Polymorph Selectivity under Nanoscopic Confinement

Journal of the American Chemical Society

Volumn 126, Issue 11, 2004, Pages 3382-3383

  Ha, Jeong Myeong ^a   Wolf, Johanna H ^a   Hillmyer, Marc A ^a   Ward, Michael D ^a  

^a University of Minnesota   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANTHRANILIC ACID DERIVATIVE;

ARTICLE; CLINICAL OBSERVATION; CRYSTAL STRUCTURE; CRYSTALLIZATION; METAL BINDING; NANOTECHNOLOGY; PARTICLE SIZE; RELIABILITY; SCANNING ELECTRON MICROSCOPY; SOLID STATE; STRUCTURE ANALYSIS;

EID: 1642306501     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja049724r     Document Type: Article

References (25)

1. Oxtoby, D. W. Acc. Chem. Res. 1998, 31, 91.
2. Bernstein, J. Polymorphism in Molecular Crystals; Oxford: New York, 2002.
3. Polymorphism in Pharmaceutical Solids; Brittain, J. G., Ed.; Marcell Dekker: New York, 1999.
4. Mitchell, C.; Yu, L.; Ward, M. D. J. Am. Chem. Soc. 2001, 123, 10830.
5. Weissbuch, I.; Lahav, M.; Leiserowitz, L. Cryst. Growth Des. 2003, 3, 125.
6. Levi, Y.; Albeck, S.; Brack, A.; Weiner, S.; Addadi, L. Chem. Eur. J. 1998, 4, 389.
7. Frostman, L. M.; Bader, M. M.; Ward; M. D. Langmuir 1994, 10, 576.
8. Aizenberg, J.; Black, A. J.; Whitesides, G. M. J. Am. Chem. Soc. 1999, 121, 4500.
9. Unruh, K. M.; Huber, T. E.; Huber, C. A. Phys. Rev. B 1993, 48, 9021.
10. Scherer, G. W. Cem. Concr. Res. 1999, 29, 1347.
11. Jackson, C. L.; McKenna, G. B. Chem. Mater. 1996, 8, 2128.
12. Haller, W. Nature 1965, 206, 693. CPG was obtained from CPG, Inc., Lincoln Park, New Jersey.
13. Wolf, J. H.; Hillmyer, M. A., Langmuir 2003, 19, 6553.
14. For related work on polystyrene monoliths, see: Zalusky, A. S.; Olayo-Valles, R.; Wolf, J. H.; Hillmyer, M. A. J. Am. Chem. Soc. 2002, 124, 12761.
15. I: Brown, C. J.; Ehrenberg, M. Acta Crystallogr. 1985, C41, 441. II: Boone, C. G. G.; Derissen, J. L.; Schoone, J. C. Acta Crystallogr. 1977, B33, 3205. III: Takazawa, H.; Ohba, S.; Saito, Y. Acta Crystallogr. 1986, C42, 1880.
16. I: Brown, C. J.; Ehrenberg, M. Acta Crystallogr. 1985, C41, 441. II: Boone, C. G. G.; Derissen, J. L.; Schoone, J. C. Acta Crystallogr. 1977, B33, 3205. III: Takazawa, H.; Ohba, S.; Saito, Y. Acta Crystallogr. 1986, C42, 1880.
17. I: Brown, C. J.; Ehrenberg, M. Acta Crystallogr. 1985, C41, 441. II: Boone, C. G. G.; Derissen, J. L.; Schoone, J. C. Acta Crystallogr. 1977, B33, 3205. III: Takazawa, H.; Ohba, S.; Saito, Y. Acta Crystallogr. 1986, C42, 1880.
18. Ojala, W. H.; Etter, M. C. J. Am. Chem. Soc. 1992, 114, 10288.
19. Carter, P. W.; Ward, M. D. J. Am. Chem. Soc. 1994, 116, 769.
20. m(7.5 nm) = 114 °C (form II).
21. Yu, L.; Stephenson, G. A.; Mitchell, C. A.; Bunnell, C. A.; Snorek, S. V.; Bowyer, J. J.; Borchardt, T. B.; Stowell, J. G.; Byrn, S. R. J. Am. Chem. Soc. 2000, 122, 585. Y is the most stable form below 70 °C, ON is the most stable above 70 °C.
22. Form Y crystallized readily during evaporation of solvent from 1-mm diameter capillaries. See: Hilden, J. L.; Reyes, C. E.; Kelm, M. J.; Tan, J. S. ; Stowell, J. G.; Morris, K. R. Cryst. Growth Des. 2003, 3, 921.
23. m(bulk) = 109 °C.
24. The onset of the glass transition of PCHE is ∼132 °C. Above this temperature the pores will collapse.
25. Lang, M.; Grzesiak, A. L.; Matzger, A. J. J. Am. Chem. Soc. 2002, 124, 14834.