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Volumn 4, Issue 3, 2009, Pages 428-435

Bridging M-Cl bonds with ambiphilic phosphine-borane ligands

Author keywords

Ambiphilic ligands; Boranes; Density functional calculations; NMR spectroscopy; X ray diffraction

Indexed keywords

AMBIPHILIC LIGANDS; BORANES; BRIDGING COORDINATIONS; DENSITY FUNCTIONAL CALCULATIONS; DFT CALCULATIONS; DI-NUCLEAR COMPLEXES; HETEROLEPTIC; INTERCONVERSION; LEWIS ACIDS; LINKAGE ISOMERS; MONONUCLEAR COMPLEXES; NMR SPECTROSCOPY; SOLID-STATE STRUCTURES; SPECTROSCOPIC DATUM; STERIC FACTORS;

EID: 62749178577     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.200800388     Document Type: Article
Times cited : (42)

References (101)
  • 1
    • 62749083238 scopus 로고    scopus 로고
    • Ambiphilic compounds have also been investigated as multicenter catalysts,[2] molecular sensors,[3] π-conjugated materials,[4] dihydrogen activators,[5] precursors for photoisomerizable heterodienes,[6] and mechanistic probes, 7
    • [7]
  • 6
    • 5344224096 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2004, 43, 4566-4583.
    • (2004) Angew. Chem. Int. Ed , vol.43 , pp. 4566-4583
  • 11
    • 20644469225 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 3606-3609.
    • (2005) Angew. Chem. Int. Ed , vol.44 , pp. 3606-3609
  • 13
    • 0037119389 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 2927-2931;
    • (2002) Angew. Chem. Int. Ed , vol.41 , pp. 2927-2931
  • 19
    • 35648993031 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 8050-8053;
    • (2007) Angew. Chem. Int. Ed , vol.46 , pp. 8050-8053
  • 21
    • 62749139057 scopus 로고    scopus 로고
    • G. C. Welch, L. Cabrera, P. A. Chase, E. Hollink, J. D. Masuda, P. Wei, D.W. Stephan, Dalton Trans. 2007, 34073414;
    • d) G. C. Welch, L. Cabrera, P. A. Chase, E. Hollink, J. D. Masuda, P. Wei, D.W. Stephan, Dalton Trans. 2007, 34073414;
  • 23
    • 54749124338 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 7543-7546.
    • (2008) Angew. Chem. Int. Ed , vol.47 , pp. 7543-7546
  • 25
    • 34249996418 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 3333-3336.
    • (2007) Angew. Chem. Int. Ed , vol.46 , pp. 3333-3336
  • 27
    • 62749142200 scopus 로고    scopus 로고
    • The ability of Lewis acids to act as o-acceptor ligands was recognized early on, and referred to as Z-type ligands: a R. B. King, Adv. Chem. Ser. 1967, 62, 203-220;
    • The ability of Lewis acids to act as o-acceptor ligands was recognized early on, and referred to as Z-type ligands: a) R. B. King, Adv. Chem. Ser. 1967, 62, 203-220;
  • 29
    • 62749087460 scopus 로고    scopus 로고
    • Transition metal → borane interactions were first structurally authenticated within metallaboratranes deriving from hydrido tris(imazolyl)borate ligands: a) A. F. Hill, G. R. Owen, A. J. P. White, D.J. Williams, Angew. Chem. 1999, 111, 2920-2923;
    • Transition metal → borane interactions were first structurally authenticated within metallaboratranes deriving from hydrido tris(imazolyl)borate ligands: a) A. F. Hill, G. R. Owen, A. J. P. White, D.J. Williams, Angew. Chem. 1999, 111, 2920-2923;
  • 30
    • 0033578646 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 1999, 38, 2759-2761;
    • (1999) Angew. Chem. Int. Ed , vol.38 , pp. 2759-2761
  • 46
    • 33744485927 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 1611-1614;
    • (2006) Angew. Chem. Int. Ed , vol.45 , pp. 1611-1614
  • 50
    • 36549064306 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 8583-8586;
    • (2007) Angew. Chem. Int. Ed , vol.46 , pp. 8583-8586
  • 52
    • 62749185269 scopus 로고    scopus 로고
    • S. Bontemps, G. .Bouhadir, W. Gu, M. Mercy, C.-H. Chen, B. M. Foxman, L. Maron, O. V. Ozerov, D. Bourissou, Angew. Chem. 2008, 120, 1503-1506;
