456998
-
-
K. A. Bunten. D. H. Farrar, A.J. Poë. A. Lough, Organometallics 2002, 21, 3344-3350;
-
(2002)
Organometallics
, vol.21
, pp. 3344-3350
-
-
Bunten, K.A.1
Farrar, D.H.2
Poë, A.J.3
Lough, A.4
-
92
-
-
0000087352
-
-
b) S. A. Laneman, F. R. Fronczek, G. G. Staneley, J. Am. Chem. Soc. 1988, 110, 5585-5586;
-
(1988)
J. Am. Chem. Soc
, vol.110
, pp. 5585-5586
-
-
Laneman, S.A.1
Fronczek, F.R.2
Staneley, G.G.3
-
94
-
-
0033536265
-
-
d) R. Paciello. L. Siggel. H. J. Kneuper, N. Walker, M. Roper, J. Mol. Catal. A: Chem. 1999, 143, 85-97.
-
(1999)
J. Mol. Catal. A: Chem
, vol.143
, pp. 85-97
-
-
Paciello, R.1
Siggel, L.2
Kneuper, H.J.3
Walker, N.4
Roper, M.5
-
95
-
-
38149081955
-
-
The change from cis to trans coordination is accompanied by a widening of both the PCC and CCB bond angles by about 4°.
-
The change from cis to trans coordination is accompanied by a widening of both the PCC and CCB bond angles by about 4°.
-
-
-
-
96
-
-
33748669297
-
-
This situation is reminiscent to that observed with related diphosphines featuring a diphenyl ether tether: a P. Dierkes. P. W. N. M. van Leeuwen, J. Chem. Soc. Dalton Trans. 1999, 1519-1529
-
This situation is reminiscent to that observed with related diphosphines featuring a diphenyl ether tether: a) P. Dierkes. P. W. N. M. van Leeuwen, J. Chem. Soc. Dalton Trans. 1999, 1519-1529:
-
-
-
-
98
-
-
16244380227
-
-
The short distance between the carbon atom of the CO group and the ipso-carbon of the phenyl ring at boron (3.107 A) in compound 6a may suggest some π⋯π interaction. For a recent example of such contacts between carbonyl ligands and an aryl ring, see D. L. Reger. R. P. Watson. M. D. Smith. P. J. Pellechia. Organometallics 2005, 24, 1544-1555.
-
The short distance between the carbon atom of the CO group and the ipso-carbon of the phenyl ring at boron (3.107 A) in compound 6a may suggest some π⋯π interaction. For a recent example of such contacts between carbonyl ligands and an aryl ring, see D. L. Reger. R. P. Watson. M. D. Smith. P. J. Pellechia. Organometallics 2005, 24, 1544-1555.
-
-
-
-
99
-
-
38149045565
-
-
The optimized geometry of 6a* reproduces the short distance (3.118 A) observed experimentally (3.107 Å) between the carbon atom of the CO group and the ipso-carbon of the phenyl ring at boron. In a similar way. the cis isomer 6 c* is predicted to also feature such a short CC distance (3.026 A).
-
The optimized geometry of 6a* reproduces the short distance (3.118 A) observed experimentally (3.107 Å) between the carbon atom of the CO group and the ipso-carbon of the phenyl ring at boron. In a similar way. the cis isomer 6 c* is predicted to also feature such a short CC distance (3.026 A).
-
-
-
-
100
-
-
38149086591
-
-
-1).
-
-1).
-
-
-
-
101
-
-
3042781157
-
-
-1: see a) J. I. Van der Vlugt. R. Sablong. P. C. M. M. Magusin, A. M. Mills, A. L. Spek. D. Vogt, Organometallics 2004, 23, 3177-3183;
-
-1: see a) J. I. Van der Vlugt. R. Sablong. P. C. M. M. Magusin, A. M. Mills, A. L. Spek. D. Vogt, Organometallics 2004, 23, 3177-3183;
-
-
-
-
103
-
-
38149050339
-
-
2] (126Hz). This difference may also be attributed to the reduced electron density at rhodium.
