-
1
-
-
34547765544
-
Non-heme Fe(IV)-oxo intermediates
-
Krebs, C., Fujimori, D. G., Walsh, C. T. & Bollinger, J. M. Jr. Non-heme Fe(IV)-Oxo intermediates. Acc. Chem. Res. 40, 484-492 (2007).
-
(2007)
Acc. Chem. Res.
, vol.40
, pp. 484-492
-
-
Krebs, C.1
Fujimori, D.G.2
Walsh, C.T.3
Bollinger Jr., J.M.4
-
2
-
-
1542378704
-
Dioxygen activation at mono-nuclear nonheme iron active sites: Enzymes, models, and intermediates
-
Costas, M., Mehn, M. P., Jensen, M. P. & Que, L. Dioxygen activation at mono-nuclear nonheme iron active sites: enzymes, models, and intermediates. Chem. Rev. 104, 939-986 (2004).
-
(2004)
Chem. Rev.
, vol.104
, pp. 939-986
-
-
Costas, M.1
Mehn, M.P.2
Jensen, M.P.3
Que, L.4
-
3
-
-
34547803345
-
Guest editorial: Dioxygen activation by metalloenzymes and models
-
Nam, W. Guest editorial: dioxygen activation by metalloenzymes and models. Acc. Chem. Res. 40, 465 (2007).
-
(2007)
Acc. Chem. Res.
, vol.40
, pp. 465
-
-
Nam, W.1
-
4
-
-
33947700818
-
Radical intermediates in monooxygenase reactions of Rieske dioxygenases
-
DOI 10.1021/ja068188v
-
Chakrabarty, S., Austin, R. N., Deng, D., Groves, J. T. & Lipscomb, J. D. Radical intermediates in monooxygenase reactions of rieske dioxygenases. J. Am. Chem. Soc. 129, 3514-3515 (2007). (Pubitemid 46502708)
-
(2007)
Journal of the American Chemical Society
, vol.129
, Issue.12
, pp. 3514-3515
-
-
Chakrabarty, S.1
Austin, R.N.2
Deng, D.3
Groves, J.T.4
Lipscomb, J.D.5
-
5
-
-
77954913417
-
Current challenges of modeling diiron enzyme active sites for dioxygen activation by biomimetic synthetic complexes
-
Friedle, S., Reisner, E. & Lippard, S. J. Current challenges of modeling diiron enzyme active sites for dioxygen activation by biomimetic synthetic complexes. Chem. Soc. Rev. 39, 2768-2779 (2010).
-
(2010)
Chem. Soc. Rev.
, vol.39
, pp. 2768-2779
-
-
Friedle, S.1
Reisner, E.2
Lippard, S.J.3
-
6
-
-
0036197490
-
Electronic structure and reactivity of high-valent oxo iron porphyrins
-
Fujii, H. Electronic structure and reactivity of high-valent oxo iron porphyrins. Coord. Chem. Rev. 226, 51-60 (2002).
-
(2002)
Coord. Chem. Rev.
, vol.226
, pp. 51-60
-
-
Fujii, H.1
-
7
-
-
33645875048
-
High-valent iron in chemical and biological oxidations
-
Groves, J. T. High-valent iron in chemical and biological oxidations. J. Inorg. Biochem. 100, 434-447 (2006).
-
(2006)
J. Inorg. Biochem.
, vol.100
, pp. 434-447
-
-
Groves, J.T.1
-
8
-
-
33845557435
-
High-valent iron-porphyrin complexes related to peroxidase and cytochrome P-450
-
Groves, J. T., Haushalter, R. C., Nakamura, M., Nemo, T. E. & Evans, B. J. High-valent iron-porphyrin complexes related to peroxidase and cytochrome P-450. J. Am. Chem. Soc. 103, 2884-2886 (1981).
-
(1981)
J. Am. Chem. Soc.
, vol.103
, pp. 2884-2886
-
-
Groves, J.T.1
Haushalter, R.C.2
Nakamura, M.3
Nemo, T.E.4
Evans, B.J.5
-
9
-
-
78649450297
-
The mystery of cytochrome P450 compound I: A mini-review dedicated to klaus ruckpaul
-
Jung, C. The mystery of cytochrome P450 Compound I: a mini-review dedicated to Klaus Ruckpaul. Biochimica et Biophysica Acta (BBA) 1814, 46-57 (2011).
-
(2011)
Biochimica et Biophysica Acta (BBA)
, vol.1814
, pp. 46-57
-
-
Jung, C.1
-
10
-
-
79955057971
-
Dioxygen activation in soluble methane monooxygenase
-
Tinberg, C. E. & Lippard, S. J. Dioxygen activation in soluble methane monooxygenase. Acc. Chem. Res. 44, 280-288 (2011).
-
(2011)
Acc. Chem. Res.
, vol.44
, pp. 280-288
-
-
Tinberg, C.E.1
Lippard, S.J.2
-
11
-
-
33845379095
-
Functionalized nitrogen atom transfer catalyzed by cytochrome P-450
-
Svastits, E. W., Dawson, J. H., Breslow, R. & Gellman, S. H. Functionalized nitrogen atom transfer catalyzed by cytochrome P-450. J. Am. Chem. Soc. 107, 6427-6428 (1985).
-
(1985)
J. Am. Chem. Soc.
, vol.107
, pp. 6427-6428
-
-
Svastits, E.W.1
Dawson, J.H.2
Breslow, R.3
Gellman, S.H.4
-
12
-
-
81555207920
-
X-ray emission spectroscopy evidences a Central carbon in the nitrogenase iron-molybdenum cofactor
-
Lancaster, K. M. et al. X-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactor. Science 334, 974-977 (2011).
