Functional nanomaterials based on block copolymer self-assembly

Progress in Polymer Science (Oxford)

Volumn 35, Issue 11, 2010, Pages 1325-1349

  Kim, Jin Kon ^a   Yang, Seung Yun ^a   Lee, Youngmin ^a   Kim, Youngsuk ^a  

^a Pohang University of Science and Technology (POSTECH)   (South Korea)

Author keywords

Block copolymer; Nanomaterials; Nanostructures; Self assembly

Indexed keywords

NANOSTRUCTURED MATERIALS; NANOSTRUCTURES; SELF ASSEMBLY;

BLOCK COPOLYMER SELF-ASSEMBLY; FUNCTIONAL NANO MATERIALS; FUTURE PERSPECTIVES; NANO-METER SCALE; NANOSCALE MORPHOLOGY; ORDERED STRUCTURES; SELF-ASSEMBLING;

BLOCK COPOLYMERS;

EID: 78049295921     PISSN: 00796700     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.progpolymsci.2010.06.002     Document Type: Review

References (327)

1. M.S. Dresselhaus Physics and chemistry of nanometer-scale materials: symposium summary, looking outward and beyond Mater Sci Eng B 19 1993 192 197
2. J.R. Heath The chemistry of size and order on the nanometer scale Science 270 1995 1315 1316
3. R. Landauer Conductance determined by transmission: probes and quantised constriction resistance J Phys Condens Mat 1 1989 8099 8110
4. C.B. Murray, C.R. Kagan, and M.G. Bawendi Self-organization of CdSe nanocrystallites into three-dimensional quantum dot superlattices Science 270 1995 1335 1338
5. J.I. Pascual, J. Méndez, J. Gómez-Herrero, A.M. Baró, N. Garcia, U. Landman, W.D. Luedtke, E.N. Bogachek, and H.P. Cheng Properties of metallic nanowires: from conductance quantization to localization Science 267 1995 1793 1795
6. R.W. Siegel Nanophase materials assembled from atom clusters Mater Sci Eng B 19 1993 37 43
7. N. Vlachopoulos, P. Liska, J. Augustynski, and M. Grätzel Very efficient visible light energy harvesting and conversion by spectral sensitization of high surface area polycrystalline titanium dioxide films J Am Chem Soc 110 1988 1216 1220
8. G.E. Molau Colloidal and morphological behavior of block and graft copolymers 1970 Plenum Press New York
9. A. Noshay, and J.E. McGrath Block copolymers: overview and critical survey 1977 Academic Press New York
10. R.B. Gallot Preparation and study of block copolymers with ordered structures Adv Polym Sci 29 1978 85 156
11. G. Riess, G. Hurtrez, and P. Bohadur Block copolymers, encyclopedia of polymer science and engineering 1985 Wiley-Interscience New York
12. N.R. Legge, G. Holden, and H.E. Schroeder Thermoplastic elastomers 2nd ed. 1987 Hanser Munich
13. I.W. Hamley The physics of block copolymers 1998 Oxford University Press Oxford
14. I.W. Hamley, Developments in block copolymer science and technology 2004 John Wiley & Sons New York
15. N. Hadjichristidis, S. Pispas, and G. Floudas Block copolymers: synthetic strategies, physical properties, and applications 2003 Wiley-Interscience New Jersey
16. T.P. Lodge Block copolymers: past successes and future challenges Macromol Chem Phys 204 2003 265 273
17. C.D. Han Rheology and processing of polymeric materials: vol 1, polymer rheology 2007 Oxford University Press New York
18. T. Hashimoto Order-disorder transition in block copolymer N.R. Legge, G. Holden, H.E. Schroeder, Thermoplastic elastomers. A comprehensive review. 1987 Hanser Munich 349 383
19. E. Helfand, and Z.R. Wasserman Microdomain structure and the interface in block copolymers I. Goodman, Developments in block copolymers-1 1982 Applied Science New York 99 125
20. L. Leibler Theory of microphase separation in block copolymers Macromolecules 13 1980 1602 1617
21. L. Qi, H. Cölfen, and M. Antonietti Synthesis and characterization of CdS nanoparticles stabilized by double-hydrophilic block copolymers Nano Lett 1 2001 61 65
22. S. Förster, and M. Antonietti Amphiphilic block copolymers in structure-controlled nanomaterial hybrids Adv Mater 10 1998 195 217
23. S.I. Yoo, J.H. Kwon, and B.H. Sohn Single layers of diblock copolymer micelles for the fabrication of arrays of nanoparticles J Mater Chem 17 2007 2969 2975
24. R. Glass, M. Möller, and J.P. Spatz Block copolymer micelle nanolithography Nanotechnology 14 2003 1153 1160
25. J.K. Kim, J.I. Lee, and D.H. Lee Self-assembled block copolymers: Bulk to Thin Film Macromol Res 16 2008 267 292
26. S. Förster, and T. Plantenberg From self-organizing polymers to nanohybrid and biomaterials Angew Chem Int Ed 41 2002 688 714
27. R.A. Segalman Patterning with block copolymer thin films Mater Sci Eng R 48 2005 191 226
28. G.J.A.A. Soler-Illia, E.L. Crepaldi, D. Grosso, and C. Sanchez Block copolymer-templated mesoporous oxides Curr Opin Colloid Interface Sci 8 2003 109 126
29. J.S. Lee, A. Hirao, and S. Nakahama Polymerization of monomers containing functional silyl groups. 5. Synthesis of new porous membranes with functional groups Macromolecules 21 1988 274 276
30. N. Haberkorn, M.C. Lechmann, B.H. Sohn, K. Char, J.S. Gutmann, and P. Theato Templated organic and hybrid materials for optoelectronic applications Macromol Rapid Commun 30 2009 1146 1166
31. D.A. Olson, L. Chen, and M.A. Hillmyer Templating nanoporous polymers with ordered block copolymers Chem Mater 20 2008 869 890
32. C. Park, J. Yoon, and E.L. Thomas Enabling nanotechnology with self assembled block copolymer patterns Polymer 44 2003 6725 6760
33. I.W. Hamley Nanostructure fabrication using block copolymers Nanotechnology 14 2003 R39 R54
34. I.W. Hamley Nanotechnology with soft materials Angew Chem Int Ed 42 2003 1692 1712
35. M. Lazzari, and M.A. López-Quintela Block copolymers as a tool for nanomaterial fabrication Adv Mater 15 2003 1583 1594
36. C.J. Hawker, and T.P. Russell Block copolymer lithography: merging "bottom-up" with "top-down" processes MRS Bull 30 2005 952 966
37. S.B. Darling Directing the self-assembly of block copolymers Prog Polym Sci 32 2007 1152 1204
38. I.W. Hamley Ordering in thin films of block copolymers: fundamentals to potential applications Prog Polym Sci 34 2009 1161 1210
39. R.A. Segalman, B. McCulloch, S. Kirmayer, and J.J. Urban Block copolymers for organic optoelectronics Macromolecules 42 2009 9205 9216
40. J. Bang, U. Jeong, D.Y. Ryu, T.P. Russell, and C.J. Hawker Block copolymer nanolithography: translation of molecular level control to nanoscale patterns Adv Mater 21 2009 4769 4792
41. H.-C. Kim, S.-M. Park, and W.D. Hinsberg Block copolymer based nanostructures: materials, processes, and applications to electronics Chem Rev 110 2010 146 177
42. S.B. Darling Block copolymers for photovoltaics Energy Environ Sci 2 2009 1266 1273
43. F.S. Bates, and G.H. Fredrickson Block copolymer thermodynamics: theory and experiment Annu Rev Phys Chem 41 1990 525 557
44. F.S. Bates Polymer-polymer phase behavior Science 251 1991 898 905
45. G.H. Fredrickson, and F.S. Bates Dynamics of block copolymers: theory and experiment Annu Rev Mater Sci 26 2003 501 550
46. J.K. Kim, and C.D. Han Phase behavior and phase transition in AB- and ABA-type microphase-separated block copolymer Adv Polym Sci 231 2010 77 145
47. E. Helfand, and Z.R. Wasserman Block copolymer theory. 4. Narrow interphase approximation Macromolecules 9 1976 879 888
48. E. Helfand, and Z.R. Wasserman Block copolymer theory. 5. Spherical domains Macromolecules 11 1978 960 966
49. E. Helfand, and Z. Wasserman Block copolymer theory. 6. Cylindrical domains Macromolecules 13 1980 994 998
50. D.J. Meier Theoritical aspects of block copolymers N.R. Legge, G. Holden, H.E. Schroeder, Thermoplastic elastomers 1987 Hanser Munich 269 301
