Alkynyl crown ethers as a scaffold for hyperconjugative assistance in noncatalyzed azide-alkyne click reactions: Ion sensing through enhanced transition-state stabilization

Journal of Organic Chemistry

Volumn 79, Issue 13, 2014, Pages 6221-6232

  Gold, Brian ^a   Batsomboon, Paratchata ^a   Dudley, Gregory B ^a   Alabugin, Igor V ^a  

^a FLORIDA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALIGNMENT; CROWN ETHERS; CYCLOADDITION; LIGANDS; SCAFFOLDS;

CLICK REACTION; CYCLOADDITIONS; HYPERCONJUGATIVE INTERACTIONS; OPTIMAL ALIGNMENTS; OPTIMAL ARRANGEMENT; POSITIVELY CHARGED IONS; PREORGANIZATION; TRANSITION-STATE;

STABILIZATION;

ALKYNE; ALKYNYL CROWN ETHER; AZIDE; COBALT COMPLEX; CROWN ETHER; UNCLASSIFIED DRUG;

ACCELERATION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CHEMICAL BOND; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; CLICK CHEMISTRY; CONFORMATION; CYCLOADDITION; HYPERCONJUGATIVE ASSISTANCE; KINETICS; LINEAR SYSTEM; PREDICTION; PROTON NUCLEAR MAGNETIC RESONANCE; SOLVATION; SYNTHESIS; TRANSITION STATE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM;

ALKYNES; AZIDES; CROWN ETHERS; CYCLOADDITION REACTION; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 84903713719     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo500958n     Document Type: Article

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