    • f) S. Bontemps, G. .Bouhadir, W. Gu, M. Mercy, C.-H. Chen, B. M. Foxman, L. Maron, O. V. Ozerov, D. Bourissou, Angew. Chem. 2008, 120, 1503-1506;
  • 53
    • 41749100255 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 1481-1484;
    • (2008) Angew. Chem. Int. Ed , vol.47 , pp. 1481-1484
  • 56
    • 85153028687 scopus 로고    scopus 로고
    • F.-G. Fontaine, J. Boudreau, M.-H. Thibault, Eur. J. Inorg. Chem. 2008, 54395454;
    • i) F.-G. Fontaine, J. Boudreau, M.-H. Thibault, Eur. J. Inorg. Chem. 2008, 54395454;
  • 74
    • 62749136666 scopus 로고    scopus 로고
    • 2BPh} with cleavage of the chloro bridge rather than that of the Rh-→ ;B interaction.[100]
    • 2BPh} with cleavage of the chloro bridge rather than that of the Rh-→ ;B interaction.[100]
  • 78
    • 62749176758 scopus 로고    scopus 로고
    • Such an equilibrium between the bridging and B-pendant forms may explain that no distinct B NMR signal could be detected for 5 and 6 in solution.
    • Such an equilibrium between the bridging and B-pendant forms may explain that no distinct "B NMR signal could be detected for 5 and 6 in solution.
  • 81
    • 54749106508 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 7489-7492.
    • (2008) Angew. Chem. Int. Ed , vol.47 , pp. 7489-7492
  • 82
    • 62749189554 scopus 로고    scopus 로고
    • Although aryl dimesitylboranes normally only bind fluoride, the geometric constraint induced by the rigid R2P-O(CsH4)BMeS2 skeleton was recently found to allow the interaction of the BMeS2 group with larger Lewis bases.[6.7
    • [6.7]
  • 83
    • 62749176969 scopus 로고    scopus 로고
    • The coexistence of the bridging and B-pendant forms suggests some hemilabile character for the ambiphilic PBCy2 ligand. For a recent review on the hemilability of hybrid ligands, see: P. Braunstein, F. Naud, Angew. Chem. 2001, 113, 702-722;
    • 2 ligand. For a recent review on the hemilability of hybrid ligands, see: P. Braunstein, F. Naud, Angew. Chem. 2001, 113, 702-722;
  • 84
    • 0035804417 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2001, 40, 680-699.
    • (2001) Angew. Chem. Int. Ed , vol.40 , pp. 680-699
  • 85
    • 62749176068 scopus 로고    scopus 로고
    • SADABS, Program for data correction, Bruker-AXS
    • SADABS, Program for data correction, Bruker-AXS.
  • 87
    • 62749206559 scopus 로고    scopus 로고
    • SHELXL-97, Program for Crystal Structure Refinement, G. M. Sheldrick, University of Göttingen, 1997.
    • SHELXL-97, Program for Crystal Structure Refinement, G. M. Sheldrick, University of Göttingen, 1997.
  • 88
    • 62749190704 scopus 로고    scopus 로고
    • Gaussian 03, Revision B.05, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr. T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. X. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G.A. Voth, P. Salvador, J.J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkar
    • Gaussian 03, Revision B.05, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr. T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. X. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G.A. Voth, P. Salvador, J.J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, J. A. Pople, Gaussian, Inc., Pittsburgh PA, 2003.
  • 90
    • 5944261746 scopus 로고    scopus 로고
    • J. P. Perdew, Phys. Rev. B 1986, 33, 8822-8824; Erratum:
    • b) J. P. Perdew, Phys. Rev. B 1986, 33, 8822-8824; Erratum:
  • 94
    • 0000766887 scopus 로고    scopus 로고
    • Ed, J. Grotendorst, John von Neuman Institute for Computing, Jülich, Germany
    • a) M. Dolg, Modern Methods and Algorithm of Quantum Chemistry, Vol. 1 (Ed.: J. Grotendorst), John von Neuman Institute for Computing, Jülich, Germany, 2000, pp. 479-508;
    • (2000) Modern Methods and Algorithm of Quantum Chemistry , vol.1 , pp. 479-508
    • Dolg, M.1


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