51. J.D. Vavasour, and M.D. Whitmore Self-consistent mean field theory of the microphases of diblock copolymers Macromolecules 25 1992 5477 5486
52. M.W. Matsen, and M. Schick Stable and unstable phases of a diblock copolymer melt Phys Rev Lett 72 1994 2660 2663
53. M.W. Matsen, and F.S. Bates Unifying weak- and strong-segregation block copolymer theories Macromolecules 29 1996 1091 1098
54. E.W. Cochran, C.J. Garcia-Cervera, and G.H. Fredrickson Stability of the gyroid phase in diblock copolymers at strong segregation Macromolecules 39 2006 2449 2451
55. F.S. Bates, and M.A. Hartney Block copolymers near the microphase separation transition. 3. Small-angle neutron scattering study of the homogeneous melt state Macromolecules 18 1985 2478 2486
56. M. Shibayama, T. Hashimoto, and H. Kawai Ordered structure in block polymer solutions. 1. Selective solvents Macromolecules 16 1983 16 28
57. T. Hashimoto, M. Shibayama, and H. Kawai Ordered structure in block polymer solutions. 4. Scaling rules on size of fluctuations with block molecular weight, concentration, and temperature in segregation and homogeneous regimes Macromolecules 16 1983 1093 1101
58. R.-J. Roe, M. Fishkis, and J.C. Chang Small-angle X-ray diffraction study of thermal transition in styrene-butadiene block copolymers Macromolecules 14 1981 1091 1103
59. C.D. Han, J. Kim, and J.K. Kim Determination of the order-disorder transition temperature of block copolymers Macromolecules 22 1989 383 394
60. C.D. Han, D.M. Baek, and J.K. Kim Effect of microdomain structure on the order-disorder transition temperature of polystyrene-block-polyisoprene-block- polystyrene copolymers Macromolecules 23 1990 561 570
61. C.D. Han, D.M. Baek, J.K. Kim, T. Ogawa, N. Sakamoto, and T. Hashimoto Effect of volume fraction on the order-disorder transition in low molecular weight polystyrene-block-polyisoprene copolymers. 1. Order-disorder transition temperature determined by rheological measurements Macromolecules 28 1995 5043 5062
62. N.P. Balsara, D. Perahia, C.R. Safinya, M. Tirrell, and T.P. Lodge Birefringence detection of the order-to-disorder transition in block copolymer liquids Macromolecules 25 1992 3896 3901
63. H. Kasten, and B. Stühn Density discontinuity at the microphase separation transition of a symmetric diblock copolymer Macromolecules 28 1995 4777 4778
64. B. Stühn, R. Mutter, and T. Albrecht Direct observation of structure formation at the temperature-driven order-to-disorder transition in diblock copolymers Europhys Lett 18 1992 427 432
65. V.P. Voronov, V.M. Buleiko, V.E. Podneks, I.W. Hamley, J.P.A. Fairclough, A.J. Ryan, S.M. Mai, B.X. Liao, and C. Booth A high-resolution calorimetry study of the order-disorder transition in a diblock copolymer melt Macromolecules 30 1997 6674 6676
66. H.J. Kim, S.B. Kim, J.K. Kim, Y.M. Jung, D.Y. Ryu, K.A. Lavery, and T.P. Russell Phase behavior of a weakly interacting block copolymer by temperature-dependent FTIR spectroscopy Macromolecules 39 2006 408 412
67. K. Almdal, K.A. Koppi, F.S. Bates, and K. Mortensen Multiple ordered phases in a block copolymer melt Macromolecules 25 1992 1743 1751
68. S. Sakurai, H. Kawada, T. Hashimoto, and L.J. Fetters Thermoreversible morphology transition between spherical and cylindrical microdomains of block copolymers Macromolecules 26 1993 5796 5802
69. K.A. Koppi, M. Tirrell, and F.S. Bates Shear-induced isotropic-to- lamellar transition Phys Rev Lett 70 1993 1449 1452
70. I.W. Hamley, K.A. Koppi, J.H. Rosedale, F.S. Bates, K. Almdal, and K. Mortensen Hexagonal mesophases between lamellae and cylinders in a diblock copolymer melt Macromolecules 26 1993 5959 5970
71. K. Almdal, K.A. Koppi, and F.S. Bates Dynamically sheared body-centered-cubic ordered diblock copolymer melt Macromolecules 26 1993 4058 4060
72. A.K. Khandpur, S. Foerster, F.S. Bates, I.W. Hamley, A.J. Ryan, W. Bras, K. Almdal, and K. Mortensen Polyisoprene-polystyrene diblock copolymer phase diagram near the order-disorder transition Macromolecules 28 1995 8796 8806
73. N. Sakamoto, T. Hashimoto, C.D. Han, D. Kim, and N.Y. Vaidya Order-order and order-disorder transitions in a polystyrene-block-polyisoprene-block- polystyrene copolymer Macromolecules 30 1997 1621 1632
74. C.Y. Ryu, M.E. Vigild, and T.P. Lodge Fluctuations with cubic symmetry in a hexagonal copolymer microstructure Phys Rev Lett 81 1998 5354 5357
75. C.Y. Ryu, and T.P. Lodge Thermodynamic stability and anisotropic fluctuations in the cylinder-to-sphere transition of a block copolymer Macromolecules 32 1999 7190 7201
76. K. Kimishima, T. Koga, and T. Hashimoto Order-order phase transition between spherical and cylindrical microdomain structures of block copolymer. I. Mechanism of the transition Macromolecules 33 2000 968 977
77. J.K. Kim, H.H. Lee, Q.-J. Gu, T. Chang, and Y.H. Jeong Determination of order-order and order-disorder transition temperatures of SIS block copolymers by differential scanning calorimetry and rheology Macromolecules 31 1998 4045 4048
78. J.H. Ahn, and W.C. Zin Effect of polyisoprene molecular weight on morphological transition in binary blends of styrene-isoprene diblock copolymer and polyisoprene Macromolecules 35 2002 10238 10240
79. Y.-L. Loo, R.A. Register, D.H. Adamson, and A.J. Ryan A highly regular hexagonally perforated lamellar structure in a quiescent diblock copolymer Macromolecules 38 2005 4947 4949
80. T.P. Lodge, B. Pudil, and K.J. Hanley The full phase behavior for block copolymers in solvents of varying selectivity Macromolecules 35 2002 4707 4717
81. J. Bang, T.P. Lodge, X. Wang, K.L. Brinker, and W.R. Burghardt Thermoreversible, epitaxial fcc ↔ bcc transitions in block copolymer solutions Phys Rev Lett 89 2002 pp. 215505/1-4
82. T.P. Lodge, J. Bang, M.J. Park, and K. Char Origin of the thermoreversible fcc-bcc transition in block copolymer solutions Phys Rev Lett 92 2004 pp. 145501/1-4
83. M.J. Park, J. Bang, T. Harada, K. Char, and T.P. Lodge Epitaxial transitions among FCC, HCP, BCC, and cylinder phases in a block copolymer solution Macromolecules 37 2004 9064 9075
84. Y.-Y. Huang, H.-L. Chen, and T. Hashimoto Face-centered cubic lattice of spherical micelles in block copolymer/homopolymer blends Macromolecules 36 2003 764 770
85. Y.-Y. Huang, J.-Y. Hsu, H.-L. Chen, and T. Hashimoto Precursor-driven bcc-fcc order-order transition of sphere-forming block copolymer/homopolymer blend Macromolecules 40 2007 3700 3707
86. T.S. Bailey, C.M. Hardy, T.H. Epps, and F.S. Bates A noncubic triply periodic network morphology in poly(isoprene-b-styrene-b-ethylene oxide) triblock copolymers Macromolecules 35 2002 7007 7017
87. M. Takenaka, T. Wakada, S. Akasaka, S. Nishitsuji, K. Saijo, H. Shimizu, M.I. Kim, and H. Hasegawa Orthorhombic Fddd network in diblock copolymer melts Macromolecules 40 2007 4399 4402
88. T.P. Russell, T.E. Karis, Y. Gallot, and A.M. Mayes A lower critical ordering transition in a diblock copolymer melt Nature 368 1994 729 731
89. T. Hashimoto, H. Hasegawa, T. Hashimoto, H. Katayama, M. Kamigaito, M. Sawamoto, and M. Imai Synthesis and SANS characterization of poly(vinyl methyl ether)-block-polystyrene Macromolecules 30 1997 6819 6825
90. M. Pollard, T.P. Russell, A.V. Ruzette, A.M. Mayes, and Y. Gallot The effect of hydrostatic pressure on the lower critical ordering transition in diblock copolymers Macromolecules 31 1998 6493 6498
