메뉴 건너뛰기




Volumn 2, Issue 7, 2010, Pages 558-565

Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; COORDINATION COMPOUND; DIAZENE; IMIDE; IRON; LIGAND; NITROGEN; SILICON;

EID: 77953998181     PISSN: 17554330     EISSN: 17554349     Source Type: Journal    
DOI: 10.1038/nchem.660     Document Type: Article
Times cited : (267)

References (42)
  • 1
    • 68049104344 scopus 로고    scopus 로고
    • Characterization of structurally unusual diiron NxHy complexes
    • Saouma, C. T., Müller, P. & Peters, J. C. Characterization of structurally unusual diiron NxHy complexes. J. Am. Chem. Soc. 131, 10358-10359 (2009).
    • (2009) J. Am. Chem. Soc. , vol.131 , pp. 10358-10359
    • Saouma, C.T.1    Müller, P.2    Peters, J.C.3
  • 2
    • 59849091037 scopus 로고    scopus 로고
    • Base-mediated conversion of hydrazine to diazene and dinitrogen at an iron center
    • Field, L. D., Li, H. L. & Magill, A. M. Base-mediated conversion of hydrazine to diazene and dinitrogen at an iron center. Inorg. Chem. 48, 5-7 (2009).
    • (2009) Inorg. Chem. , vol.48 , pp. 5-7
    • Field, L.D.1    Li, H.L.2    Magill, A.M.3
  • 4
    • 11144310104 scopus 로고    scopus 로고
    • Syntheses structures and reactivity of electron-rich Fe and Ru complexes with the new pentadentate ligand Et2NpyS4-H2 {4-(diethylamino)-2,6-bis[(2- mercaptophenyl) thiomethyl]pyridine}
    • Sellmann, D., Shaban, S. Y. & Heinemann, F. W. Syntheses, structures and reactivity of electron-rich Fe and Ru complexes with the new pentadentate ligand Et2NpyS4-H2 {4-(diethylamino)-2,6-bis[(2-mercaptophenyl) thiomethyl]pyridine}. Eur. J. Inorg. Chem. 4591-4601 (2004).
    • (2004) Eur. J. Inorg. Chem. , pp. 4591-4601
    • Sellmann, D.1    Shaban, S.Y.2    Heinemann, F.W.3
  • 6
    • 34250158429 scopus 로고    scopus 로고
    • 2 reduction
    • 2 reduction. Biochemistry 46, 6784-6794 (2007).
    • (2007) Biochemistry , vol.46 , pp. 6784-6794
    • Barney, B.M.1
  • 7
    • 33751232674 scopus 로고    scopus 로고
    • A methyldiazene (HN = N-CH3)-derived species bound to the nitrogenase active-site FeMo cofactor: Implications for mechanism
    • Barney, B. M. et al. A methyldiazene (HN = N-CH3)-derived species bound to the nitrogenase active-site FeMo cofactor: implications for mechanism. Proc. Natl Acad. Sci. USA 103, 17113-17118 (2006).
    • (2006) Proc. Natl Acad. Sci. USA , vol.103 , pp. 17113-17118
    • Barney, B.M.1
  • 8
    • 27544492629 scopus 로고    scopus 로고
    • Intermediates trapped during nitrogenase reduction of N;N, CH32N=NH, and H2N-NH2
    • Barney, B. M. et al. Intermediates trapped during nitrogenase reduction of N;N, CH32N=NH, and H2N-NH2. J. Am. Chem. Soc. 127, 14960-14961 (2005).
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 14960-14961
    • Barney, B.M.1
  • 9
    • 33751224183 scopus 로고    scopus 로고
    • 2)FeI, FeIV;N, and related species
    • 2)FeI, FeIV;N, and related species. Proc. Natl Acad. Sci. USA 103, 17107-17112 (2006).
    • (2006) Proc. Natl Acad. Sci. USA , vol.103 , pp. 17107-17112
    • Hendrich, M.P.1
  • 10
    • 21744458724 scopus 로고    scopus 로고
    • Synthesis and characterization of cationic iron complexes supported by the neutral ligands NPi-Pr 3 NArPi-Pr 3 and NSt-Bu 3
    • MacBeth, C. E., Harkins, S. B. & Peters, J. C. Synthesis and characterization of cationic iron complexes supported by the neutral ligands NPi-Pr 3, NArPi-Pr 3, and NSt-Bu 3. Can. J. Chem. 83, 332-340 (2005).