-
(2011)
Science
, vol.334
, pp. 974-977
-
-
Lancaster, K.M.1
-
13
-
-
0021764818
-
The mechanism of klebsiella pneumoniae nitrogenase action. Simulation of the dependences of hydrogen evolution rate on component-protein concentration and ratio and sodium dithionite concentration
-
Thorneley, R. N. F. & Lowe, D. J. The mechanism of Klebsiella pneumoniae nitrogenase action. Simulation of the dependences of hydrogen evolution rate on component-protein concentration and ratio and sodium dithionite concentration. Biochem. J. 224, 903-909 (1984).
-
(1984)
Biochem. J.
, vol.224
, pp. 903-909
-
-
Thorneley, R.N.F.1
Lowe, D.J.2
-
14
-
-
0021764942
-
The mechanism of klebsiella pneumoniae nitrogenase action. Pre-steady-state kinetics of an enzyme-bound intermediate in nitrogen reduction and of ammonia formation
-
Thorneley, R. N. F. & Lowe, D. J. The mechanism of Klebsiella pneumoniae nitrogenase action. Pre-steady-state kinetics of an enzyme-bound intermediate in nitrogen reduction and of ammonia formation. Biochem. J. 224, 887-894 (1984).
-
(1984)
Biochem. J.
, vol.224
, pp. 887-894
-
-
Thorneley, R.N.F.1
Lowe, D.J.2
-
15
-
-
0021764941
-
The mechanism of klebsiella pneumoniae nitrogenase action. Pre-steady-state kinetics of hydrogen formation
-
Lowe, D. J. & Thorneley, R. N. F. The mechanism of Klebsiella pneumoniae nitrogenase action. Pre-steady-state kinetics of hydrogen formation. Biochem. J. 224, 877-886 (1984).
-
(1984)
Biochem. J.
, vol.224
, pp. 877-886
-
-
Lowe, D.J.1
Thorneley, R.N.F.2
-
16
-
-
0021764872
-
The mechanism of klebsiella pneumoniae nitrogenase action. The determination of rate constants required for the simulation of the kinetics of nitrogen reduction and hydrogen evolution
-
Lowe, D. J. & Thorneley, R. N. F. The mechanism of Klebsiella pneumoniae nitrogenase action. The determination of rate constants required for the simulation of the kinetics of nitrogen reduction and hydrogen evolution. Biochem. J. 224, 895-901 (1984).
-
(1984)
Biochem. J.
, vol.224
, pp. 895-901
-
-
Lowe, D.J.1
Thorneley, R.N.F.2
-
17
-
-
33748223814
-
Elementary steps in heterogeneous catalysis
-
Ertl, G. Elementary steps in heterogeneous catalysis. Angew. Chem. Int. Ed. 29, 1219-1227 (1990).
-
(1990)
Angew. Chem. Int. Ed.
, vol.29
, pp. 1219-1227
-
-
Ertl, G.1
-
18
-
-
33645849237
-
Structures of the high-valent metal-ion haem-oxygen intermediates in peroxidases, oxygenases and catalases
-
Hersleth, H.- P., Ryde, U., Rydberg, P., Görbitz, C. H. & Andersson, K. K. Structures of the high-valent metal-ion haem-oxygen intermediates in peroxidases, oxygenases and catalases. J. Inorg. Biochem. 100, 460-476 (2006).
-
(2006)
J. Inorg. Biochem.
, vol.100
, pp. 460-476
-
-
Hersleth, H.-P.1
Ryde, U.2
Rydberg, P.3
Görbitz, C.H.4
Andersson, K.K.5
-
19
-
-
13844253747
-
57Fe Mössbauer spectroscopy: Monitoring changes of an iron-containing active site during a biochemical reaction
-
DOI 10.1021/ic048523I
-
57Fe Mössbauer spectroscopy: monitoring changes of an iron-containing active site during a biochemical reaction. Inorg. Chem. 44, 742-757 (2005). (Pubitemid 40255945)
-
(2005)
Inorganic Chemistry
, vol.44
, Issue.4
, pp. 742-757
-
-
Krebs, C.1
Price, J.C.2
Baldwin, J.3
Saleh, L.4
Green, M.T.5
Bollinger Jr., J.M.6
-
20
-
-
0021770913
-
Mössbauer and electron paramagnetic resonance studies of horseradish peroxidase and its catalytic intermediates
-
Schulz, C. E., Rutter, R., Sage, J. T., Debrunner, P. G. & Hager, L. P. Mössbauer and electron paramagnetic resonance studies of horseradish peroxidase and its catalytic intermediates. Biochemistry 23, 4743-4754 (1984).
-
(1984)
Biochemistry
, vol.23
, pp. 4743-4754
-
-
Schulz, C.E.1
Rutter, R.2
Sage, J.T.3
Debrunner, P.G.4
Hager, L.P.5
-
21
-
-
0000721674
-
Compound I and II analogs of a chlorin
-
Jayaraj, K. et al. Compound I and II analogs of a chlorin. J. Am. Chem. Soc. 117, 9079-9080 (1995).