91. A.V.G. Ruzette, P. Banerjee, A.M. Mayes, M. Pollard, T.P. Russell, R. Jerome, T. Slawecki, R. Hjelm, and P. Thiyagarajan Phase behavior of diblock copolymers between styrene and n-alkyl methacrylates Macromolecules 31 1998 8509 8516
92. R. Weidisch, M. Stamm, D.W. Schubert, M. Arnold, H. Budde, and S. Horing Correlation between phase behavior and tensile properties of diblock copolymers Macromolecules 32 1999 3405 3411
93. H. Hasegawa, N. Sakamoto, H. Takeno, H. Jinnai, T. Hashimoto, D. Schwahn, H. Frielinghaus, S. Janen, M. Imai, and K. Mortensen Small-angle neutron scattering studies on phase behavior of block copolymers J Phys Chem Solids 60 1999 1307 1312
94. D. Patterson, and A. Robard Thermodynamics of polymer compatibility Macromolecules 11 1978 690 695
95. D.Y. Ryu, U. Jeong, J.K. Kim, and T.P. Russell Closed-loop phase behaviour in block copolymers Nat Mater 1 2002 114 117
96. D.Y. Ryu, D.J. Lee, J.K. Kim, K.A. Lavery, T.P. Russell, Y.S. Han, B.S. Seong, C.H. Lee, and P. Thiyagarajan Effect of hydrostatic pressure on closed-loop phase behavior of block copolymers Phys Rev Lett 90 2003 235501/1-4
97. D.Y. Ryu, U. Jeong, D.H. Lee, J. Kim, H.S. Youn, and J.K. Kim Phase behavior of deuterated polystyrene-block-poly(n-pentyl methacrylate) copolymers Macromolecules 36 2003 2894 2902
98. H.J. Kim, S.B. Kim, J.K. Kim, and Y.M. Jung Hydrostatic pressure effect on the phase transitions of a closed-loop type block copolymer by using 2D FTIR correlation spectroscopy J Phys Chem B 112 2008 15295 15300
99. Y. Matsushita, H. Choshi, T. Fujimoto, and M. Nagasawa Preparation and morphological properties of a triblock copolymer of the ABC type Macromolecules 13 1980 1053 1058
100. Y. Mogi, H. Kotsuji, Y. Kaneko, K. Mori, Y. Matsushita, and I. Noda Preparation and morphology of triblock copolymers of the ABC type Macromolecules 25 1992 5408 5411 (Pubitemid 23572201)
101. T.S. Bailey, H.D. Pham, and F.S. Bates Morphological behavior bridging the symmetric AB and ABC states in the poly(styrene-b-isoprene-b-ethylene oxide) triblock copolymer system Macromolecules 34 2001 6994 7008
102. F.S. Bates Network phases in block copolymer melts Mater Res Bull 30 2005 525 532
103. T.H. Epps, E.W. Cochran, T.S. Bailey, R.S. Waletzko, C.M. Hardy, and F.S. Bates Ordered network phases in linear poly(isoprene-b-styrene-b-ethylene oxide) triblock copolymers Macromolecules 37 2004 8325 8341
104. T.H. Epps, J. Chatterjee, and F.S. Bates Phase transformations involving network phases in ISO triblock copolymer-homopolymer blends Macromolecules 38 2005 8775 8784
105. R. Stadler, C. Auschra, J. Beckmann, U. Krappe, I. Voight-Martin, and L. Leibler Morphology and thermodynamics of symmetric poly(A-block-B-block-C) triblock copolymers Macromolecules 28 1995 3080 3097
106. U. Breiner, U. Krappe, E.L. Thomas, and R. Stadler Structural characterization of the "Knitting Pattern" in polystyrene-block- poly(ethylene-co-butylene)-block-poly(methyl methacrylate) triblock copolymers Macromolecules 31 1998 135 141
107. W. Zheng, and Z.-G. Wang Morphology of ABC triblock copolymers Macromolecules 28 1995 7215 7223
108. F.S. Bates, and G.H. Fredrickson Block copolymers-designer soft materials Phys Today 52 1999 32 38
109. F.S. Bates, G.H. Fredrickson, D. Hucul, and S.F. Hahn PCHE-based pentablock copolymers: evolution of a new plastic AIChE J 47 2001 762 765
110. C.Y. Ryu, J. Ruokolainen, G.H. Fredrickson, E.J. Kramer, and S.F. Hahn Chain architecture effects on deformation and fracture of block copolymers with unentangled matrices Macromolecules 35 2002 2157 2166
111. T.J. Hermel, S.F. Hahn, K.A. Chaffin, W.W. Gerberich, and F.S. Bates Role of molecular architecture in mechanical failure of glassy/semicrystalline block copolymers: CEC vs CECEC lamellae Macromolecules 36 2003 2190 2193
112. R. Yin, and T.E. Hogen-Esch Synthesis and characterization of narrow-molecular-weight-distribution polystyrene-poly(dimethylsiloxane) macrocyclic block copolymers and their isobaric precursors Macromolecules 26 1993 6952 6957
113. R.L. Lescanec, D.A. Hajduk, G.Y. Kim, Y. Gan, R. Yin, S.M. Gruner, T.E. Hogen-Esch, and E.L. Thomas Comparison of the lamellar morphology of microphase-separated cyclic block copolymers and their linear precursors Macromolecules 28 1995 3485 3489
114. J.F. Marko Microphase separation of block copolymer rings Macromolecules 26 1993 1442 1444
115. A.N. Morozov, and J.G.E.M. Fraaije Phase behavior of ring diblock copolymer melt in equilibrium and under shear Macromolecules 34 2001 1526 1528
116. W.H. Jo, and S.S. Jang Monte Carlo simulation of the order-disorder transition of a symmetric cyclic diblock copolymer system J Chem Phys 111 1999 1712 1720
117. A.M. Mayes, and M.O. de la Cruz Microphase separation in multiblock copolymer melts J Chem Phys 91 1989 7228 7235
118. P. Rangarajan, R.A. Register, L.J. Fetters, W. Bras, S. Naylor, and A.J. Ryan Crystallization of a weakly segregated polyolefin diblock copolymer Macromolecules 28 1995 4932 4938
119. P. Rangarajan, R.A. Register, D.H. Adamson, L.J. Fetters, W. Bras, S. Naylor, and A.J. Ryan Dynamics of structure formation in crystallizable block copolymers Macromolecules 28 1995 1422 1428
120. A.J. Ryan, I.W. Hamley, W. Bras, and F.S. Bates Structure development in semicrystalline diblock copolymers crystallizing from the ordered melt Macromolecules 28 1995 3860 3868
121. I.W. Hamley, J.P.A. Fairclough, F.S. Bates, and A.J. Ryan Crystallization thermodynamics and kinetics in semicrystalline diblock copolymers Polymer 39 1998 1429 1437
122. D.J. Quiram, R.A. Register, and G.R. Marchand Crystallization of asymmetric diblock copolymers from microphase-separated melts Macromolecules 30 1997 4551 4558
123. I.W. Hamley, J.P.A. Fairclough, N.J. Terrill, A.J. Ryan, P.M. Lipic, F.S. Bates, and E. Towns-Andrews Crystallization in oriented semicrystalline diblock copolymers Macromolecules 29 1996 8835 8843
124. I.W. Hamley, J.P.A. Fairclough, A.J. Ryan, F.S. Bates, and E. Towns-Andrews Crystallization of nanoscale-confined diblock copolymer chains Polymer 37 1996 4425 4429
125. Y. Mohajer, I.C. Wang, G.L. Wilkes, and J.E. McGrath Hydrogenated linear block copolymers of butadiene and isoprene: effects of variation of composition and sequence architecture on properties Polymer 23 1982 1523 1535
126. K.C. Douzinas, and R.E. Cohen Chain folding in ethylene-butylene- ethylethylene semicrystalline diblock copolymers Macromolecules 25 1992 5030 5035
127. R.E. Cohen, A. Bellare, and M.A. Drzewinski Spatial organization of polymer chains in a crystallizable diblock copolymer of polyethylene and polystyrene Macromolecules 27 1994 2321 2323
128. P. Rangarajan, R.A. Register, and L.J. Fetters Morphology of semicrystalline block copolymers of ethylene-(ethylene-alt-propylene) Macromolecules 26 1993 4640 4645
129. S.-M. Mai, J.P.A. Fairclough, K. Viras, P.A. Gorry, I.W. Hamley, A.J. Ryan, and C. Booth Chain folding in semicrystalline oxyethylene/oxybutylene diblock copolymers Macromolecules 30 1997 8392 8400
130. A.J. Ryan, J.P.A. Fairclough, I.W. Hamley, S.-M. Mai, and C. Booth Chain folding in crystallizable block copolymers Macromolecules 30 1997 1723 1727
131. P.C. Ashman, and C. Booth Crystallinity and fusion of ethylene oxide/propylene oxide block copolymers: 1. Type PE copolymers Polymer 16 1975 889 896