-
2] (126Hz). This difference may also be attributed to the reduced electron density at rhodium.
-
-
-
-
104
-
-
38149067254
-
-
[15b] but comparison with related complexes without σ-acceptor ligand was not readily possible.
-
[15b] but comparison with related complexes without σ-acceptor ligand was not readily possible.
-
-
-
-
105
-
-
31544452262
-
-
2J(P.P) coupling constants greater than 500 Hz. See for example: O. Grossman.C.Azerraf. D. Gelman. Organometallics 2006, 25, 375-381.
-
2J(P.P) coupling constants greater than 500 Hz. See for example: O. Grossman.C.Azerraf. D. Gelman. Organometallics 2006, 25, 375-381.
-
-
-
-
106
-
-
0035323797
-
-
1J(Pt.P) coupling constants of around 2500 Hz:C.A. Bessel, P. Aggarwal. A.C.Marschilok. K.J. Takeuchi. Chem. Rev. 2001, 101, 1031-1066.
-
1J(Pt.P) coupling constants of around 2500 Hz:C.A. Bessel, P. Aggarwal. A.C.Marschilok. K.J. Takeuchi. Chem. Rev. 2001, 101, 1031-1066.
-
-
-
-
107
-
-
0039705601
-
-
P. Braunstein, U. Englert. G. E. Herberich, M. Neuschütz. Angew. Chem. 1995, 107, 1090- 1092:
-
(1995)
Angew. Chem
, vol.107
, pp. 1090-1092
-
-
Braunstein, P.1
Englert, U.2
Herberich, G.E.3
Neuschütz, M.4
-
108
-
-
33748229501
-
-
Angew. Chem. Int. Ed. 1995,34, 1010-1012.
-
(1995)
Angew. Chem. Int. Ed
, vol.34
, pp. 1010-1012
-
-
-
114
-
-
38149016676
-
-
SADABS, Program for data correction, Bruker-AXS
-
SADABS, Program for data correction, Bruker-AXS.
-
-
-
-
116
-
-
38149104423
-
-
SHELXL-97. Program for Crystal Structure Refinement. G. M. Sheldrick. University of Göttingen. 1997.
-
SHELXL-97. Program for Crystal Structure Refinement. G. M. Sheldrick. University of Göttingen. 1997.
-
-
-
-
117
-
-
38149126893
-
-
Gaussian03. Revision B.05, M. J. Frisch. G.W. Trucks, H.B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr. T. Vreven. K. N. Kudin. J.C.Burant, J. M. Millam, S. S. Iyengar. J. Tomasi, V. Barone. B. Mennucci. M. Cossi, G. Scalmani, N. Rega. G. A. Petersson. H. Nakatsuji, M. Hada. M. Ehara. K. Toyota. R. Fukuda. J. Hasegawa. M. Ishida. T. Nakajima, Y. Honda. O. Kitao, H. Nakai. M. X. Kiene. Li. J. E. Knox, H. P. Hratchian, J. B. Cross. C. Adamo, J. Jaramillo, R. Gomperts. R. E. Stratmann, O. Yazyev. A. J. Austin. R. Cammi. C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G. A. Voth. P. Salvador. J. J. Dannenberg. V. G. Zakrzewski. S. Dapprich, A. D. Daniels, M.C.Strain, O. Farkas, D. K. Malick. A. D. Rabuck. K. Raghavachari, J. B. Foresman. J. V. Ortiz. Q. Cui. A. G. Baboul. S. Clifford. J. Cioslowski. B. B. Stefanov. G. Liu, A. Liashenko. P. Piskorz, I. Komaromi. R. L. Martin. D. J. Fox. T. Keith. M. A. Al-Laham. C. Y. Peng. A. Nanayakkara, M. Challacom
-