    • (2005) Can. J. Chem. , vol.83 , pp. 332-340
    • MacBeth, C.E.1    Harkins, S.B.2    Peters, J.C.3
  • 11
    • 0037433228 scopus 로고    scopus 로고
    • Modeling a central ligand in the nitrogenase FeMo cofactor
    • Hinnemann, B. & Nørskov, J. K., Modeling a central ligand in the nitrogenase FeMo cofactor. J. Am. Chem. Soc. 125, 1466-1467 (2003).
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 1466-1467
    • Hinnemann, B.1    Nørskov, J.K.2
  • 12
    • 34547470503 scopus 로고    scopus 로고
    • 2 and Fe(II) H-C interactions supported by tris(phosphino)silyl ligands
    • 2 and Fe(II) H-C interactions supported by tris(phosphino)silyl ligands. Angew. Chem. Int. Ed. 46, 5768-5771 (2007).
    • (2007) Angew. Chem. Int. Ed. , vol.46 , pp. 5768-5771
    • Mankad, N.P.1    Whited, M.T.2    Peters, J.C.3
  • 13
    • 64349091071 scopus 로고    scopus 로고
    • Dinitrogen complexes supported by tris(phosphino)silyl ligands
    • Whited, M. T., Mankad, N. P., Lee, Y., Oblad, P. F. & Peters, J. C. Dinitrogen complexes supported by tris(phosphino)silyl ligands. Inorg. Chem. 48, 2507-2517 (2009).
    • (2009) Inorg. Chem. , vol.48 , pp. 2507-2517
    • Whited, M.T.1    Mankad, N.P.2    Lee, Y.3    Oblad, P.F.4    Peters, J.C.5
  • 14
    • 76149117785 scopus 로고    scopus 로고
    • Synthesis and molecular and electronic structures of reduced bis(imino)pyridine cobalt dinitrogen complexes: Ligand versus metal reduction
    • Bowman, A. C. et al. Synthesis and molecular and electronic structures of reduced bis(imino)pyridine cobalt dinitrogen complexes: ligand versus metal reduction. J. Am. Chem. Soc. 132, 1676-1684 (2010).
    • (2010) J. Am. Chem. Soc. , vol.132 , pp. 1676-1684
    • Bowman, A.C.1
  • 15
    • 0043236213 scopus 로고    scopus 로고
    • Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms
    • Betley, T. A. & Peters, J. C. Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms. J. Am. Chem. Soc. 125, 10782-10783 (2003).
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 10782-10783
    • Betley, T.A.1    Peters, J.C.2
  • 16
    • 37049096497 scopus 로고
    • Synthesis structure and spectroscopic properties of copper(II) compounds containing nitrogen-sulfur donor ligands; The crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(II) perchlorate
    • Addison, A.W., Rao, T. N., Reedijk, J., Van Rijn, J. & Verschoor, G. C. Synthesis, structure and spectroscopic properties of copper(II) compounds containing nitrogen-sulfur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(II) perchlorate. J. Chem. Soc. Dalton Trans. 1349-1356 (1984).
    • (1984) J. Chem. Soc. Dalton Trans. , pp. 1349-1356
    • Addison, A.W.1    Rao, T.N.2    Reedijk, J.3    Van Rijn, J.4    Verschoor, G.C.5
  • 17
    • 13944266333 scopus 로고    scopus 로고
    • Studies relevant to catalytic reduction of dinitrogen to ammonia by molybdenum triamidoamine complexes
    • Yandulov, D. V. & Schrock, R. R. Studies relevant to catalytic reduction of dinitrogen to ammonia by molybdenum triamidoamine complexes. Inorg. Chem. 44, 1103-1117 (2005).
