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One should note that a saturation of the Si(LVM) signal is not observed, even if the shell reaches a maximum of 50 nm at the base of the nanowire. There are mainly two reasons that account for this: (1) The Raman measurements are realized between the two contacts, which means that we cannot measure at the exact base of the nanowire (where the shell would be 50 nm), but always at a distance of at least 2 microns. (2) The probe depth is defined as the distance d at which the light intensity is reduced a factore with respect to the incident intensity. This means that the light intensity is strongly reduced but still some scattering is expected at a depth of 50 nm.
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