Gaussian03. Revision B.05, M. J. Frisch. G.W. Trucks, H.B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr. T. Vreven. K. N. Kudin. J.C.Burant, J. M. Millam, S. S. Iyengar. J. Tomasi, V. Barone. B. Mennucci. M. Cossi, G. Scalmani, N. Rega. G. A. Petersson. H. Nakatsuji, M. Hada. M. Ehara. K. Toyota. R. Fukuda. J. Hasegawa. M. Ishida. T. Nakajima, Y. Honda. O. Kitao, H. Nakai. M. X. Kiene. Li. J. E. Knox, H. P. Hratchian, J. B. Cross. C. Adamo, J. Jaramillo, R. Gomperts. R. E. Stratmann, O. Yazyev. A. J. Austin. R. Cammi. C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G. A. Voth. P. Salvador. J. J. Dannenberg. V. G. Zakrzewski. S. Dapprich, A. D. Daniels, M.C.Strain, O. Farkas, D. K. Malick. A. D. Rabuck. K. Raghavachari, J. B. Foresman. J. V. Ortiz. Q. Cui. A. G. Baboul. S. Clifford. J. Cioslowski. B. B. Stefanov. G. Liu, A. Liashenko. P. Piskorz, I. Komaromi. R. L. Martin. D. J. Fox. T. Keith. M. A. Al-Laham. C. Y. Peng. A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen. M.W. Wong, C. Gonzalez, J. A. Pople, Gaussian, Inc., Pittsburgh PA, 2003.
-
-
-
-
118
-
-
84873055189
-
-
Wiley, New York
-
W. J. Hehre, L. Radom, P. v. R. Schleyer, J. A. Pople, Ab Initio Molecular Orbital Theory, Wiley, New York, 1986.
-
(1986)
Ab Initio Molecular Orbital Theory
-
-
Hehre, W.J.1
Radom, L.2
Schleyer, P.V.R.3
Pople, J.A.4
-
121
-
-
0003454331
-
-
Eds, J. F. Dobson. G. Vignale. M. P. Das, Plenum Press, New York
-
b) K. Burke. J. P. Perdew, W. Yang, Electronic Density Functional Theory: Recent Progress and New Directions (Eds.: J. F. Dobson. G. Vignale. M. P. Das), Plenum Press, New York, 1998.
-
(1998)
Electronic Density Functional Theory: Recent Progress and New Directions
-
-
Burke, K.1
Perdew, J.P.2
Yang, W.3
-
122
-
-
0000766887
-
-
Ed, J. Grotendorst, John von Neuman Institute for Computing, Jülich Germany
-
a) M. Dolg, Modern Methods and Algorithm of Quantum Chemistry. Vol. 1 (Ed.: J. Grotendorst), John von Neuman Institute for Computing, Jülich (Germany), 2000, pp. 479-508;
-
(2000)
Modern Methods and Algorithm of Quantum Chemistry
, vol.1
, pp. 479-508
-
-
Dolg, M.1
-
123
-
-
36549092018
-
-
b) M. Dolg, U. Wedig, H. Stoll, H. Preuss, J. Chem. Phys. 1987, 86, 866-872;
-
(1987)
J. Chem. Phys
, vol.86
, pp. 866-872
-
-
Dolg, M.1
Wedig, U.2
Stoll, H.3
Preuss, H.4
-
124
-
-
11744322674
-
-
c) D. Andrae. U. Häussermann, M. DoIg, H. Stoll. H. Preuss, Theor. Chim. Acta. 1990, 77, 123-141.
-
(1990)
Theor. Chim. Acta
, vol.77
, pp. 123-141
-
-
Andrae, D.1
Häussermann, U.2
DoIg, M.3
Stoll, H.4
Preuss, H.5
-
127
-
-
38149026070
-
-
Molekel 4.3, P. Flükiger, H. P. Lüthi, S. Portmann. J. Weber, Swiss Center for Scientific Computing, Manno. Switzerland. 2000-2002:
-
a) Molekel 4.3, P. Flükiger, H. P. Lüthi, S. Portmann. J. Weber, Swiss Center for Scientific Computing, Manno. Switzerland. 2000-2002:
-
-
-
|