132. C. Booth, and D.V. Dodgson Melting behavior of ethylene oxide-propylene oxide (sym-EPE) block copolymers J Polym Sci Polym Phys Ed 11 1973 265 268
133. S. Nojima, K. Kato, S. Yamamoto, and T. Ashida Crystallization of block copolymers. 1. Small-angle X-ray scattering study of a ε-caprolactone- butadiene diblock copolymer Macromolecules 25 1992 2237 2242
134. S. Nojima, M. Ono, and T. Ashida Crystallization of block copolymers II. Morphological study of poly (ethylene glycol)-poly (ε-caprolactone) block copolymers Polym J 24 1992 1271 1280
135. S. Nojima, S. Yamamoto, and T. Ashida Crystallization of block copolymers IV. Molecular weight dependence of the morphology formed in ε-caprolactone-butadiene diblock copolymers Polym J 27 1995 673 682
136. J.K. Kim, D.-J. Park, M.-S. Lee, and K.J. Ihn Synthesis and crystallization behavior of poly(-lactide)-block-poly(ε-caprolactone) copolymer Polymer 42 2001 7429 7441
137. I.W. Hamley, V. Castelletto, P. Parras, Z.B. Lu, C.T. Imrie, and T. Itoh Ordering on multiple lengthscales in a series of side group liquid crystal block copolymers containing a cholesteryl-based mesogen Soft Matter 1 2005 355 363
138. G. Mao, J. Wang, S.R. Clingman, C.K. Ober, J.T. Chen, and E.L. Thomas Molecular design, synthesis, and characterization of liquid crystal-coil diblock copolymers with azobenzene side groups Macromolecules 30 1997 2556 2567
139. W.-Y. Zheng, R.J. Albalak, and P.T. Hammond Mesogen orientation within Smectic C* side chain liquid crystalline diblock copolymers Macromolecules 31 1998 2686 2689
140. K.M. Lee, and C.D. Han Microphase separation transition and rheology of side-chain liquid-crystalline block copolymers Macromolecules 35 2002 3145 3156
141. B. de Boer, U. Stalmach, P.F. van Hutten, C. Melzer, V.V. Krasnikov, and G. Hadziioannou Supramolecular self-assembly and opto-electronic properties of semiconducting block copolymers Polymer 42 2001 9097 9109
142. J. Liu, E. Sheina, T. Kowalewski, and R.D. McCullough Tuning the electrical conductivity and self-assembly of regioregular polythiophene by block copolymerization: nanowire morphologies in new di- and triblock copolymers Angew Chem Int Ed 41 2002 329 332
143. B.D. Olsen, and R.A. Segalman Structure and thermodynamics of weakly segregated rod-coil block copolymers Macromolecules 38 2005 10127 10137
144. B.D. Olsen, and R.A. Segalman Nonlamellar phases in asymmetric rod-coil block copolymers at increased segregation strengths Macromolecules 40 2007 6922 6929
145. Y. Tao, B.D. Olsen, V. Ganesan, and R.A. Segalman Domain size control in self-assembling rod-coil block copolymer and homopolymer blends Macromolecules 40 2007 3320 3327
146. J.H. Kim, M.S. Rahman, J.S. Lee, and J.W. Park Liquid crystalline ordering in the self-assembled monolayers of tethered rodlike polymers J Am Chem Soc 129 2007 7756 7757
147. M.S. Rahman, M. Changez, S. Samal, and J.S. Lee Solvent-induced transition of hollow sphere to giant-tube from amphiphilic rod-coil-rod triblock copolymers of 2-vinylpyridine and n-hexyl isocyanate J Nanosci Nanotechnol 7 2007 3892 3895
148. M.S. Rahman, S. Samal, and J.-S. Lee Synthesis and self-assembly studies of amphiphilic poly(n-hexyl isocyanate)-block-poly(2-vinylpyridine)-block- poly(n-hexyl isocyanate) rod-coil-rod triblock copolymer Macromolecules 39 2006 5009 5014
149. R.S. Loewe, S.M. Khersonsky, and R.D. McCullough A simple method to prepare head-to-tail coupled, regioregular poly(3-alkylthiophenes) using Grignard metathesis Adv Mater 11 1999 250 253
150. M. Jeffries-El, G. Sauvé, and R.D. McCullough Facile synthesis of end-functionalized regioregular poly(3-alkylthiophene)s via modified Grignard metathesis reaction Macromolecules 38 2005 10346 10352
151. M.C. Iovu, M. Jeffries-El, E.E. Sheina, J.R. Cooper, and R.D. McCullough Regioregular poly(3-alkylthiophene) conducting block copolymers Polymer 46 2005 8582 8586
152. M.C. Iovu, C. Rockford Craley, M. Jeffries-El, A.B. Krankowski, R. Zhang, T. Kowalewski, and R.D. McCullough Conducting regioregular polythiophene block copolymer nanofibrils synthesized by reversible addition fragmentation chain transfer polymerization (RAFT) and nitroxide mediated polymerization (NMP) Macromolecules 40 2007 4733 4735
153. Y. Lee, K.I. Fukukawa, J. Bang, C.J. Hawker, and J.K. Kim A high purity approach to poly (3-hexylthiophene) diblock copolymers J Polym Sci Part A Polym Chem 46 2008 8200 8205
154. C.-A. Dai, W.-C. Yen, Y.-H. Lee, C.-C. Ho, and W.-F. Su Facile synthesis of well-defined block copolymers containing regioregular poly(3-hexyl thiophene) via anionic macroinitiation method and their self-assembly behavior J Am Chem Soc 129 2007 11036 11038
155. T. Higashihara, K. Ohshimizu, A. Hirao, and M. Ueda Facile synthesis of ABA triblock copolymer containing regioregular poly (3-hexylthiophene) and polystyrene segments via linking reaction of poly (styryl) lithium Macromolecules 41 2008 9505 9507
156. H.C. Moon, A. Anthonysamy, Y. Lee, and J.K. Kim Facile synthesis of well-defined coil-rod-coil block copolymer composed of regioregular poly(3-hexyl thiophene) via anionic coupling reaction Macromolecules 43 2010 1747 1752
157. B.W. Boudouris, C.D. Frisbie, and M.A. Hillmyer Nanoporous poly(3-alkylthiophene) thin films generated from block copolymer templates Macromolecules 41 2008 67 75
158. C.C. Ho, Y.H. Lee, C.A. Dai, R.A. Segalman, and W.F. Su Synthesis and self-assembly of poly (diethylhexyloxy-p-phenylenevinylene)-b-poly(methyl methacrylate) rod-coil block copolymers Macromolecules 42 2009 4208 4219
159. G. Sauvé, and R.D. McCullough High field-effect mobilities for diblock copolymers of poly(3-hexylthiophene) and poly(methyl acrylate) Adv Mater 19 2007 1822 1825
160. I. Botiz, and S.B. Darling Self-assembly of poly(3-hexylthiophene)-block- polylactide block copolymer and subsequent incorporation of electron acceptor material Macromolecules 42 2009 8211 8217
161. C.L. Chochos, J.K. Kallitsis, and V.G. Gregoriou Rod-coil block copolymers incorporating terfluorene segments for stable blue light emission J Phys Chem B 109 2005 8755 8760
162. S. Becker, C. Ego, A.C. Grimsdale, E.J.W. List, D. Marsitzky, A. Pogantsch, S. Setayesh, G. Leising, and K. Müllen Optimisation of polyfluorenes for light emitting applications Synth Met 125 2002 73 80
163. N.P. Tzanetos, and J.K. Kallitsis Synthesis and optical properties of copolymers containing side chain oxadiazole blocks and a rigid central moiety Chem Mater 16 2004 2648 2655
164. S.S. Sun Design of a block copolymer solar cell Sol Energy Mater Sol Cells 79 2003 257 264
165. F.S. Kim, X. Guo, M.D. Watson, and S.A. Jenekhe Organic electronics: high-mobility Ambipolar transistors and high-gain inverters from a donor-acceptor copolymer semiconductor Adv Mater 22 2010 478 482
166. U. Stalmach, B. De Boer, C. Videlot, P.F. Van Hutten, and G. Hadziioannou Semiconducting diblock copolymers synthesized by means of controlled radical polymerization techniques J Am Chem Soc 122 2000 5464 5472
167. M.H. van der Veen, B. De Boer, U. Stalmach, K.I. van de Wetering, and G. Hadziioannou Donor-acceptor diblock copolymers based on PPV and C60: synthesis, thermal properties, and morphology Macromolecules 37 2004 3673 3684
168. K. van de Wetering, C. Brochon, C. Ngov, and G. Hadziioannou Design and synthesis of a low band gap conjugated macroinitiator: toward rod-coil donor-acceptor block copolymers Macromolecules 39 2006 4289 4297