-
(1995)
J. Am. Chem. Soc.
, vol.117
, pp. 9079-9080
-
-
Jayaraj, K.1
-
22
-
-
34249098665
-
Spectroscopic and computational evaluation of the structure of the high-spin Fe(IV)-oxo intermediates in taurine: α-ketoglutarate dioxygenase from Escherichia coli and its His99Ala ligand variant
-
DOI 10.1021/ja067899q
-
Sinnecker, S. et al. Spectroscopic and computational evaluation of the structure of the high-spin Fe(IV)-Oxo intermediates in taurine: α-Ketoglutarate dioxygenase from Escherichia coli and Its His99Ala ligand variant. J. Am. Chem. Soc. 129, 6168-6179 (2007). (Pubitemid 46786807)
-
(2007)
Journal of the American Chemical Society
, vol.129
, Issue.19
, pp. 6168-6179
-
-
Sinnecker, S.1
Svensen, N.2
Barr, E.W.3
Ye, S.4
Bollinger Jr., J.M.5
Neese, F.6
Krebs, C.7
-
23
-
-
0242490463
-
Atom transfer as a preparative tool in coordination chemistry. Synthesis and characterization of cr(V) nitrido complexes of bidentate ligands
-
Birk, T. & Bendix, J. Atom transfer as a preparative tool in coordination chemistry. Synthesis and characterization of Cr(V) nitrido complexes of bidentate ligands. Inorg. Chem. 42, 7608-7615 (2003).
-
(2003)
Inorg. Chem.
, vol.42
, pp. 7608-7615
-
-
Birk, T.1
Bendix, J.2
-
24
-
-
33645841657
-
Mid- to high-valent imido and nitrido complexes of iron
-
Mehn, M. P. & Peters, J. C. Mid- to high-valent imido and nitrido complexes of iron. J. Inorg. Biochem. 100, 634-643 (2006).
-
(2006)
J. Inorg. Biochem.
, vol.100
, pp. 634-643
-
-
Mehn, M.P.1
Peters, J.C.2
-
25
-
-
33645856788
-
On the status of ferryl protonation
-
Behan, R. K. & Green, M. T. On the status of ferryl protonation. J. Inorg. Biochem. 100, 448-459 (2006).
-
(2006)
J. Inorg. Biochem.
, vol.100
, pp. 448-459
-
-
Behan, R.K.1
Green, M.T.2
-
26
-
-
33747616214
-
Resonance Raman spectroscopy of chloroperoxidase compound II provides direct evidence for the existence of an iron(IV)-hydroxide
-
DOI 10.1073/pnas.0603159103
-
Stone, K. L., Behan, R. K. & Green, M. T. Resonance Raman spectroscopy of chloroperoxidase compound II provides direct evidence for the existence of an iron(IV)-hydroxide. Proc. Natl Acad. Sci. USA 103, 12307-12310 (2006). (Pubitemid 44267255)
-
(2006)
Proceedings of the National Academy of Sciences of the United States of America
, vol.103
, Issue.33
, pp. 12307-12310
-
-
Stone, K.L.1
Behan, R.K.2
Green, M.T.3
-
27
-
-
33646498740
-
Evidence for two ferryl species in chloroperoxidase compound II
-
Stone, K. L., Hoffart, L. M., Behan, R. K., Krebs, C. & Green, M. T. Evidence for two Ferryl species in chloroperoxidase compound II. J. Am. Chem. Soc. 128, 6147-6153 (2006).
-
(2006)
J. Am. Chem. Soc.
, vol.128
, pp. 6147-6153
-
-
Stone, K.L.1
Hoffart, L.M.2
Behan, R.K.3
Krebs, C.4
Green, M.T.5
-
28
-
-
33748353401
-
Evidence for basic ferryls in cytochromes P450
-
DOI 10.1021/ja062428p
-
Behan, R. K., Hoffart, L. M., Stone, K. L., Krebs, C. & Green, M. T. Evidence for basic Ferryls in Cytochromes P450. J. Am. Chem. Soc. 128, 11471-11474 (2006). (Pubitemid 44338839)
-
(2006)
Journal of the American Chemical Society
, vol.128
, Issue.35
, pp. 11471-11474
-
-
Behan, R.K.1
Hoffart, L.M.2
Stone, K.L.3
Krebs, C.4
Green, M.T.5
-
29
-
-
47949104059
-
Electronic structure and spectroscopy of 'superoxidized' iron centers in model systems: Theoretical and experimental trends
-
Berry, J. F., DeBeer George, S. & Neese, F. Electronic structure and spectroscopy of 'superoxidized' iron centers in model systems: theoretical and experimental trends. Phys. Chem. Chem. Phys. 10, 4361-4374 (2008).
-
(2008)
Phys. Chem. Chem. Phys.
, vol.10
, pp. 4361-4374
-
-
Berry, J.F.1
DeBeer George, S.2
Neese, F.3
-
30
-
-
70349684632
-
Enhanced reactivities of iron(IV)-oxo porphyrin π-cation radicals in oxygenation reactions by electron-donating axial ligands
-
Kang, Y. et al. Enhanced reactivities of iron(IV)-oxo porphyrin π-cation radicals in oxygenation reactions by electron-donating axial ligands. Chemistry - A European J. 15, 10039-10046 (2009).
-
(2009)
Chemistry - A European J.
, vol.15
, pp. 10039-10046
-
-
Kang, Y.1
-
31
-
-
77349115125
-
P 450 enzymes: Their structure, reactivity, and selectivity - Modeled by QM/MM calculations
-
Shaik, S. et al. P 450 enzymes: their structure, reactivity, and selectivity - modeled by QM/MM calculations. Chem. Rev. 110, 949-1017 (2010).
-
(2010)
Chem. Rev.
, vol.110
, pp. 949-1017
-
-
Shaik, S.1
-
33
-
-
33645868668
-
High-valent nonheme iron-oxo species in biomimetic oxidations
-
Shan, X. & Que, L. Jr. High-valent nonheme iron-oxo species in biomimetic oxidations. J. Inorg. Biochem. 100, 421-433 (2006).
-
(2006)
J. Inorg. Biochem.
, vol.100
, pp. 421-433
-
-
Shan, X.1
Que Jr., L.2
-
34
-
-
80053272885
-
Efficient water oxidation catalysts based on readily available iron coordination complexes
-
Fillol, J. L. et al. Efficient water oxidation catalysts based on readily available iron coordination complexes. Nat. Chem. 3, 807-813 (2011).
