Formation, structure, and EPR detection of a high spin FeIV-Oxo Species Derived from Either an FeIII-Oxo or FeIII-OH Complex

Journal of the American Chemical Society

Volumn 132, Issue 35, 2010, Pages 12188-12190

  Lacy, David C ^a   Gupta, Rupal ^b   Stone, Kari L ^a,c   Greaves, John ^a   Ziller, Joseph W ^a   Hendrich, Michael P ^b   Borovik, A S ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b CARNEGIE MELLON UNIVERSITY   (United States)

^c BENEDICTINE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COORDINATION GEOMETRY; ELECTRONIC PARAMETERS; EPR SPECTRA; EPR SPECTROSCOPY; FT-IR STUDY; G-VALUES; HIGH SPINS; HYDROGEN BONDINGS; LINE SHAPE; METALLOENZYMES; MOSSBAUER; NONHEME; OPTICAL SPECTRA; OXO SPECIES; OXOIRON; PROTON-COUPLED ELECTRON TRANSFER; SPECTROSCOPIC METHOD; SYNTHETIC CHEMISTRY; SYNTHETIC SYSTEMS; VISIBLE BAND; X-RAY DIFFRACTION METHOD;

BOND LENGTH; DYES; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRON TRANSPORT PROPERTIES; HYDROGEN BONDS; MOLYBDENUM COMPOUNDS; REACTION KINETICS; SIGNAL DETECTION; SPECTROSCOPIC ANALYSIS; X RAY DIFFRACTION;

COORDINATION REACTIONS;

ENZYME; HYDROGEN; IRON; IRON COMPLEX; LIGAND; MONOMER; NITROGEN; NONHEME IRON PROTEIN; OXYGEN;

ARTICLE; ATOM; CHEMICAL STRUCTURE; CRYSTALLIZATION; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; ELECTROSPRAY MASS SPECTROMETRY; GEOMETRY; HYDROGEN BOND; INFRARED SPECTROSCOPY; ISOTOPE LABELING; MOSSBAUER SPECTROSCOPY; PROTON TRANSPORT; ROOM TEMPERATURE; SPECTROSCOPY; STRUCTURE ANALYSIS; X RAY DIFFRACTION;

ELECTRON SPIN RESONANCE SPECTROSCOPY; FERRIC COMPOUNDS; IRON; MOLECULAR STRUCTURE; OXIDATION-REDUCTION;

EID: 77956249891     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1047818     Document Type: Article

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