169. K. Sivula, Z.T. Ball, N. Watanabe, and J.M.J. Fréchet Amphiphilic diblock copolymer compatibilizers and their effect on the morphology and performance of polythiophene: fullerene solar cells Adv Mater 18 2006 206 210
170. C. Yang, J.K. Lee, A.J. Heeger, and F. Wudl Well-defined donor-acceptor rod-coil diblock copolymers based on P3HT containing C 60: the morphology and role as a surfactant in bulk-heterojunction solar cells J Mater Chem 19 2009 5416 5423
171. M. Sommer, S.M. Lindner, and M. Thelakkat Microphase-separated donor-acceptor diblock copolymers: influence of HOMO energy levels and morphology on polymer solar cells Adv Funct Mater 17 2007 1493 1500
172. M. Sommer, A.S. Lang, and M. Thelakkat Crystalline-crystalline donor-acceptor block copolymers Angew Chem Int Ed 47 2008 7901 7904
173. Q. Zhang, A. Cirpan, T.P. Russell, and T. Emrick Donor-acceptor poly(thiophene-block-perylene diimide) copolymers: synthesis and solar cell fabrication Macromolecules 42 2009 1079 1082
174. G. Riess Micellization of block copolymers Prog Polym Sci 28 2003 1107 1170
175. J.-F. Gohy Block copolymer micelles Adv Polym Sci 190 2005 65 136
176. T. Smart, H. Lomas, M. Massignani, M.V. Flores-Merino, L.R. Perez, and G. Battaglia Block copolymer nanostructures Nano Today 3 2008 38 46
177. P. Bhargava, Y. Tu, J.X. Zheng, H. Xiong, R.P. Quirk, and S.Z.D. Cheng Temperature-induced reversible morphological changes of polystyrene-block- poly(ethylene oxide) micelles in solution J Am Chem Soc 129 2007 1113 1121
178. D.J. Pochan, Z. Chen, H. Cui, K. Hales, K. Qi, and K.L. Wooley Toroidal triblock copolymer assemblies Science 306 2004 94 97
179. B.-K. Cho, A. Jain, S.M. Gruner, and U. Wiesner Mesophase structure-mechanical and ionic transport correlations in extended amphiphilic dendrons Science 305 2004 1598 1601
180. D. Yan, Y. Zhou, and J. Hou Supramolecular self-assembly of macroscopic tubes Science 303 2004 65 67
181. Z. Li, E. Kesselman, Y. Talmon, M.A. Hillmyer, and T.P. Lodge Multicompartment micelles from ABC Miktoarm stars in water Science 306 2004 98 101
182. H. Cui, Z. Chen, S. Zhong, K.L. Wooley, and D.J. Pochan Block copolymer assembly via kinetic control Science 317 2007 647 650
183. K. Kataoka, G.S. Kwon, M. Yokoyama, T. Okano, and Y. Sakurai Block copolymer micelles as vehicles for drug delivery J Controlled Release 24 1993 119 132
184. K. Kataoka, A. Harada, and Y. Nagasaki Block copolymer micelles for drug delivery: design, characterization and biological significance Adv Drug Delivery Rev 47 2001 113 131
185. Y. Bae, and K. Kataoka Intelligent polymeric micelles from functional poly(ethylene glycol)-poly(amino acid) block copolymers Adv Drug Deliv Rev 61 2009 768 784
186. C. Giacomelli, L.L. Men, R. Borsali, J. Lai-Kee-Him, A. Brisson, S.P. Armes, and A.L. Lewis Phosphorylcholine-based pH-responsive diblock copolymer micelles as drug delivery vehicles: light scattering, electron microscopy and fluorescence experiments Biomacromolecules 7 2006 817 828
187. U. Borchert, U. Lipprandt, M. Bilang, A. Kimpfler, A. Rank, R. Peschka-Süss, R. Schubert, P. Lindner, and S. Förster pH-induced release from P2VP-PEO block copolymer vesicles Langmuir 22 2006 5843 5847
188. M.D.C. Topp, P.J. Dijkstra, H. Talsma, and J. Feijen Thermosensitive micelle-forming block copolymers of poly(ethylene glycol) and poly(N-isopropylacrylamide) Macromolecules 30 1997 8518 8520
189. S. Qin, Y. Geng, D.E. Discher, and S. Yang Temperature-controlled assembly and release from polymer vesicles of poly(ethylene oxide)-block-poly(N- isopropylacrylamide) Adv Mater 18 2006 2905 2909
190. H. Ai, C. Flask, B. Weinberg, X. Shuai, M.D. Pagel, D. Farrell, J. Duerk, and J. Gao Magnetic-loaded polymeric micelles as ultrasensitive magnetic-resonance probes Adv Mater 17 2005 1949 1952
191. B. Dubertret, P. Skourides, D.J. Norris, V. Noireaux, A.H. Brivanlou, and A. Libchaber In vivo imaging of quantum dots encapsulated in phospholipid micelles Science 298 2002 1759 1762
192. Y. Matsumura, and H. Maeda A new concept for macromolecular therapeutics in cancer chemotherapy: mechanism of tumoritropic accumulation of proteins and the antitumor agent smancs Cancer Res 46 1986 6387 6392
193. S.P. Anthony, and J.K. Kim Two-dimensional arrays of luminescent metal-selenide nanoparticles Chem Commun 10 2008 1193 1195
194. Y. Kim, H. Han, Y. Kim, W. Lee, M. Alexe, S. Baik, and J.K. Kim Ultrahigh density array of epitaxial ferroelectric nanoislands on conducting substrates Nano Lett 10 2010 2141 2146
195. T. Lohmueller, E. Bock, and J.P. Spatz Synthesis of quasi-hexagonal ordered arrays of metallic nanoparticles with tuneable particle size Adv Mater 20 2008 2297 2302
196. S.-H. Yun, S.I. Yoo, J.C. Jung, W.-C. Zin, and B.-H. Sohn Highly ordered arrays of nanoparticles in large areas from diblock copolymer micelles in hexagonal self-assembly Chem Mater 18 2006 5646 5648
197. S.J. Lee, J.T. Hupp, and S.T. Nguyen Growth of narrowly dispersed porphyrin nanowires and their hierarchical assembly into macroscopic columns J Am Chem Soc 130 2008 9632 9633
198. X. Wang, K. Liu, A.C. Arsenault, D.A. Rider, G.A. Ozin, M.A. Winnik, and I. Manners Shell-cross-linked cylindrical polyisoprene-b-polyferrocenylsilane (PI-b-PFS) block copolymer micelles: one-dimensional (1D) organometallic nanocylinders J Am Chem Soc 129 2007 5630 5639
199. J.A. Massey, M.A. Winnik, and I. Manners Fabrication of oriented nanoscopic ceramic lines from cylindrical micelles of an organometallic polyferrocene block copolymer J Am Chem Soc 123 2001 3147 3148
200. P. Mansky, Y. Liu, E. Huang, T.P. Russell, and C.J. Hawker Controlling polymer-surface interactions with random copolymer brushes Science 275 1997 1458 1460
201. D.Y. Ryu, K. Shin, E. Drockenmuller, C.J. Hawker, and T.P. Russell A generalized approach to the modification of solid surfaces Science 308 2005 236 239
202. J. Bang, J. Bae, P. Löwenhielm, C. Spiessberger, S.A. Given-Beck, T.P. Russell, and C.J. Hawker Facile routes to patterned surface neutralization layers for block copolymer lithography Adv Mater 19 2007 4552 4557
203. G. Kim, and M. Libera Morphological development in solvent-cast polystyrene-polybutadiene-polystyrene (SBS) triblock copolymer thin films Macromolecules 31 1998 2569 2577
204. G. Kim, and M. Libera Kinetic constraints on the development of surface microstructure in SBS thin films Macromolecules 31 1998 2670 2672
205. S.H. Kim, M.J. Misner, and T.P. Russell Solvent-induced ordering in thin film diblock copolymer/homopolymer mixtures Adv Mater 16 2004 2119 2123
206. S.H. Kim, M.J. Misner, T. Xu, M. Kimura, and T.P. Russell Highly oriented and ordered arrays from block copolymers via solvent evaporation Adv Mater 16 2004 226 231
207. Z.Q. Lin, D.H. Kim, X.D. Wu, L. Boosahda, D. Stone, L. LaRose, and T.P. Russell A rapid route to arrays of nanostructures in thin films Adv Mater 14 2002 1373 1376
208. S.H. Kim, M.J. Misner, L. Yang, O. Gang, B.M. Ocko, and T.P. Russell Salt complexation in block copolymer thin films Macromolecules 39 2006 8473 8479
209. J. Ruokolainen, G.H. Fredrickson, E.J. Kramer, C.Y. Ryu, S.F. Hahn, and S.N. Magonov Effect of thermal history and microdomain orientation on deformation and fracture properties of poly(cyclohexylethylene)-polyethylene triblock copolymers containing cylindrical PE domains Macromolecules 35 2002 9391 9402