-
(2011)
Nat. Chem.
, vol.3
, pp. 807-813
-
-
Fillol, J.L.1
-
35
-
-
68249145924
-
EPR spectroscopic trapping of the active species of nonheme iron-catalyzed oxidation
-
Lyakin, O. Y., Bryliakov, K. P., Britovsek, G. J. P. & Talsi, E. P. EPR spectroscopic trapping of the active species of nonheme iron-catalyzed oxidation. J. Am. Chem. Soc. 131, 10798-10799 (2009).
-
(2009)
J. Am. Chem. Soc.
, vol.131
, pp. 10798-10799
-
-
Lyakin, O.Y.1
Bryliakov, K.P.2
Britovsek, G.J.P.3
Talsi, E.P.4
-
36
-
-
60149098753
-
Reactive intermediates in oxygenation reactions with mononu-clear nonheme iron catalysts
-
Yoon, J. et al. Reactive intermediates in oxygenation reactions with mononu-clear nonheme iron catalysts. Angew. Chem. Int. Ed. 48, 1257-1260 (2009).
-
(2009)
Angew. Chem. Int. Ed.
, vol.48
, pp. 1257-1260
-
-
Yoon, J.1
-
37
-
-
77953827137
-
Iron-catalyzed halogenation of alkanes: Modeling of nonheme halogenases by experiment and DFT calculations
-
Comba, P. & Wunderlich, S. Iron-catalyzed halogenation of alkanes: modeling of nonheme halogenases by experiment and DFT calculations. Chemistry - A Eur. J. 16, 7293-7299 (2010).
-
(2010)
Chemistry - A Eur. J.
, vol.16
, pp. 7293-7299
-
-
Comba, P.1
Wunderlich, S.2
-
38
-
-
77955581906
-
Fast water oxidation using iron
-
Ellis, W. C., McDaniel, N. D., Bernhard, S. & Collins, T. J. Fast water oxidation using iron. J. Am. Chem. Soc. 132, 10990-10991 (2010).
-
(2010)
J. Am. Chem. Soc.
, vol.132
, pp. 10990-10991
-
-
Ellis, W.C.1
McDaniel, N.D.2
Bernhard, S.3
Collins, T.J.4
-
39
-
-
80053227687
-
Observation of fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C-H and C=C oxidation reactions
-
Prat, I. et al. Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C-H and C=C oxidation reactions. Nat. Chem. 3, 788-793 (2011).
-
(2011)
Nat. Chem.
, vol.3
, pp. 788-793
-
-
Prat, I.1
-
41
-
-
0037436143
-
Crystallographic and spectroscopic characterization of a Nonheme Fe(IV)=O complex
-
DOI 10.1126/science.299.5609.1037
-
Rohde, J.- U. et al. Crystallographic and spectroscopic characterization of a nonheme Fe(IV)=O complex. Science 299, 1037-1039 (2003). (Pubitemid 36222923)
-
(2003)
Science
, vol.299
, Issue.5609
, pp. 1037-1039
-
-
Rohde, J.-U.1
In, J.-H.2
Lim, M.H.3
Brennessel, W.W.4
Bukowski, M.R.5
Stubna, A.6
Munck, E.7
Nam, W.8
Que Jr., L.9
-
42
-
-
33947491127
-
Complexes of cobalt(III) with a cyclic tetradentate secondary amine
-
Bosnich, B., Poon, C. K. & Tobe, M. L. Complexes of Cobalt(III) with a cyclic tetradentate secondary amine. Inorg. Chem. 4, 1102-1108 (1965).
-
(1965)
Inorg. Chem.
, vol.4
, pp. 1102-1108
-
-
Bosnich, B.1
Poon, C.K.2
Tobe, M.L.3
-
43
-
-
77956042984
-
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer
-
Fukuzumi, S. et al. Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer. Nat. Chem. 2, 756-759 (2010).
-
(2010)
Nat. Chem.
, vol.2
, pp. 756-759
-
-
Fukuzumi, S.1
-
44
-
-
34547732579
-
The road to non-heme oxoferryls and beyond
-
Que, L. Jr. The road to non-heme oxoferryls and beyond. Acc. Chem. Res. 40, 493-500 (2007).
-
(2007)
Acc. Chem. Res.
, vol.40
, pp. 493-500
-
-
Que Jr., L.1
-
45
-
-
54749095431
-
Proton- and reductant-assisted dioxygen activation by a non-heme iron(II) complex to form an oxoiron(IV) intermediate
-
Thibon, A. et al. Proton- and reductant-assisted dioxygen activation by a non-heme iron(II) complex to form an oxoiron(IV) intermediate. Angew. Chem. Int. Ed. 47, 7064-7067 (2008).
-
(2008)
Angew. Chem. Int. Ed.
