Alkenes as alkyne equivalents in radical cascades terminated by fragmentations: Overcoming stereoelectronic restrictions on ring expansions for the preparation of expanded polyaromatics

Journal of the American Chemical Society

Volumn 137, Issue 19, 2015, Pages 6335-6349

  Mohamed, Rana K ^a   Mondal, Sayantan ^a   Gold, Brian ^a   Evoniuk, Christopher J ^a   Banerjee, Tanmay ^a   Hanson, Kenneth ^a   Alabugin, Igor V ^a  

^a FLORIDA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; CHEMICAL BONDS; CYCLIZATION; NAPHTHALENE; TIN;

CASCADE TRANSFORMATIONS; CHEMOSELECTIVE; HYDROGEN ATOM ABSTRACTION; RADICAL CHEMISTRY; REGIO-SELECTIVE; STEREOELECTRONIC EFFECT; SYNTHETIC EQUIVALENTS; THROUGH-BOND INTERACTIONS;

HYDROCARBONS;

ALKENE DERIVATIVE; ALKYNE DERIVATIVE; HYDROGEN;

AROMATIZATION; ARTICLE; CHEMICAL BOND; CONTROLLED STUDY; CYCLIZATION; FRAGMENTATION REACTION; MOLECULAR INTERACTION; REACTION OPTIMIZATION; RING OPENING; STEREOCHEMISTRY;

EID: 84930225180     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b02373     Document Type: Article

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