210. V. Khanna, E.W. Cochran, A. Hexemer, G.E. Stein, G.H. Fredrickson, E.J. Kramer, X. Li, J. Wang, and S.F. Hahn Effect of chain architecture and surface energies on the ordering behavior of lamellar and cylinder forming block copolymers Macromolecules 39 2006 9346 9356
211. A. Knoll, A. Horvat, K.S. Lyakhova, G. Krausch, G.J.A. Sevink, A.V. Zvelindovsky, and R. Magerle Phase behavior in thin films of cylinder-forming block copolymers Phys Rev Lett 89 2002 035501 35504
212. M. Ramanathan, E. Nettleton, and S.B. Darling Simple orientational control over cylindrical organic-inorganic block copolymer domains for etch mask applications Thin Solid Films 517 2009 4474 4478
213. T. Xu, A.V. Zvelindovsky, G.J.A. Sevink, K.S. Lyakhova, H. Jinnai, and T.P. Russell Electric field alignment of asymmetric diblock copolymer thin films Macromolecules 38 2005 10788 10798
214. Q. Wang, P.F. Nealey, and J.J. Pablo Monte Carlo simulations of asymmetric diblock copolymer thin films confined between two homogeneous surfaces Macromolecules 34 2001 3458 3470
215. Q. Wang, Q. Yan, P.F. Nealey, and J.J. Pablo Monte Carlo simulations of diblock copolymer thin films confined between two homogeneous surfaces J Chem Phys 112 2000 450 464
216. Q. Wang, P.F. Nealey, and J.J. Pablo Simulations of the morphology of cylinder-forming asymmetric diblock copolymer thin films on nanopatterned substrates Macromolecules 36 2003 1731 1740
217. U. Jeong, D.Y. Ryu, D.H. Kho, J.K. Kim, J.T. Goldbach, D.H. Kim, and T.P. Russell Enhancement in the orientation of the microdomain in block copolymer thin films upon the addition of homopolymer Adv Mater 16 2004 533 536
218. R.J. Albalak, and E.L. Thomas Microphase separation of block copolymer solutions in a flow field J Polym Sci Part B Polym Phys 31 1993 37 46
219. R.J. Albalak, and E.L. Thomas Roll-casting of block copolymers and of block copolymer-homopolymer blends J Polym Sci Part B Polym Phys 32 1994 341 350
220. Z.-R. Chen, and J.A. Kornfield Flow-induced alignment of lamellar block copolymer melts Polymer 39 1998 4679 4699
221. V.K. Gupta, R. Krishnamoorti, J.A. Kornfield, and S.D. Smith Evolution of microstructure during shear alignment in a polystyrene-polyisoprene lamellar diblock copolymer Macromolecules 28 1995 4464 4474
222. K.A. Koppi, M. Tirrell, F.S. Bates, K. Almdal, and R.H. Colby Lamellae orientation in dynamically sheared diblock copolymer melts J Phys II France 2 1992 1941 1959
223. S. Sakurai Progress in control of microdomain orientation in block copolymers-efficiencies of various external fields Polymer 49 2008 2781 2796
224. D.E. Angelescu, J.H. Waller, D.H. Adamson, P. Deshpande, S.Y. Chou, R.A. Register, and P.M. Chaikin Macroscopic orientation of block copolymer cylinders in single-layer films by shearing Adv Mater 16 2004 1736 1740
225. D.E. Angelescu, J.H. Waller, R.A. Register, and P.M. Chaikin Shear-induced alignment in thin films of spherical nanodomains Adv Mater 17 2005 1878 1881
226. Y. Morikawa, S. Nagano, K. Watanabe, K. Kamata, T. Iyoda, and T. Seki Optical alignment and patterning of nanoscale microdomains in a block copolymer thin film Adv Mater 18 2006 883 886
227. H. Yu, T. Iyoda, and T. Ikeda Photoinduced alignment of nanocylinders by supramolecular cooperative motions J Am Chem Soc 128 2006 11010 11011
228. P. Mansky, J. DeRouchey, T.P. Russell, J. Mays, M. Pitsikalis, T. Morkved, and H. Jaeger Large-area domain alignment in block copolymer thin films using electric fields Macromolecules 31 1998 4399 4401
229. J. Bodycomb, Y. Funaki, K. Kimishima, and T. Hashimoto Single-grain lamellar microdomain from a diblock copolymer Macromolecules 32 1999 2075 2077
230. T. Hashimoto, J. Bodycomb, Y. Funaki, and K. Kimishima The effect of temperature gradient on the microdomain orientation of diblock copolymers undergoing an order-disorder transition Macromolecules 32 1999 952 954
231. K. Mita, H. Tanaka, K. Saijo, M. Takenaka, and T. Hashimoto Cylindrical domains of block copolymers developed via ordering under moving temperature gradient Macromolecules 40 2007 5923 5933
232. C. Park, C. Rosa, L.J. Fetters, B. Lotz, and E.L. Thomas Alteration of classical microdomain patterns of block copolymers by degenerate epitaxy Adv Mater 13 2001 724 728
233. C. Park, C. Rosa, and E.L. Thomas Large area orientation of block copolymer microdomains in thin films via directional crystallization of a solvent Macromolecules 34 2001 2602 2606
234. C. Rosa, C. Park, B. Lotz, J.-C. Wittmann, L.J. Fetters, and E.L. Thomas Control of molecular and microdomain orientation in a semicrystalline block copolymer thin film by epitaxy Macromolecules 33 2000 4871 4876
235. C. Rosa, C. Park, E.L. Thomas, and B. Lotz Microdomain patterns from directional eutectic solidification and epitaxy Nature 405 2000 433 437
236. R.A. Segalman, A. Hexemer, R.C. Hayward, and E.J. Kramer Ordering and melting of block copolymer spherical domains in 2 and 3 dimensions Macromolecules 36 2003 3272 3288
237. R.A. Segalman, K.E. Schaefer, G.H. Fredrickson, E.J. Kramer, and S. Magonov Topographic templating of islands and holes in highly asymmetric block copolymer films Macromolecules 36 2003 4498 4506
238. M.R. Hammond, E. Cochran, G.H. Fredrickson, and E.J. Kramer Temperature dependence of order, disorder, and defects in laterally confined diblock copolymer cylinder monolayers Macromolecules 38 2005 6575 6585
239. J. Bang, S.H. Kim, E. Drockenmuller, M.J. Misner, T.P. Russell, and C.J. Hawker Defect-free nanoporous thin films from ABC triblock copolymers J Am Chem Soc 128 2006 7622 7629
240. S.O. Kim, H.H. Solak, M.P. Stoykovich, N.J. Ferrier, J.J. Pablo, and P.F. Nealey Epitaxial self-assembly of block copolymers on lithographically defined nanopatterned substrates Nature 424 2003 411 414
241. E.W. Edwards, M.F. Montague, H.H. Solak, C.J. Hawker, and P.F. Nealey Precise control over molecular dimensions of block-copolymer domains using the interfacial energy of chemically nanopatterned substrates Adv Mater 16 2004 1315 1319
242. M.P. Stoykovich, M. Muller, S.O. Kim, H.H. Solak, E.W. Edwards, J.J. Pablo, and P.F. Nealey Directed assembly of block copolymer blends into nonregular device-oriented structures Science 308 2005 1442 1446
243. E.W. Edwards, M.P. Stoykovich, H.H. Solak, and P.F. Nealey Long-range order and orientation of cylinder-forming block copolymers on chemically nanopatterned striped surfaces Macromolecules 39 2006 3598 3607
244. M.P. Stoykovich, and P.F. Nealey Block copolymers and conventional lithography Mater Today 9 2006 20 29
245. L. Rockford, Y. Liu, P. Mansky, T.P. Russell, M. Yoon, and S.G.J. Mochrie Polymers on nanoperiodic, heterogeneous surfaces Phys Rev Lett 82 1999 2602 2605
246. L. Rockford, S.G.J. Mochrie, and T.P. Russell Propagation of nanopatterned substrate templated ordering of block copolymers in thick films Macromolecules 34 2001 1487 1492
247. S. Park, D.H. Lee, J. Xu, B. Kim, S.W. Hong, U. Jeong, T. Xu, and T.P. Russell Macroscopic 10-terabit-per-square-inch arrays from block copolymers with lateral order Science 323 2009 1030 1033
248. S.M. Park, G.S.W. Craig, Y.H. La, H.H. Solak, and P.F. Nealey Square arrays of vertical cylinders of PS-b-PMMA on chemically nanopatterned surfaces Macromolecules 40 2007 5084 5094
249. C. Tang, E.M. Lennon, G.H. Fredrickson, E.J. Kramer, and C.J. Hawker Evolution of block copolymer lithography to highly ordered square arrays Science 322 2008 429 432