    • (2005) Inorg. Chem. , vol.44 , pp. 1103-1117
    • Yandulov, D.V.1    Schrock, R.R.2
  • 18
    • 41149167630 scopus 로고    scopus 로고
    • The first side-on bound metal complex of diazene, HN=NH
    • Field, L. D., Li, H. L., Dalgarno, S. J. & Turner, P. The first side-on bound metal complex of diazene, HN=NH. Chem. Commun. 1680-1682 (2008).
    • (2008) Chem. Commun. , pp. 1680-1682
    • Field, L.D.1    Li, H.L.2    Dalgarno, S.J.3    Turner, P.4
  • 19
    • 37349043186 scopus 로고    scopus 로고
    • Synthesis and characterization of an iron(II) h2-hydrazine complex
    • Crossland, J. L., Zakharov, L. N. & Tyler, D. R. Synthesis and characterization of an iron(II) h2-hydrazine complex. Inorg. Chem. 46, 10476-10478 (2007).
    • (2007) Inorg. Chem. , vol.46 , pp. 10476-10478
    • Crossland, J.L.1    Zakharov, L.N.2    Tyler, D.R.3
  • 20
    • 34347355564 scopus 로고    scopus 로고
    • Borane B-C bond cleavage by a lowcoordinate iron hydride complex and N-N bond cleavage by the hydridoborate product
    • Yu, Y., Brennessel, W. W. & Holland, P. L. Borane B-C bond cleavage by a lowcoordinate iron hydride complex and N-N bond cleavage by the hydridoborate product. Organometallics 26, 3217-3226 (2007).
    • (2007) Organometallics , vol.26 , pp. 3217-3226
    • Yu, Y.1    Brennessel, W.W.2    Holland, P.L.3
  • 21
    • 23944483411 scopus 로고    scopus 로고
    • Interaction of manganese(II), iron(II), cobalt(II), nickel(II), copper(II) and zinc(II) with acetylhydrazine, formed in situ; First crystal structure of tris(acetylhydrazine) nickel(II) perchlorate
    • Shakir, M., Parveen, S., Begum, N. & Azim, Y. Interaction of manganese(II), iron(II), cobalt(II), nickel(II), copper(II) and zinc(II) with acetylhydrazine, formed in situ; first crystal structure of tris(acetylhydrazine) nickel(II) perchlorate. Trans. Metal Chem. 29, 916-920 (2004).
    • (2004) Trans. Metal Chem. , vol.29 , pp. 916-920
    • Shakir, M.1    Parveen, S.2    Begum, N.3    Azim, Y.4
  • 24
    • 0000909981 scopus 로고
    • 2H4)2(O2CNHNH2)2], and the cyclic biferrocene diazine, [-N(Me)CC5H4FeC5H4C(Me)N-]2
    • 2H4)2(O2CNHNH2)2], and the cyclic biferrocene diazine, [-N(Me)CC5H4FeC5H4C(Me)N-]2. Polyhedron 10, 483-489 (1991).
    • (1991) Polyhedron , vol.10 , pp. 483-489
    • Casey, M.T.1
  • 25
    • 0017313650 scopus 로고
    • Carbon monoxide complexes of iron(II): Synthesis and structural studies of five- and six-coordinate complexes of the macrocyclic ligand, C22H22N4 22
    • Goedken, V. L., Peng, S.-M., Molin-Norris, J. & Park, Y.-A. Carbon monoxide complexes of iron(II): synthesis and structural studies of five- and six-coordinate complexes of the macrocyclic ligand, C22H22N4 22. J. Am. Chem. Soc. 98, 8391-8400 (1976).
    • (1976) J. Am. Chem. Soc. , vol.98 , pp. 8391-8400
    • Goedken, V.L.1    Peng, S.-M.2    Molin-Norris, J.3    Park, Y.-A.4
  • 26
    • 0034617566 scopus 로고    scopus 로고
    • Vanadium complexes of the N(CH2CH2S)3 32 and O(CH2CH2S)2 22 ligands with coligands relevant to nitrogen fixation processes
    • Davies, S. C. et al. Vanadium complexes of the N(CH2CH2S)3 32 and O(CH2CH2S)2 22 ligands with coligands relevant to nitrogen fixation processes. Inorg. Chem. 39, 3485-3498 (2000).
