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The lowest singlet state, referred to as 1Dg, features one doublyoccupied p* orbital and one empty p* orbital, so singlet dioxygen can be considered as an ambiphilic molecule
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The lowest singlet state, referred to as 1Dg, features one doublyoccupied p* orbital and one empty p* orbital, so singlet dioxygen can be considered as an ambiphilic molecule.
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The frustrated Lewis pair tBu3P/B(C6F5)3 was recently found to readily bind nitrous oxide (N2O):
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1,2-Shifts of aryl groups from boron to oxygen have already been observed; see, for example:
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1,2-Shifts of aryl groups from boron to oxygen have already been observed; see, for example:, Hoffmann R.W., Ditrich K., Synthesis, 1983, 107-109.
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Sodium perborate, which is commonly used as a bleaching agent in the detergent industry, features O-O bridges:
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The peroxoborate tBuOOB(en)(en=ethylene glycol) was prepared from tBuOOH and ClB(en) and used to oxidize organolithium and Grignard reagents. See Ref. and:
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The peroxoborate tBuOOB(en)(en=ethylene glycol) was prepared from tBuOOH and ClB(en) and used to oxidize organolithium and Grignard reagents. See Ref. and: R.W. Hoffmann, B. Hlzer, O. Knopff, K. Harms, Angew. Chem. 2000, 112, 3206-3207;
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For a crystalline peroxoboronic acid that is k2-O,O coordinated to rhodium, see:
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A peroxoborate complex [Rh], OOB(pin) (pin=tetramethylethylene glycol) has been characterized by NMR at low temperature upon reacting a h2-peroxo rhodium complex with pinacolborane HB(pin):
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A peroxoborate complex [Rh]OOB(pin) (pin=tetramethylethylene glycol) has been characterized by NMR at low temperature upon reacting a h2-peroxo rhodium complex with pinacolborane HB(pin): M.A. Ahijado Salomon, T. Braun, A. Pener, Angew. Chem. 2008, 120, 8999-9003;
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The phosphadioxirane II was predicted to rearrange into the phosphine peroxide III with a barrier height of only 5.1 kcal mol-1
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The phosphadioxirane II was predicted to rearrange into the phosphine peroxide III with a barrier height of only 5.1 kcal mol-1.
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