, vol.47
, pp. 7064-7067
-
-
Thibon, A.1
-
46
-
-
0034636867
-
2
-
DOI 10.1126/science.289.5481.938
-
2. Science 289, 938-941 (2000). (Pubitemid 30659944)
-
(2000)
Science
, vol.289
, Issue.5481
, pp. 938-941
-
-
MacBeth, C.E.1
Golombek, A.P.2
Young V.G., Jr.3
Yang, C.4
Kuczera, K.5
Hendrich, M.P.6
Borovik, A.S.7
-
47
-
-
27744591940
-
Biochemistry: A thiolate-ligated nonheme oxoiron(IV) complex relevant to cytochrome P450
-
DOI 10.1126/science.1119092
-
Bukowski, M. R. et al. A thiolate-ligated nonheme oxoiron(IV) complex relevant to Cytochrome P450. Science 310, 1000-1002 (2005). (Pubitemid 41611908)
-
(2005)
Science
, vol.310
, Issue.5750
, pp. 1000-1002
-
-
Bukowski, M.R.1
Koehntop, K.D.2
Stubna, A.3
Bominaar, E.L.4
Halfen, J.A.5
Munck, E.6
Nam, W.7
Que Jr., L.8
-
48
-
-
78149373621
-
Cytochrome P450 compound I: Capture, characterization, and C-H bond activation kinetics
-
Rittle, J. & Green, M. T. Cytochrome P450 compound I: capture, characterization, and C-H bond activation kinetics. Science 330, 933-937 (2010).
-
(2010)
Science
, vol.330
, pp. 933-937
-
-
Rittle, J.1
Green, M.T.2
-
50
-
-
33750306877
-
Electrochemical generation of a nonheme oxoiron(IV) complex
-
Collins, M. J., Ray, K. & Que, L. Jr. Electrochemical generation of a nonheme oxoiron(IV) complex. Inorg. Chem. 45, 8009-8011 (2006).
-
(2006)
Inorg. Chem.
, vol.45
, pp. 8009-8011
-
-
Collins, M.J.1
Ray, K.2
Que Jr., L.3
-
51
-
-
79952585894
-
Photo catalytic generation of a non-heme oxoiron(IV) complex with water as an oxygen source
-
Kotani, H., Suenobu, T., Lee, Y.- M., Nam, W. & Fukuzumi, S. Photo catalytic generation of a non-heme oxoiron(IV) complex with water as an oxygen source. J. Am. Chem. Soc. 133, 3249-3251 (2011).
-
(2011)
J. Am. Chem. Soc.
, vol.133
, pp. 3249-3251
-
-
Kotani, H.1
Suenobu, T.2
Lee, Y.-M.3
Nam, W.4
Fukuzumi, S.5
-
52
-
-
77950809921
-
IV=O at a nonheme iron(II) center. Insights into the O-O bond cleavage step
-
IV=O at a nonheme iron(II) center. Insights into the O-O bond cleavage step. J. Am. Chem. Soc. 132, 2134-2135 (2010).
-
(2010)
J. Am. Chem. Soc.
, vol.132
, pp. 2134-2135
-
-
Li, F.1
England, J.2
Que, L.3
-
53
-
-
70349610329
-
Dioxygen activation by mononuclear nonheme iron(II) complexes generates ironoxygen intermediates in the presence of an NADH analogue and proton
-
Hong, S., Lee, Y.- M., Shin, W., Fukuzumi, S. & Nam, W. Dioxygen activation by mononuclear nonheme Iron(II) complexes generates ironoxygen intermediates in the presence of an NADH analogue and proton. J. Am. Chem. Soc. 131, 13910-13911 (2009).
-
(2009)
J. Am. Chem. Soc.
, vol.131
, pp. 13910-13911
-
-
Hong, S.1
Lee, Y.-M.2
Shin, W.3
Fukuzumi, S.4
Nam, W.5
-
54
-
-
77956249891
-
III- OH complex
-
III- OH complex. J. Am. Chem. Soc. 132, 12188-12190 (2010).
-
(2010)
J. Am. Chem. Soc.
, vol.132
, pp. 12188-12190
-
-
Lacy, D.C.1
-
55
-
-
77955401788
-
Dioxygen activation by a non-heme iron(II) complex: Formation of an iron(IV)oxo complex via C-H activation by a putative iron(III)superoxo species
-
Lee, Y- M. et al. Dioxygen activation by a non-heme iron(II) complex: formation of an iron(IV)oxo complex via C-H activation by a putative iron(III)superoxo species. J. Am. Chem. Soc. 132, 10668-10670 (2010).
-
(2010)
J. Am. Chem. Soc.
, vol.132
, pp. 10668-10670
-
-
Lee, Y.-M.1
-
56
-
-
79955879210
-
III-OOH intermediate and its quantitative conversion to an fe O complex
-
III-OOH intermediate and its quantitative conversion to an Fe O Complex. J. Am. Chem. Soc. 133, 7256-7259 (2011).
-
(2011)
J. Am. Chem. Soc.
, vol.133
, pp. 7256-7259
-
-
Li, F.1
-
57
-
-
80054994558
-
Structure and reactivity of a mononuclear non-haem iron(III)-peroxo complex
-
Cho, J. et al. Structure and reactivity of a mononuclear non-haem iron(III)-peroxo complex. Nature 478, 502-505 (2011).
-
(2011)
Nature
, vol.478
, pp. 502-505
-
-
Cho, J.1
-
58
-
-
27544486220
-
IV=O: Spectroscopic identification and oxo-group exchange
-
DOI 10.1002/anie.200502686
-
Pestovsky, O. et al. Aqueous Fe=O: spectroscopic identification and oxo-group exchange. Angew. Chem. Int. Ed. 44, 6871-6874 (2005). (Pubitemid 41546531)
-
(2005)
Angewandte Chemie - International Edition
, vol.44
, Issue.42
, pp. 6871-6874
-
-
Pestovsky, O.1
Stoian, S.2
Bominaar, E.L.3
Shan, X.4
Munck, E.5
Que Jr., L.6
Bakac, A.7
-
59
-
-
70349972275
-
A synthetic high-spin oxoiron(IV) complex: Generation, spectroscopic characterization, and reactivity
-
England, J. et al. A synthetic high-spin Oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity. Angew. Chem. Int. Ed. 48, 3622-3626 (2009).
-
(2009)
Angew. Chem. Int. Ed.
