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Volumn 47, Issue 37, 2008, Pages 7064-7067

Proton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediate

Author keywords

Iron; Macrocyclic ligands; N ligands; O O activation; Oxo ligands

Indexed keywords


EID: 54749095431     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200801832     Document Type: Article
Times cited : (152)

References (26)
  • 6
    • 54749124693 scopus 로고    scopus 로고
    • Abbrevia tions: TMC = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane, TMC-py=1-(2′-pyridylmethyl)-4,8,11-trimethyl-1, 4,8,11-tetraazacyclotetradecane, TPP=dianion of meso-tetraphenylporphyrin, N4Py=N,N-bis(2-pyridylmethyl)-bis(2-pyridyl) methylamine.
    • Abbrevia tions: TMC = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane, TMC-py=1-(2′-pyridylmethyl)-4,8,11-trimethyl-1, 4,8,11-tetraazacyclotetradecane, TPP=dianion of meso-tetraphenylporphyrin, N4Py=N,N-bis(2-pyridylmethyl)-bis(2-pyridyl) methylamine.
  • 10
    • 54749094074 scopus 로고    scopus 로고
    • Single-crystal structure and refinement data for 2(PF 6)2: C19H35F12FeN 5P2, Mr=679.31, monoclinic, space group P21/c, a=9.8438(4, b=9.7471(5, c=28.3527(13) Å, α=90, β=90.803(2, γ=90°, V=2720.1(2) Å3, Z=4, ρcalcd=1.651 Mg m-3, MoKα radiation (λ=0.71073 Å, μ=0.771 mm-1, T=100(1) K. A total of 48672 (R int=0.0468) independent reflections with 2θ<30.71° were collected. The resulting parameters were refined to converge at R 1=0.0839 (I>2σ(I, for 392 parameters and 8407 independent reflections wR2=0.2237, max./min. residual electron density 0.733/0.658 eÅ-3, GOF=1.074. Single-crystal structure and refinement data
    • -3; GOF=1.052. Further experimental details are provided in the Supporting Information. CCDC 683058 and 685380 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
  • 20
  • 25
    • 54749151097 scopus 로고    scopus 로고
    • Ph.D. thesis, Université Paris Sud, Orsay
    • M. Martinho, Ph.D. thesis, Université Paris Sud 11 (Orsay), 2006.
    • (2006) , pp. 11
    • Martinho, M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.