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Volumn 275, Issue 5299, 1997, Pages 515-518

An Fe2/(IV)O2 diamond core structure for the key intermediate Q of methane monooxygenase

Author keywords

[No Author keywords available]

Indexed keywords

DIAMOND; IRON OXIDE; UNSPECIFIC MONOOXYGENASE; FERRYL IRON; IRON; METHANE MONOOXYGENASE; OXYGEN; OXYGENASE;

EID: 0030614503     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.275.5299.515     Document Type: Article
Times cited : (559)

References (41)
  • 16
    • 15644364219 scopus 로고    scopus 로고
    • Intermediate P has been proposed to have a (μ-1,2-peroxo)diiron(III) core on the basis of Mössbauer and resonance Raman studies (34)
    • Intermediate P has been proposed to have a (μ-1,2-peroxo)diiron(III) core on the basis of Mössbauer and resonance Raman studies (34).
  • 17
    • 0029038688 scopus 로고
    • X-ray absorption spectra were collected at Beamline X9B of the National Synchrotron Light Source (NSLS) at Brookhaven National Laboratory. The details of data collection and the procedure of EXAFS data extraction and analysis have been presented (40) [L. Shu et al., Biochemistry 34, 6649 (1995)].
    • (1995) Biochemistry , vol.34 , pp. 6649
    • Shu, L.1
  • 22
    • 15644368581 scopus 로고    scopus 로고
    • note
    • III forms of MMOH, based on their Mössbauer-determined percentages in the freeze-quenched samples. For sample 1, the pre-edge area of Q = {22 units - [(27%)(10 units)] - [(12%)(14 units)]}/61% = 29 units. For sample 2, the pre-edge area of Q = {18 units - [(33%)(10 units)] - [(23%)(14 units)]}/44% = 26 units.
  • 25
    • 0004264772 scopus 로고
    • T. G. Spiro, Ed. Wiley, New York
    • J. M. Berg and R. H. Holm, in Iron-Sulfur Proteins, T. G. Spiro, Ed. (Wiley, New York, 1982), pp. 3-66.
    • (1982) Iron-Sulfur Proteins , pp. 3-66
    • Berg, J.M.1    Holm, R.H.2
  • 30
    • 0030005669 scopus 로고    scopus 로고
    • J. A. Halfen et al., Science 271, 1397 (1996).
    • (1996) Science , vol.271 , pp. 1397
    • Halfen, J.A.1
  • 39
    • 0024294403 scopus 로고
    • and references therein
    • J. H. Dawson, Science 240, 433 (1988) and references therein.
    • (1988) Science , vol.240 , pp. 433
    • Dawson, J.H.1
  • 41
    • 15644383430 scopus 로고    scopus 로고
    • note
    • Supported by NSF grant MCB-9405723 (L.Q.), NIH grants GM-40466 (J.D.L.) and GM-22701 (E.M.), a University of Minnesota Graduate School Doctoral Dissertation Fellowship (L.S.), and an NIH Predoctoral Traineeship (J.C.N., GM-08277). Beamline X9B at the NSLS was supported by NIH grant RR-001633. We thank M. Chance and E. Sheuring at NSLS Beamline X9B for technical guidance.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.