Neutral versus charged species in enzyme catalysis. Classical and free energy barriers for oxygen atom transfer from C4a-hydroperoxyflavin to dimethyl sulfide

Journal of Organic Chemistry

Volumn 67, Issue 24, 2002, Pages 8653-8661

  Canepa, Carlo ^a   Bach, Robert D ^b   Dmitrenko, Olga ^b  

^a UNIVERSITY OF TURIN   (Italy)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; FREE ENERGY; HYDROGEN BONDS; OXIDATION; OXYGEN; POTENTIAL ENERGY;

NUCLEOPHILES;

ENZYMES;

C4A HYDROPEROXYFLAVIN; DIMETHYL SULFIDE; FORMIC ACID; HYDROPEROXIDE DERIVATIVE; UNCLASSIFIED DRUG; DIMETHYL SULFOXIDE; ENZYME; OXYGEN; PROTON; RIBOFLAVIN DERIVATIVE;

ARTICLE; CALCULATION; CHEMICAL STRUCTURE; ENERGY; ENZYME DEGRADATION; HYDROGEN BOND; OXIDATION; OXYGEN TRANSPORT; CATALYSIS; CHEMISTRY; COMPARATIVE STUDY; CONFORMATION; METABOLISM; OXIDATION REDUCTION REACTION; THEORETICAL MODEL;

CATALYSIS; DIMETHYL SULFOXIDE; ENZYMES; FLAVINS; HYDROGEN BONDING; MODELS, THEORETICAL; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; OXYGEN; PROTONS;

EID: 0037195664     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo0261597     Document Type: Article

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