, vol.48
, pp. 3622-3626
-
-
England, J.1
-
60
-
-
77955457770
-
The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway
-
England, J. et al. The crystal structure of a high-spin Oxoiron(IV) complex and characterization of its self-decay pathway. J. Am. Chem. Soc. 132, 8635-8644 (2010).
-
(2010)
J. Am. Chem. Soc.
, vol.132
, pp. 8635-8644
-
-
England, J.1
-
61
-
-
34547725316
-
Reactivity of high-valent iron-oxo species in enzymes and synthetic reagents: A tale of many states
-
Shaik, S., Hirao, H. & Kumar, D. Reactivity of high-valent iron-oxo species in enzymes and synthetic reagents: a tale of many states. Acc. Chem. Res. 40, 532-542 (2007).
-
(2007)
Acc. Chem. Res.
, vol.40
, pp. 532-542
-
-
Shaik, S.1
Hirao, H.2
Kumar, D.3
-
62
-
-
77956054916
-
Theoretical predictions of a highly reactive non-heme fe=O complex with a high-spin ground state
-
Cho, K.- B., Shaik, S. & Nam, W. Theoretical predictions of a highly reactive non-heme Fe=O complex with a high-spin ground state. Chem. Commun. 46, 4511-4513 (2010).
-
(2010)
Chem. Commun.
, vol.46
, pp. 4511-4513
-
-
Cho, K.-B.1
Shaik, S.2
Nam, W.3
-
63
-
-
79952150252
-
Nonheme oxo-iron(IV) intermediates form an oxyl radical upon approaching the C-H bond activation transition state
-
Ye, S. & Neese, F. Nonheme oxo-iron(IV) intermediates form an oxyl radical upon approaching the C-H bond activation transition state. Proc. Natl Acad. Sci. USA 108, 1228-1233 (2011).
-
(2011)
Proc. Natl Acad. Sci. USA
, vol.108
, pp. 1228-1233
-
-
Ye, S.1
Neese, F.2
-
64
-
-
79957845133
-
A mononuclear nonheme iron(IV)-oxo complex which is more reactive than cytochrome P450 model compound I
-
Seo, M. S. et al. A mononuclear nonheme iron(IV)-oxo complex which is more reactive than cytochrome P450 model compound I. Chem. Sci. 2, 1039-1045 (2011).
-
(2011)
Chem. Sci.
, vol.2
, pp. 1039-1045
-
-
Seo, M.S.1
-
65
-
-
37649000653
-
Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction
-
Sastri, C. V. et al. Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction. Proc. Natl Acad. Sci. USA 104, 19181-19186 (2007).
-
(2007)
Proc. Natl Acad. Sci. USA
, vol.104
, pp. 19181-19186
-
-
Sastri, C.V.1
-
66
-
-
33746604011
-
Propene activation by the oxo-iron active species of taurine/α- ketoglutarate dioxygenase (TauD) enzyme. How does the catalysis compare to heme-enzymes?
-
DOI 10.1021/ja061581g
-
de Visser, S. P. Propene activation by the Oxo-iron active species of Taurine/α-Ketoglutarate Dioxygenase (TauD) enzyme. How does the catalysis compare to heme-enzymes? J. Am. Chem. Soc. 128, 9813-9824 (2006). (Pubitemid 44150528)
-
(2006)
Journal of the American Chemical Society
, vol.128
, Issue.30
, pp. 9813-9824
-
-
De Visser, S.P.1
-
67
-
-
77951678517
-
The fundamental role of exchange-enhanced reactivity in C-H activation by S=2 oxo iron(IV) complexes
-
Janardanan, D., Wang, Y, Schyman, P., Que, L. Jr. & Shaik, S. The fundamental role of exchange-enhanced reactivity in C-H activation by S=2 oxo iron(IV) complexes. Angew. Chem. Int. Ed. 49, 3342-3345 (2010).
-
(2010)
Angew. Chem. Int. Ed.
, vol.49
, pp. 3342-3345
-
-
Janardanan, D.1
Wang, Y.2
Schyman, P.3
Que Jr., L.4
Shaik, S.5
-
69
-
-
65249121351
-
Peroxo and oxo intermediates in mononuclear nonheme iron enzymes and related active sites
-
Solomon, E. I., Wong, S. D., Liu, L. V., Decker, A. & Chow, M. S. Peroxo and oxo intermediates in mononuclear nonheme iron enzymes and related active sites. Curr. Opin. Chem. Biol. 13, 99-113 (2009).
-
(2009)
Curr. Opin. Chem. Biol.
, vol.13
, pp. 99-113
-
-
Solomon, E.I.1
Wong, S.D.2
Liu, L.V.3
Decker, A.4
Chow, M.S.5
-
70
-
-
0030614503
-
2 diamond core structure for the key intermediate Q of methane monooxygenase
-
DOI 10.1126/science.275.5299.515
-
2 diamond core structure for the key intermediate Q of methane monooxygenase. Science 275, 515-518 (1997). (Pubitemid 27051903)
-
(1997)
Science
, vol.275
, Issue.5299
, pp. 515-518
-
-
Shu, L.1
Nesheim, J.C.2
Kauffmann, K.3
Munck, E.4
Lipscomb, J.D.5
Que Jr., L.6
-
71
-
-
38049169173
-
2] diamond core proposed for methane monooxygenase intermediate Q
-
2] diamond core proposed for methane monooxygenase intermediate Q. Proc. Natl Acad. Sci. USA 104, 20713-20718 (2007).
