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Orpen, A.G.5
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21
-
-
33749844876
-
-
note
-
2- formalism for oxidation number assignments.
-
-
-
-
22
-
-
3242884305
-
-
For other aspects of problems in oxidation number assignments, see: (a) Steinborn, D. J. Chem. Educ. 2004, 81, 1148-1154.
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Steinborn, D.1
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23
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0036536460
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(b) Holder, D. A.; Johnson, B. G.; Karol, P. J. J. Chem. Educ. 2002, 79, 465-467.
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Holder, D.A.1
Johnson, B.G.2
Karol, P.J.3
-
27
-
-
33749846996
-
-
note
-
For both of these methods, an exception is that bonds between the same element are broken homolytically.
-
-
-
-
29
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0040898605
-
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6 with alkali-metal naphthalides. See: Godfroid, R. A.; Hill, T. G.; Onak, T. P.; Shore, S. G. J. Am. Chem. Soc. 1994, 121, 12107-12108.
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Godfroid, R.A.1
Hill, T.G.2
Onak, T.P.3
Shore, S.G.4
-
30
-
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33645508133
-
-
Oxford University Press: New York
-
n configuration is the number of electrons that are housed in metal d orbitals that are either primarily nonbonding or have metal-ligand antibonding character. See ref 12b and: Jean, Y. Molecular Orbitals of Transition Metal Complexes; Oxford University Press: New York, 2005; pp 12, 31.
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Jean, Y.1
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31
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33645516769
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King, R. B., Ed.; Wiley: New York
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(a) Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; Wiley: New York, 1994; Vol. 2, p 961.
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38
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0001001584
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Lever, A. B. P., Solomon, E. I., Eds.; Wiley: New York, (Applications and Case Studies), Chapter 7
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(c) Westcott, B. L.; Enemark, J. H. In Inorganic Electronic Structure and Spectroscopy; Lever, A. B. P., Solomon, E. I., Eds.; Wiley: New York, 1999; Vol. II (Applications and Case Studies), Chapter 7, pp 403-450.
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, pp. 403-450
-
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Westcott, B.L.1
Enemark, J.H.2
-
39
-
-
33749822230
-
-
note
-
A linear metal nitrosyl is described by three orbital interactions between the metal and NO (one σ and two π), whereas a bent metal nitrosyl is described by two orbital interactions between the metal and NO (one σ and one π).
-
-
-
-
40
-
-
33749874216
-
-
note
-
2- correspond to equivalent descriptions of a covalent metal-borane interaction involving the occupation of a single M-B σ bond by a pair of electrons.
-
-
-
-
44
-
-
33749821154
-
-
note
-
Also note that these two representations are not resonance structures because they correspond to the same electron distribution.
-
-
-
-
45
-
-
33749866790
-
-
note
-
n configuration is not typically regarded to be a function of the degree of electron transfer (i.e. the relative electronegativity of a ligand) in a normal covalent bond.
-
-
-
-
46
-
-
0000100592
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-
See, for example, ref 5c and: Aullón, G.; Alvarez, S. Inorg. Chem. 1996, 35, 3137-3144.
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-
Aullón, G.1
Alvarez, S.2
-
48
-
-
33749818357
-
-
note
-
12b A complete understanding of the molecule would, nevertheless, require the roles played by the potential π and δ acceptor orbitals of the ligand to be evaluated.
-
-
-
-
52
-
-
33749861178
-
-
For an early description of the L, X, and Z classification, see ref 28
-
For an early description of the L, X, and Z classification, see ref 28.
-
-
-
-
53
-
-
33749818661
-
-
note
-
5X] classification.
-
-
-
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