    • (2000) Inorg. Chem. , vol.39 , pp. 3485-3498
    • Davies, S.C.1
  • 27
    • 34250743509 scopus 로고    scopus 로고
    • Main group heterocycles from lithiated phosphinimines
    • Alhomaidan, O., Hollink, E. & Stephan, D. W. Main group heterocycles from lithiated phosphinimines. Organometallics 26, 3041-3048 (2007).
    • (2007) Organometallics , vol.26 , pp. 3041-3048
    • Alhomaidan, O.1    Hollink, E.2    Stephan, D.W.3
  • 28
    • 34548595391 scopus 로고    scopus 로고
    • Organogold(II) iminophosphorane complexes as efficient catalysts in the addition of 2-methylfuran and electron-rich arenes to methyl vinyl ketone
    • Aguilar, D., Contel, M., Navarro, R. & Urriolabeitia, E. P. Organogold(II) iminophosphorane complexes as efficient catalysts in the addition of 2-methylfuran and electron-rich arenes to methyl vinyl ketone. Organometallics 26, 4604-4611 (2007).
    • (2007) Organometallics , vol.26 , pp. 4604-4611
    • Aguilar, D.1    Contel, M.2    Navarro, R.3    Urriolabeitia, E.P.4
  • 29
    • 18844400064 scopus 로고    scopus 로고
    • Synthesis structure, reactivity, and catalytic activity of C,N- and C,N,N-orthopalladated iminophosphoranes
    • Bielsa, R., Larrea, A., Navarro, R., Soler, T. & Urriolabeitia, E. P. Synthesis, structure, reactivity, and catalytic activity of C,N- and C,N,N-orthopalladated iminophosphoranes. Eur. J. Inorg. Chem. 1724-1736 (2005).
    • (2005) Eur. J. Inorg. Chem. , pp. 1724-1736
    • Bielsa, R.1    Larrea, A.2    Navarro, R.3    Soler, T.4    Urriolabeitia, E.P.5
  • 31
    • 0141619221 scopus 로고    scopus 로고
    • Pyridine- and imidazole-phosphinimine bidentate ligand complexes: Considerations for ethylene oligomerization catalysts
    • Spencer, L. P. et al. Pyridine- and imidazole-phosphinimine bidentate ligand complexes: considerations for ethylene oligomerization catalysts. Organometallics 22, 3841-3854 (2003).
    • (2003) Organometallics , vol.22 , pp. 3841-3854
    • Spencer, L.P.1
  • 32
    • 0012716927 scopus 로고    scopus 로고
    • Iron phosphinimide and phosphinimine complexes: Catalyst precursors for ethylene polymerization
    • LePichon, L., Stephan, D. W., Gao, Z. & Wang, Q. Iron phosphinimide and phosphinimine complexes: catalyst precursors for ethylene polymerization. Organometallics 21, 1362-1366 (2002).
    • (2002) Organometallics , vol.21 , pp. 1362-1366
    • Lepichon, L.1    Stephan, D.W.2    Gao, Z.3    Wang, Q.4
  • 33
    • 23844439213 scopus 로고    scopus 로고
    • Intra- and intermolecular N-H . . . F-C hydrogenbonding interactions in amine adducts of tris(pentafluorophenyl)borane and -alane
    • Mountford, A. J. et al. Intra- and intermolecular N-H . . . F-C hydrogenbonding interactions in amine adducts of tris(pentafluorophenyl)borane and -alane. Inorg. Chem. 44, 5921-5933 (2005).
    • (2005) Inorg. Chem. , vol.44 , pp. 5921-5933
    • Mountford, A.J.1
  • 34
    • 3242877691 scopus 로고    scopus 로고
    • Weak hydrogen bridges: A systematic theoretical study on the nature and strength of C-H F-C interactions
    • Hyla-Kryspin, I., Haufe, G. & Grimme, S. Weak hydrogen bridges: a systematic theoretical study on the nature and strength of C-H F-C interactions. Chem. Eur. J. 10, 3411-3422 (2004).