-
(2007)
Proc. Natl Acad. Sci. USA
, vol.104
, pp. 20713-20718
-
-
Xue, G.1
-
73
-
-
58549096706
-
Insights into the P-to-Q conversion in the catalytic cycle of methane monooxygenase from a synthetic model system
-
Xue, G., Fiedler, A. T., Martinho, M., Münck, E. & Que, L. Insights into the P-to-Q conversion in the catalytic cycle of methane monooxygenase from a synthetic model system. Proc. Natl Acad. Sci. USA 105, 20615-20620 (2008).
-
(2008)
Proc. Natl Acad. Sci. USA
, vol.105
, pp. 20615-20620
-
-
Xue, G.1
Fiedler, A.T.2
Martinho, M.3
Münck, E.4
Que, L.5
-
75
-
-
0037031703
-
Nitrogenase MoFe-protein at 1.16 A resolution: A central ligand in the FeMo-cofactor
-
DOI 10.1126/science.1073877
-
Einsle, O. et al. Nitrogenase MoFe-protein at 1.16. Å. resolution: a central ligand in the FeMo-cofactor. Science 297, 1696-1700 (2002). (Pubitemid 35000783)
-
(2002)
Science
, vol.297
, Issue.5587
, pp. 1696-1700
-
-
Einsle, O.1
Tezcan, F.A.2
Andrade, S.L.A.3
Schmid, B.4
Yoshida, M.5
Howard, J.B.6
Rees, D.C.7
-
77
-
-
33748534826
-
Self-assembly of a tetradecanuclear iron nitride cluster
-
DOI 10.1002/anie.200601570
-
Bennett, M. V. & Holm, R. H. Self-assembly of a tetradecanuclear iron nitride cluster. Angew. Chem. Int. Ed. 45, 5613-5616 (2006). (Pubitemid 44366759)
-
(2006)
Angewandte Chemie - International Edition
, vol.45
, Issue.34
, pp. 5613-5616
-
-
Bennett, M.V.1
Holm, R.H.2
-
79
-
-
79953905029
-
Catalytic C-H bond amination from high-spin iron imido complexes
-
King, E. R., Hennessy, E. T. & Betley, T. A. Catalytic C-H bond amination from high-spin iron imido complexes. J. Am. Chem. Soc. 133, 4917-4923 (2011).
-
(2011)
J. Am. Chem. Soc.
, vol.133
, pp. 4917-4923
-
-
King, E.R.1
Hennessy, E.T.2
Betley, T.A.3
-
80
-
-
0000290295
-
Resonance Raman spectra of nitridoiron(V) porphyrin intermediates produced by laser photolysis
-
Wagner, W. D. & Nakamoto, K. Resonance Raman spectra of nitridoiron(V) porphyrin intermediates produced by laser photolysis. J. Am. Chem. Soc. 111, 1590-1598 (1989).
-
(1989)
J. Am. Chem. Soc.
, vol.111
, pp. 1590-1598
-
-
Wagner, W.D.1
Nakamoto, K.2
-
82
-
-
18844417470
-
+: A genuine iron(v) species with a ground-state spin S = 1/2
-
DOI 10.1002/anie.200462368
-
+: a genuine iron(V) species with a ground-state Spin S=1/2. Angew. Chem. Int. Ed. 44, 2908-2912 (2005). (Pubitemid 40689670)
-
(2005)
Angewandte Chemie - International Edition
, vol.44
, Issue.19
, pp. 2908-2912
-
-
Aliaga-Alcalde, N.1
DeBeer George, S.2
Mienert, B.3
Bill, E.4
Wieghardt, K.5
Neese, F.6
-
83
-
-
34548809198
-
Characterization of a genuine iron(V)-nitrido species by nuclear resonant vibrational spectroscopy coupled to density functional calculations
-
DOI 10.1021/ja070792y
-
Petrenko, T. et al. Characterization of a genuine iron(V)nitrido species by nuclear resonant vibrational spectroscopy coupled to density functional calculations. J. Am. Chem. Soc. 129, 11053-11060 (2007). (Pubitemid 47435708)
-
(2007)
Journal of the American Chemical Society
, vol.129
, Issue.36
, pp. 11053-11060
-
-
Petrenko, T.1
George, S.D.2
Aliaga-Alcalde, N.3
Bill, E.4
Mienert, B.5
Xiao, Y.6
Guo, Y.7
Sturhahn, W.8
Cramer, S.P.9
Wieghardt, K.10
Neese, F.11
-
84
-
-
33745609775
-
An octahedral coordination complex of iron(VI)
-
DOI 10.1126/science.1128506
-
Berry, J. F. et al. An octahedral coordination complex of Iron(VI). Science 312, 1937-1941 (2006). (Pubitemid 43993717)
-
(2006)
Science
, vol.312
, Issue.5782
, pp. 1937-1941
-
-
Berry, J.F.1
Bill, E.2
Bothe, E.3
George, S.D.4
Mienert, B.5
Neese, F.6
Wieghardt, K.7
-
86
-
-
34547190214
-
XAS characterization of a nitridoiron(IV) complex with a very short fe-N bond
-
Rohde, J.- U. et al. XAS characterization of a nitridoiron(IV) complex with a very short Fe-N bond. Inorg. Chem. 46, 5720-5726 (2007).
-
(2007)
Inorg. Chem.
, vol.46
, pp. 5720-5726
-
-
Rohde, J.-U.1
-
87
-
-
41949118097
-
An iron nitride complex
-
Vogel, C., Heinemann, F. W., Sutter, J., Anthon, C. & Meyer, K. An iron nitride complex. Angew. Chem. Int. Ed. 47, 2681-2684 (2008).
-
(2008)
Angew. Chem. Int. Ed.