250. T. Thurn-Albrecht, J. Schotter, G.A. Kästle, N. Emley, T. Shibauchi, L. Krusin-Elbaum, K. Guarini, C.T. Black, M.T. Tuominen, and T.P. Russell Ultrahigh-density nanowire arrays grown in self-assembled diblock copolymer templates Science 290 2000 2126 2129
251. 11 holes in 1 square centimeter Science 276 1997 1401 1404
252. K. Asakawa, and T. Hiraoka Nanopatterning with microdomains of block copolymers using reactive-ion etching selectivity Jpn J Appl Phys 41 2002 6112 6118
253. L. Chen, W.A. Phillip, E.L. Cussler, and M.A. Hillmyer Robust nanoporous membranes templated by a doubly reactive block copolymer J Am Chem Soc 129 2007 13786 13787
254. J. Rzayev, and M.A. Hillmyer Nanochannel array plastics with tailored surface chemistry J Am Chem Soc 127 2005 13373 13379
255. A.S. Zalusky, R. Olayo-Valles, J.H. Wolf, and M.A. Hillmyer Ordered nanoporous polymers from polystyrene-polylactide block copolymers J Am Chem Soc 124 2002 12761 12773
256. W.H. Tseng, C.K. Chen, Y.W. Chiang, R.M. Ho, S. Akasaka, and H. Hasegawa Helical nanocomposites from chiral block copolymer templates J Am Chem Soc 131 2009 1356 1357
257. R.M. Ho, C.K. Chen, and Y.W. Chiang Novel nanostructures from self-assembly of chiral block copolymers Macromol Rapid Commun 30 2009 1439 1456
258. S. Ndoni, M.E. Vigild, and R.H. Berg Nanoporous materials with spherical and gyroid cavities created by quantitative etching of polydimethylsiloxane in polystyrene-polydimethylsiloxane block copolymers J Am Chem Soc 125 2003 13366 13367
259. M. Park, P.M. Chaikin, R.A. Register, and D.H. Adamson Large area dense nanoscale patterning of arbitrary surfaces Appl Phys Lett 79 2001 257 259 (Pubitemid 33627597)
260. R.R. Li, P.D. Dapkus, M.E. Thompson, W.G. Jeong, C. Harrison, P.M. Chaikin, R.A. Register, and D.H. Adamson Dense arrays of ordered GaAs nanostructures by selective area growth on substrates patterned by block copolymer lithography Appl Phys Lett 76 2000 1689 1691
261. M. Haupt, S. Miller, R. Glass, M. Arnold, R. Sauer, K. Thonke, M. Möller, and J.P. Spatz Nanoporous gold films created using templates formed from self-assembled structures of inorganic-block copolymer miclles Adv Mater 15 2003 829 831
262. M. Haupt, S. Miller, A. Ladenburger, R. Sauer, K. Thonke, J.P. Spatz, S. Riethmüller, M. Möller, and F. Banhart Semiconductor nanostructures defined with self-organizing polymers J Appl Phys 91 2002 6057 6059
263. B. Koslowski, S. Strobel, T. Herzog, B. Heinz, H.G. Boyen, R. Notz, and P. Ziemann Fabrication of regularly arranged nanocolumns on diamond (1 0 0) using micellar masks J Appl Phys 87 2000 7533 7538
264. J.Y. Cheng, C.A. Ross, V.Z.-H. Chan, E.L. Thomas, R.G.H. Lammerink, and G.J. Vancso Formation of a cobalt magnetic dot array via block copolymer lithography Adv Mater 13 2001 1174 1178
265. R. Ruiz, H. Kang, F.A. Detcheverry, E. Dobisz, D.S. Kercher, T.R. Albrecht, J.J. Pablo, and P.F. Nealey Density multiplication and improved lithography by directed block copolymer assembly Science 321 2008 936 939
266. K. Naito, H. Hieda, M. Sakurai, Y. Kamata, and K. Asakawa 2.5-inch disk patterned media prepared by an artificially assisted self-assembling method IEEE Trans Magn 38 2002 1949 1951
267. S.B. Darling, and A. Hoffmann Tuning metal surface diffusion on diblock copolymer films J Vac Sci Technol A 25 2007 1048 1051
268. W.A. Lopes, and H.M. Jaeger Hierarchical self-assembly of metal nanostructures on diblock copolymer scaffolds Nature 414 2001 735 738
269. S.B. Darling, N.A. Yufa, A.L. Cisse, S.D. Bader, and S.J. Sibener Self-organization of FePt nanoparticles on photochemically modified diblock copolymer templates Adv Mater 17 2005 2446 2450
270. Y. Boontongkong, R.E. Cohen, and M.F. Rubner Selective electroless copper deposition within block copolymer microdomains Chem Mater 12 2000 1628 1633
271. R.W. Zehner, W.A. Lopes, T.L. Morkved, H. Jaeger, and L.R. Sita Selective decoration of a phase-separated diblock copolymer with thiol-passivated gold nanocrystals Langmuir 14 1998 241 244
272. S.B. Darling Mechanism for hierarchical self-assembly of nanoparticles on scaffolds derived from block copolymers Surf Sci 601 2007 2555 2561
273. S. Horiuchi, T. Fujita, T. Hayakawa, and Y. Nakao Three-dimensional nanoscale alignment of metal nanoparticles using block copolymer films as nanoreactors Langmuir 19 2003 2963 2973
274. A. Jo, W. Joo, W.H. Jin, H. Nam, and J.K. Kim Ultrahigh-density phase-change data storage without the use of heating Nat Nanotech 4 2009 727 731
275. M. Bal, A. Ursache, M.T. Tuominen, J.T. Goldbach, and T.P. Russell Nanofabrication of integrated magnetoelectronic devices using patterned self-assembled copolymer templates Appl Phys Lett 81 2002 3479 3481
276. J.I. Lee, S.H. Cho, S.M. Park, J.K. Kim, J.W. Yu, Y.C. Kim, and T.P. Russell Highly aligned ultrahigh density arrays of conducting polymer nanorods using block copolymer templates Nano Lett 8 2008 2315 2320
277. X. Li, S. Tian, Y. Ping, D.H. Kim, and W. Knoll One-step route to the fabrication of highly porous polyaniline nanofiber films by using PS-b-PVP diblock copolymers as templates Langmuir 21 2005 9393 9397
278. D.H. Lee, D.O. Shin, W.J. Lee, and S.O. Kim Hierarchically organized carbon nanotube arrays from self-assembled block copolymer nanotemplates Adv Mater 20 2008 2480 2485
279. D.H. Lee, W.J. Lee, and S.O. Kim Vertical single-walled carbon nanotube arrays via block copolymer lithography Chem Mater 21 2009 1368 1374
280. D.H. Lee, W.J. Lee, and S.O. Kim Highly efficient vertical growth of wall-number-selected, n-doped carbon nanotube arrays Nano Lett 9 2009 1427 1432
281. J.-M. Ha, M.A. Hillmyer, and M.D. Ward Thermotropic properties of organic nanocrystals embedded in ultrasmall crystallization chambers J Phys Chem B 109 2005 1392 1399
282. J.-M. Ha, J.H. Wolf, M.A. Hillmyer, and M.D. Ward Polymorph selectivity under nanoscopic confinement J Am Chem Soc 126 2004 3382 3383
283. B.J.S. Johnson, J.H. Wolf, A.S. Zalusky, and M.A. Hillmyer Template syntheses of polypyrrole nanowires and CdS nanoparticles in porous polymer monoliths Chem Mater 16 2004 2909 2917
284. E.J.W. Crossland, M. Nedelcu, C. Ducati, S. Ludwigs, M.A. Hillmyer, U. Steiner, and H.J. Snaith Block copolymer morphologies in dye-sensitized solar cells: probing the photovoltaic structure-function relation Nano Lett 9 2009 2813 2819
285. - d mesoporous silica and its tubelike carbon replica Angew Chem Int Ed 42 2003 3930 3934
286. Y. Deng, T. Yu, Y. Wan, Y. Shi, Y. Meng, D. Gu, L. Zhang, Y. Huang, C. Liu, X. Wu, and D. Zhao Ordered mesoporous silicas and carbons with large accessible pores templated from amphiphilic diblock copolymer poly(ethylene oxide)-b-polystyrene J Am Chem Soc 129 2007 1690 1697
287. S.-S. Kim, D.-K. Lee, J. Shah, and T.J. Pinnavaia Nanocasting of carbon nanotubes: in-situ graphitization of a low-cost mesostructured silica templated by non-ionic surfactant micelles Chem Commun 2003 1436 1437
288. T.-W. Kim, F. Kleitz, B. Paul, and R. Ryoo MCM-48-like large mesoporous silicas with tailored pore structure: facile synthesis domain in a ternary triblock copolymer-butanol-water system J Am Chem Soc 127 2005 7601 7610
289. F. Kleitz, S.H. Choi, and R. Ryoo Cubic Ia3d large mesoporous silica: synthesis and replication to platinum nanowires, carbon nanorods and carbon nanotubes Chem Commun 2003 2136 2137
