A synthetic precedent for the [FeIV2(μ-O) 2] diamond core proposed for methane monooxygenase intermediate Q

Proceedings of the National Academy of Sciences of the United States of America

Volumn 104, Issue 52, 2007, Pages 20713-20718

  Xue, Genqiang ^a   Wang, Dong ^a   De Hont, Raymond ^b   Fiedler, Adam T ^a   Shan, Xiaopeng ^a   Münck, Eckard ^b   Que Jr , Lawrence ^a  

^a University of Minnesota   (United States)

^b CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

Diiron(IV); Electrochemistry; Iron oxo; Nonheme; Oxygen activation

Indexed keywords

IRON; METHANE; METHANE MONOOXYGENASE; METHANE MONOOXYGENASE INTERMEDIATE Q; UNCLASSIFIED DRUG; CARBON; HYDROGEN; LIGAND; OXYGEN; OXYGENASE;

ARTICLE; CHEMICAL BOND; COMPLEX FORMATION; ELECTROCHEMISTRY; ELECTROLYSIS; ENZYME STRUCTURE; HYDROXYLATION; MOSSBAUER SPECTROSCOPY; OXIDATION; OXIDATION REDUCTION REACTION; PRIORITY JOURNAL; RAMAN SPECTROMETRY; CHEMISTRY; CONFORMATION; ELECTROSPRAY MASS SPECTROMETRY; HYDROGEN BOND; METHODOLOGY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOCHEMISTRY; RADIATION SCATTERING; X RAY;

CARBON; ELECTROCHEMISTRY; HYDROGEN; HYDROGEN BONDING; IRON; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; OXYGEN; OXYGENASES; PHOTOCHEMISTRY; SCATTERING, RADIATION; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION; SPECTROSCOPY, MOSSBAUER; X-RAYS;

EID: 38049169173     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.0708516105     Document Type: Article

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