Insights into the dual activation mechanism involving bifunctional cinchona alkaloid thiourea organocatalysts: An NMR and DFT study

Journal of Organic Chemistry

Volumn 77, Issue 21, 2012, Pages 9813-9825

  Zhu, Jun Ling ^a   Zhang, Yong ^a   Liu, Chong ^a   Zheng, An Min ^b   Wang, Wei ^a  

^a LANZHOU UNIVERSITY   (China)

^b INSTITUTE OF GEOLOGY AND GEOPHYSICS   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY E; ACTIVATION MECHANISMS; BIFUNCTIONAL; C-C BOND FORMATION; CATALYTIC SYSTEM; CHALCONES; CINCHONA ALKALOID; DFT CALCULATION; DFT STUDY; DIASTEREO-SELECTIVITY; DUAL ACTIVATION; FIRST-ORDER; IN-DEPTH UNDERSTANDING; KEY FEATURE; KINETIC STUDY; MECHANISTIC STUDIES; MICHAEL ADDITIONS; MICHAEL REACTIONS; NITROMETHANE; NMR MEASUREMENTS; ORGANOCATALYSIS; ORGANOCATALYSTS; PROTONATED AMINE; RATE DETERMINING STEP; VARIABLE-TEMPERATURE NMR;

ACTIVATION ENERGY; ADDITION REACTIONS; CATALYSIS; CATALYSTS; DENSITY FUNCTIONAL THEORY; METABOLITES; NITROGEN COMPOUNDS; RATE CONSTANTS; REACTION KINETICS; STEREOSELECTIVITY;

THIOUREAS;

2 PYRROLIDINONE; CHALCONE; CINCHONA ALKALOID; THIOUREA;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; MICHAEL ADDITION; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; STEREOCHEMISTRY; SYNTHESIS;

EID: 84868368375     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo302133n     Document Type: Article

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