Dioxygen activation by a non-heme iron(II) complex: Formation of an iron(IV)-oxo complex via C-H activation by a putative iron(III)-superoxo species

Journal of the American Chemical Society

Volumn 132, Issue 31, 2010, Pages 10668-10670

  Lee, Yong Min ^a   Hong, Seungwoo ^b   Morimoto, Yuma ^c   Shin, Woonsup ^b   Fukuzumi, Shunichi ^a,c   Nam, Wonwoo ^a  

^a Ewha Womans University   (South Korea)

^b Sogang University   (South Korea)

^c OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

C-H ACTIVATION; C-H BOND; DIOXYGEN ACTIVATION; HEME IRON; HIGH-VALENT IRONS; NON-HEME IRON ENZYMES; OXO COMPLEXES;

ACTIVATION ANALYSIS; HEMOGLOBIN; OLEFINS; OXYGENATION; PORPHYRINS; REACTION INTERMEDIATES; SUBSTRATES;

IRON COMPOUNDS;

ALKENE; CARBON; HYDROGEN; NONHEME IRON PROTEIN; OXYGEN;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BOND; COMPLEX FORMATION; OXYGENATION;

FERROUS COMPOUNDS; MOLECULAR STRUCTURE; OXYGEN;

EID: 77955401788     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja103903c     Document Type: Article

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