, vol.47
, pp. 2681-2684
-
-
Vogel, C.1
Heinemann, F.W.2
Sutter, J.3
Anthon, C.4
Meyer, K.5
-
88
-
-
0032578159
-
Nitridomanganese(V) and -(VI) complexes containing macrocyclic amine ligands
-
DOI 10.1021/ja980686j
-
Meyer, K., Bendix, J., Metzler-Nolte, N., Weyhermüller, T. & Wieghardt, K. Nitridomanganese(V) and -(VI) complexes containing macrocyclic amine ligands. J. Am. Chem. Soc. 120, 7260-7270 (1998). (Pubitemid 28389351)
-
(1998)
Journal of the American Chemical Society
, vol.120
, Issue.29
, pp. 7260-7270
-
-
Meyer, K.1
Bendix, J.2
Metzler-Nolte, N.3
Weyhermuller, T.4
Wieghardt, K.5
-
89
-
-
0035966477
-
Homoleptic carbene complexes: Part IX. Bis(imidazolin-2-ylidene-1-yl) borate complexes of palladium(II), platinum(II) and gold(I)
-
DOI 10.1016/S0020-1693(00)00323-6, PII S0020169300003236
-
Fränkel, R. et al. Homoleptic carbene complexes: Part IX. Bis(imidazolin-2-ylidene-1-yl)borate complexes of palladium(II), platinum(II) and gold(I). Inorg. Chim. Acta 312, 23-39 (2001). (Pubitemid 32168087)
-
(2001)
Inorganica Chimica Acta
, vol.312
, Issue.1-2
, pp. 23-39
-
-
Frankel, R.1
Kniczek, J.2
Ponikwar, W.3
Noth, H.4
Polborn, K.5
Fehlhammer, W.P.6
-
90
-
-
49449089944
-
Structural and spectroscopic characterization of an electrophilic iron nitrido complex
-
Scepaniak, J. J. et al. Structural and spectroscopic characterization of an electrophilic iron nitrido complex. J. Am. Chem. Soc. 130, 10515-10517 (2008).
-
(2008)
J. Am. Chem. Soc.
, vol.130
, pp. 10515-10517
-
-
Scepaniak, J.J.1
-
91
-
-
79952747772
-
Spin crossover in a four-coordinate iron(II) complex
-
Scepaniak, J. J. et al. Spin crossover in a four-coordinate iron(II) complex. J. Am. Chem. Soc. 133, 3824-3827 (2011).
-
(2011)
J. Am. Chem. Soc.
, vol.133
, pp. 3824-3827
-
-
Scepaniak, J.J.1
-
92
-
-
79952060575
-
Synthesis, structure, and reactivity of an iron(V) nitride
-
Scepaniak, J. J. et al. Synthesis, structure, and reactivity of an Iron(V) nitride. Science 331, 1049-1052 (2011).
-
(2011)
Science
, vol.331
, pp. 1049-1052
-
-
Scepaniak, J.J.1
-
93
-
-
33748222041
-
5+ structural elements
-
5+ structural elements. Angew. Chem. Int. Ed. 34, 669-672 (1995).
-
(1995)
Angew. Chem. Int. Ed.
, vol.34
, pp. 669-672
-
-
Justel, T.1
-
94
-
-
0017319319
-
Metal-metal interactions involving metal-loporphyrins. III. Conversion of tetraphenylporphinatoiron(III) azide to an N-bridged hemin dimer
-
Summerville, D. A. & Cohen, I. A. Metal-metal interactions involving metal-loporphyrins. III. Conversion of tetraphenylporphinatoiron(III) azide to an N-bridged hemin dimer. J. Am. Chem. Soc. 98, 1747-1752 (1976).
-
(1976)
J. Am. Chem. Soc.
, vol.98
, pp. 1747-1752
-
-
Summerville, D.A.1
Cohen, I.A.2
-
95
-
-
0039725130
-
5+ (S = 0) cores
-
5+ (S=0) cores. Chemistry - A European J. 5, 793-810 (1999). (Pubitemid 129504186)
-
(1999)
Chemistry - A European Journal
, vol.5
, Issue.2
, pp. 793-810
-
-
Justel, T.1
Muller, M.2
Weyhermuller, T.3
Kressl, C.4
Bill, E.5
Hildebrandt, P.6
Lengen, M.7
Grodzicki, M.8
Trautwein, A.X.9
Nuber, B.10
Wieghardt, K.11
-
96
-
-
0000820085
-
Selective intermolecular carbon-hydrogen bond activation by synthetic metal complexes in homogeneous solution
-
Arndtsen, B. A., Bergman, R. G., Mobley, T. A. & Peterson, T. H. Selective intermolecular carbon-hydrogen bond activation by synthetic metal complexes in homogeneous solution. Acc. Chem. Res. 28, 154-162 (1995).
-
(1995)
Acc. Chem. Res.
, vol.28
, pp. 154-162
-
-
Arndtsen, B.A.1
Bergman, R.G.2
Mobley, T.A.3
Peterson, T.H.4
-
97
-
-
84857516597
-
O-O bond formation mediated by a hexanuclear iron complex supported on a stannoxane core
-
doi:10.1002/chem.201102326
-
Kundu, S. et al. O-O Bond formation mediated by a hexanuclear iron complex supported on a Stannoxane core. Chemistry - A European J., doi:10.1002/ chem.201102326 (2012).
-
(2012)
Chemistry - A European J.
-
-
Kundu, S.1
-
98
-
-
42149103898
-
Theoretical studies of O-O bond formation in photosystem II
-
Siegbahn, P. E. M. Theoretical studies of O-O bond formation in photosystem II. Inorg. Chem. 47, 1779-1786 (2008).
-
(2008)
Inorg. Chem.
, vol.47
, pp. 1779-1786
-
-
Siegbahn, P.E.M.1
|