Origins of stereoselectivity in intramolecular aldol reactions catalyzed by cinchona amines

Journal of the American Chemical Society

Volumn 137, Issue 5, 2015, Pages 2116-2127

  Lam, Yu Hong ^a   Houk, K N ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CONDENSATION REACTIONS; DISPERSIONS; HYDROGEN; HYDROGEN BONDS; KETONES; STEREOSELECTIVITY;

ALDOL CONDENSATION; CONFORMATIONAL PREFERENCES; DISPERSION CORRECTION; DISPERSION EFFECT; DISPERSION-CORRECTED DENSITY FUNCTIONAL; ENAMINE INTERMEDIATES; INTRAMOLECULAR ALDOL REACTIONS; TRANSITION STRUCTURES;

DENSITY FUNCTIONAL THEORY;

2 CYCLOHEXENONE; AMINE; CINCHONA ALKALOID; CINCHONA AMINE; CYCLOOCTANE; ENAMINE; HEPTANE DERIVATIVE; UNCLASSIFIED DRUG; KETONE;

ALDOL REACTION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHIRALITY; CINCHONA; CONFORMATION; CONTROLLED STUDY; CYCLIZATION; DENSITY FUNCTIONAL THEORY; DISPERSION; ENANTIOSELECTIVITY; ENERGY TRANSFER; GEOMETRY; HYDROGEN BOND; HYDROLYSIS; MEASUREMENT ACCURACY; PARTITION COEFFICIENT; PROTON TRANSPORT; STEREOCHEMISTRY; STEREOISOMERISM; CHEMISTRY;

AMINES; CATALYSIS; CINCHONA ALKALOIDS; CYCLIZATION; KETONES; MODELS, MOLECULAR; MOLECULAR CONFORMATION; STEREOISOMERISM;

EID: 84922770554     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja513096x     Document Type: Article

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