A synthetic high-spin oxoiron(IV) complex: Generation, spectro-scopic characterization, and reactivity

Angewandte Chemie - International Edition

Volumn 48, Issue 20, 2009, Pages 3622-3626

  England, Jason ^b   Martinho, Marlène ^a   Farquhar, Erik R ^b   Frisch, Jonathan R ^b   Bominaar, Emile L ^a   Münck, Eckard ^a   Que Jr , Lawrence ^b  

^a CARNEGIE MELLON UNIVERSITY   (United States)

^b University of Minnesota   (United States)

Author keywords

Bioinorganic chemistry; Enzyme models; High valent compounds; Iron; Nonheme iron complexes

Indexed keywords

BIOINORGANIC CHEMISTRY; ENZYME MODELS; HIGH-VALENT COMPOUNDS; IRON CENTERS; NONHEME IRON COMPLEXES; OXOIRON; TETRADENTATE; TRIGONAL BIPYRAMIDAL GEOMETRY;

AMINES; BIOCHEMISTRY; ENZYMES; SPIN DYNAMICS;

IRON COMPOUNDS;

FE(IV)(O)(1,1,1-TRIS(2-(N2-(1,1,3,3-TETRAMETHYLGUANIDINO))THYL)AMINE); FERROUS ION; OXIDIZING AGENT;

CHEMISTRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS;

FERROUS COMPOUNDS; MAGNETIC RESONANCE SPECTROSCOPY; OXIDANTS;

EID: 70349972275     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200900863     Document Type: Article

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