Synthesis, structure, and reactivity of an iron(V) nitride

Science

Volumn 331, Issue 6020, 2011, Pages 1049-1052

  Scepaniak, Jeremiah J ^a   Vogel, Carola S ^b   Khusniyarov, Marat M ^b   Heinemann, Frank W ^b   Meyer, Karsten ^b   Smith, Jeremy M ^a  

^a NEW MEXICO STATE UNIVERSITY   (United States)

^b UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; FERROUS ION; IRON COMPLEX; IRON NITRIDE; NITRIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

CRYSTAL; ELECTRON; ELECTRON SPIN RESONANCE; IRON; LIGAND; OXIDATION; X-RAY DIFFRACTION;

ARTICLE; CRYSTAL STRUCTURE; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE; LOW TEMPERATURE; OXIDATION; PRIORITY JOURNAL; SYNTHESIS; THERMOSTABILITY; X RAY DIFFRACTION;

CRYSTALLIZATION; CRYSTALLOGRAPHY, X-RAY; ELECTRON SPIN RESONANCE SPECTROSCOPY; FERRIC COMPOUNDS; IRON; LIGANDS; MOLECULAR STRUCTURE; NITROGEN; OXIDATION-REDUCTION; PHYSICOCHEMICAL PROCESSES; SPECTROSCOPY, MOSSBAUER;

EID: 79952060575     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1198315     Document Type: Article

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27. We acknowledge funding from Friedrich-Alexander-University Erlangen-Nuremberg and the Deutsche Forschungsgemeinschaft (K.M.); Fonds der Chemischen Industrie (M.M.K.); and the Department of Energy Office of Basic Energy Sciences (DE-FG02-08ER15996) and the Camille and Henry Dreyfus Foundation ( J.M.S.). J. Sutter is gratefully acknowledged for collecting the spectroscopic data, and K. Wieghardt and E. Bill (Max-Planck-Institut for Bioinorganic Chemistry, Mülheim/Ruhr, Germany) for helpful discussions. The crystallographic data CCDC-786059 (2 at 35 K) and CCDC-786060 (2 at 100 K) can be obtained free at www.ccdc.cam.ac.uk/data-request/cif (or from Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK; fax: ++44-1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).