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N-Heterocyclic carbenes were recently found to also be efficient promoters in the trimerization of isocyanates into isocyanurates:
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The cyclotrimerization of isocyanates can also be catalyzed by transition metal complexes, and intermediates, including 1: 1 and 1: 2 adducts, have been characterized:
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A phosphonio enolate zwitterion, resulting from the three-component coupling of a phosphine, an electron-deficient alkyne and an aldehyde, has recently been isolated and structurally characterized:
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