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Volumn 44, Issue 19, 2005, Pages 2908-2912

The geometric and electronic structure of [(cyclam-acetato)Fe(N)] +: A genuine iron(v) species with a ground-state spin S = 1/2

Author keywords

Electronic structure; EXAFS spectroscopy; Iron; M ssbauer spectroscopy; Nitrido ligands

Indexed keywords

ELECTRONIC CONFIGURATION; GROUND STATE SPIN; IRON CENTERS; IRON-NITRIDO SPECIES;

EID: 18844417470     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200462368     Document Type: Article
Times cited : (124)

References (38)
  • 2
    • 0041305986 scopus 로고    scopus 로고
    • and references therein
    • Angew. Chem. Int. Ed. 2003, 42, 2942, and references therein.
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 2942
  • 30
    • 18844430797 scopus 로고    scopus 로고
    • note
    • It should be noted that EXAFS fits were also performed on the sample at an intermediate stage of illumination, shown in Figure 1. These data clearly required a short Fe-N distance (1.61 Å) in the fit (see Figure S4-S6 in the Supporting Information), supporting the fact that the change in electronic structure is coupled to the formation of a short Fe-N bond (1.6 Å).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.