    • (2004) Chem. Eur. J. , vol.10 , pp. 3411-3422
    • Hyla-Kryspin, I.1    Haufe, G.2    Grimme, S.3
  • 35
    • 0000243556 scopus 로고    scopus 로고
    • Understanding the behavior of halogens as hydrogen bond acceptors
    • Brammer, L., Bruton, E. A. & Sherwood, P. Understanding the behavior of halogens as hydrogen bond acceptors. Cryst. Growth Des. 1, 277-290 (2001).
    • (2001) Cryst. Growth Des. , vol.1 , pp. 277-290
    • Brammer, L.1    Bruton, E.A.2    Sherwood, P.3
  • 36
    • 0034600791 scopus 로고    scopus 로고
    • The C-F . . . cation interaction: An ammonium complex of a hexafluoro macrocyclic cage compound
    • Takemura, H. et al. The C-F . . . cation interaction: an ammonium complex of a hexafluoro macrocyclic cage compound. Chem. Eur. J. 6, 2334 (2000).
    • (2000) Chem. Eur. J. , vol.6 , pp. 2334
    • Takemura, H.1
  • 37
    • 0030590426 scopus 로고    scopus 로고
    • How good is fluorine as a hydrogen bond acceptor?
    • Howard, J. A. K., Hoy, V. J., O'Hagan, D. & Smith, G. T. How good is fluorine as a hydrogen bond acceptor? Tetrahedron 52, 12613-12622 (1996).
    • (1996) Tetrahedron , vol.52 , pp. 12613-12622
    • Howard, J.A.K.1    Hoy, V.J.2    O'Hagan, D.3    Smith, G.T.4
  • 38
    • 0000736056 scopus 로고    scopus 로고
    • Molybdenum and tungsten complexes of the N(CH2CH2S)3 32 (NS3) ligand with oxide, sulfide, diazenide, hydrazide and nitrosyl co-ligands
    • Davies, S. C., Hughes, D. L., Richards, R. L. & Sanders, J. R. Molybdenum and tungsten complexes of the N(CH2CH2S)3 32 (NS3) ligand with oxide, sulfide, diazenide, hydrazide and nitrosyl co-ligands. J. Chem. Soc. Dalton Trans. 719-725 (2000).
    • (2000) J. Chem. Soc. Dalton Trans. , pp. 719-725
    • Davies, S.C.1    Hughes, D.L.2    Richards, R.L.3    Sanders, J.R.4
  • 39
    • 0001328494 scopus 로고    scopus 로고
    • Reactivity of hydrides FeH2(CO)2P2 (P = phosphites) with aryldiazonium cations: Preparation, characterization, X-ray crystal structure, and electrochemical studies of mono- and binuclear aryldiazenido complexes
    • Albertin, G. et al. Reactivity of hydrides FeH2(CO)2P2 (P = phosphites) with aryldiazonium cations: preparation, characterization, X-ray crystal structure, and electrochemical studies of mono- and binuclear aryldiazenido complexes. Inorg. Chem. 37, 5602-5610 (1998).
    • (1998) Inorg. Chem. , vol.37 , pp. 5602-5610
    • Albertin, G.1
  • 41
    • 0039539914 scopus 로고
    • Aryldiazo complexes. Structure of an iron-aryldiazo complex, dicarbonyl bis(triphenylphosphine) benzenediazonium iron(1+) tetrafluoroborate (1-)
    • Haymore, B. L. & Ibers, J. A. Aryldiazo complexes. Structure of an iron-aryldiazo complex, dicarbonyl bis(triphenylphosphine) benzenediazonium iron(1+) tetrafluoroborate (1-). Inorg. Chem. 14, 1369-1376 (1975).
    • (1975) Inorg. Chem. , vol.14 , pp. 1369-1376
    • Haymore, B.L.1    Ibers, J.A.2
  • 42
    • 0037024176 scopus 로고    scopus 로고
    • Reduction of dinitrogen to ammonia at a well-protected reaction site in a molybdenum triamidoamine complex
    • Yandulov, D. V. & Schrock, R. R. Reduction of dinitrogen to ammonia at a well-protected reaction site in a molybdenum triamidoamine complex. J. Am. Chem. Soc. 124, 6252-6253 (2002).
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 6252-6253
    • Yandulov, D.V.1    Schrock, R.R.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.