The "somersault" mechanism for the p-450 hydroxylation of hydrocarbons. The intervention of transient inverted metastable hydroperoxides

Journal of the American Chemical Society

Volumn 128, Issue 5, 2006, Pages 1474-1488

  Bach, Robert D ^a   Dmitrenko, Olga ^a  

^a UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; ENZYMES; HYDROCARBONS; HYDROGEN BONDS; ISOMERS; OXIDATION; OXYGEN;

ENZYMATIC CYTOCHROMES; HYDROPEROXIDES; ISOBUTANE OXIDATION; ISOMERIC FERRYL OXYGEN;

HYDROXYLATION;

CYTOCHROME P450; HYDROCARBON; HYDROPEROXIDE; HYDROXYL RADICAL; METAL OXIDE; TERT BUTYL ALCOHOL;

ARTICLE; CALCULATION; COMPLEX FORMATION; ENZYME MECHANISM; HYDROGEN BOND; HYDROXYLATION; MODEL; OXIDATION; OXIDATION REDUCTION REACTION;

BUTANES; CYTOCHROME P-450 ENZYME SYSTEM; FERRIC COMPOUNDS; HYDROCARBONS; HYDROGEN BONDING; HYDROGEN PEROXIDE; HYDROXYLATION; METALLOPORPHYRINS; METHANE; MODELS, MOLECULAR; THERMODYNAMICS;

EID: 32244443818     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja052111+     Document Type: Article

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