290. H. Kosonen, S. Valkama, A. Nykänen, M. Toivanen, G. Brinke, J. Ruokolainen, and O. Ikkala Functional porous structures based on the pyrolysis of cured templates of block copolymer and phenolic resin Adv Mater 18 2006 201 205
291. J.W. Kriesel, M.S. Sander, and T.D. Tilley Block copolymer-assisted synthesis of mesoporous, multicomponent oxides by nonhydrolytic, thermolytic decomposition of molecular precursors in nonpolar media Chem Mater 13 2001 3554 3563
292. M. Kruk, M. Jaroniec, C.H. Ko, and R. Ryoo Characterization of the porous structure of SBA-15 Chem Mater 12 2000 1961 1968
293. C. Liang, K. Hong, G.A. Guiochon, J.W. Mays, and S. Dai Synthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers Angew Chem Int Ed 43 2004 5785 5789
294. X. Liu, B. Tian, C. Yu, F. Gao, S. Xie, B. Tu, R. Che, L.-M. Peng, and D. Zhao Room-temperature synthesis in acidic media of large-pore three-dimensional bicontinuous mesoporous silica with Ia3d symmetry Angew Chem Int Ed 41 2002 3876 3878
295. N.A. Melosh, P. Davidson, and B.F. Chmelka Monolithic mesophase silica with large ordering domains J Am Chem Soc 122 2000 823 829
296. Y. Meng, D. Gu, F. Zhang, Y. Shi, L. Cheng, D. Feng, Z. Wu, Z. Chen, Y. Wan, A. Stein, and D. Zhao A family of highly ordered mesoporous polymer resin and carbon structures from organic-organic self-assembly Chem Mater 18 2006 4447 4464
297. Y. Meng, D. Gu, F. Zhang, Y. Shi, H. Yang, Z. Li, C. Yu, B. Tu, and D. Zhao Ordered mesoporous polymers and homologous carbon frameworks: amphiphilic surfactant templating and direct transformation Angew Chem Int Ed 44 2005 7053 7059
298. A.T. Rodriguez, M. Chen, Z. Chen, C.J. Brinker, and H. Fan Nanoporous carbon nanotubes synthesized through confined hydrogen-bonding self-assembly J Am Chem Soc 128 2006 9276 9277
299. M. Stefik, S. Mahajan, H. Sai, T.H. Epps, F.S. Bates, S.M. Gruner, O.F.J. DiSalvo, and U. Wiesner Ordered three- and five-ply nanocomposites from ABC block terpolymer microphase separation with niobia and aluminosilicate sols Chem Mater 21 2009 5466 5473
300. S. Tanaka, N. Nishiyama, Y. Egashira, and K. Ueyama Synthesis of ordered mesoporous carbons with channel structure from an organic-organic nanocomposite Chem Commun 2005 2125 2127
301. G.E.S. Toombes, O.S. Mahajan, M. Weyland, A. Jain, P. Du, M. Kamperman, S.M. Gruner, D.A. Muller, and U. Wiesner Self-assembly of four-layer woodpile structure from zigzag ABC copolymer/aluminosilicate concertinas Macromolecules 41 2008 852 859
302. G.E.S. Toombes, S. Mahajan, M. Thomas, P. Du, M.W. Tate, S.M. Gruner, and U. Wiesner Hexagonally patterned lamellar morphology in ABC triblock copolymer/aluminosilicate nanocomposites Chem Mater 20 2008 3278 3287
303. C.-M. Yang, B. Zibrowius, W. Schmidt, and F. Schüth Consecutive generation of mesopores and micropores in SBA-15 Chem Mater 15 2003 3739 3741
304. S. Yang, P.A. Mirau, C.-S. Pai, O. Nalamasu, E. Reichmanis, J.C. Pai, Y.S. Obeng, J. Seputro, E.K. Lin, H.-J. Lee, J. Sun, and D.W. Gidley Nanoporous ultralow dielectric constant organosilicates templated by triblock copolymers Chem Mater 14 2002 369 374
305. F. Zhang, Y. Meng, D. Gu, Y. Yan, Z. Chen, B. Tu, and D. Zhao An aqueous cooperative assembly route to synthesize ordered mesoporous carbons with controlled structures and morphology Chem Mater 18 2006 5279 5288
306. F. Zhang, Y. Meng, D. Gu, Y. Yan, C. Yu, B. Tu, and D. Zhao A facile aqueous route to synthesize highly ordered mesoporous polymers and carbon frameworks with Ia3hd bicontinuous cubic structure J Am Chem Soc 127 2005 13508 13509
307. A.C. Edrington, A.M. Urbas, P. DeRege, C.X. Chen, T.M. Swager, N. Hadjichristidis, M. Xenidou, L.J. Fetters, J.D. Joannopoulos, and Y. Fink Polymer-based photonic crystals Adv Mater 13 2001 421 425
308. Y. Fink, A.M. Urbas, M.G. Bawendi, J.D. Joannopoulos, and E.L. Thomas Block copolymers as photonic bandgap materials J Lightwave Technol 17 1999 1963 1969
309. M. Bockstaller, R. Kolb, and E.L. Thomas Metallodielectric photonic crystals based on diblock copolymers Adv Mater 13 2001 1783 1786
310. A.M. Urbas, R. Sharp, Y. Fink, E.L. Thomas, M. Xenidou, and L.J. Fetters Tunable block copolymer/homopolymer photonic crystals Adv Mater 12 2000 812 814
311. S. Valkama, H. Kosonen, J. Ruokolainen, T. Haatainen, M. Torkkeli, R. Serimaa, G Ten Brinke, and O. Ikkala Self-assembled polymeric solid films with temperature-induced large and reversible photonic-bandgap switching Nat Mater 3 2004 872 876
312. A.M. Urbas, M. Maldovan, P. DeRege, and E.L. Thomas Bicontinuous cubic block copolymer photonic crystals Adv Mater 14 2002 1850 1853
313. C. Osuji, C.-Y. Chao, I. Bita, C.K. Ober, and E.L. Thomas Temperature-dependent photonic bandgap in a self-assembled hydrogen-bonded liquid-crystalline diblock copolymer Adv Funct Mater 12 2002 753 758
314. Y. Kang, J.J. Walish, T. Gorishnyy, and E.L. Thomas Broad-wavelength- range chemically tunable block-copolymer photonic gels Nat Mater 6 2007 957 960
315. J.S. Lee, A. Hirao, and S. Nakahama Polymerization of monomers containing functional silyl groups. 7. Porous membranes with controlled microstructures Macromolecules 22 1989 2602 2606
316. G. Liu, J. Ding, A. Guo, M. Herfort, and D. Bazett-Jones Potential skin layers for membranes with tunable nanochannels Macromolecules 30 1997 1851 1853
317. W.A. Phillip, J. Rzayev, M.A. Hillmyer, and E.L. Cussler Gas and water liquid transport through nanoporous block copolymer membranes J Membr Sci 286 2006 144 152
318. S.Y. Yang, I. Ryu, H.Y. Kim, J.K. Kim, S.K. Jang, and T.P. Russell Nanoporous membranes with ultrahigh selectivity and flux for the filtration of viruses Adv Mater 18 2006 709 712
319. S.Y. Yang, J. Park, J. Yoon, M. Ree, S.K. Jang, and J.K. Kim Virus filtration membranes prepared from nanoporous block copolymers with good dimensional stability under high pressures and excellent solvent resistance Adv Funct Mater 18 2008 1371 1377
320. K.V. Peinemann, V. Abetz, and P.F.W. Simon Asymmetric superstructure formed in a block copolymer via phase separation Nat Mater 6 2007 992 996
321. D.A. Bernards, and T.A. Desai Nanoscale porosity in polymer films: fabrication and therapeutic applications Soft Matter 6 2010 1621 1631
322. J. Yoon, S.Y. Yang, B. Lee, W. Joo, K. Heo, J.K. Kim, and M. Ree Nondestructive quantitative synchrotron grazing incidence X-ray scattering analysis of cylindrical nanostructures in supported thin films J Appl Crystallogr 40 2007 305 312 (Pubitemid 46439130)
323. S.Y. Yang, J.-A. Yang, E.-S. Kim, G. Jeon, E.J. Oh, K.Y. Choi, S.K. Hahn, and J.K. Kim Single file diffusion of protein drugs through cylindrical nanochannels ACS Nano 4 2010 3817 3822
324. V. Kukla, J. Kornatowski, D. Demuth, I. Girnus, H. Pfeifer, and L.V.C. Rees NMR studies of single-file diffusion in unidimensional channel zeolites Science 272 1996 702 704
325. Q.-H. Wei, C. Bechinger, and P. Leiderer Single-file diffusion of colloids in one-dimensional channels Science 287 2000 625 627
326. W. Joo, M.S. Park, and J.K. Kim Block copolymer film with sponge-like nanoporous strucutre for antireflection coating Langmuir 22 2006 7960 7963
327. W. Joo, H.J. Kim, and J.K. Kim Broadband antireflection coating covering from visible to near infra-red wavelengths by using multilayered nanoporous block copolymer films Langmuir 26 2010 5110 5114