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Intermediate P has been proposed to have a (μ-1,2-peroxo)diiron(III) core on the basis of Mössbauer and resonance Raman studies (34)
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III forms of MMOH, based on their Mössbauer-determined percentages in the freeze-quenched samples. For sample 1, the pre-edge area of Q = {22 units - [(27%)(10 units)] - [(12%)(14 units)]}/61% = 29 units. For sample 2, the pre-edge area of Q = {18 units - [(33%)(10 units)] - [(23%)(14 units)]}/44% = 26 units.
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Supported by NSF grant MCB-9405723 (L.Q.), NIH grants GM-40466 (J.D.L.) and GM-22701 (E.M.), a University of Minnesota Graduate School Doctoral Dissertation Fellowship (L.S.), and an NIH Predoctoral Traineeship (J.C.N., GM-08277). Beamline X9B at the NSLS was supported by NIH grant RR-001633. We thank M. Chance and E. Sheuring at NSLS Beamline X9B for technical guidance.
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