DFT study of the mechanism and origin of enantioselectivity in chiral BINOL-phosphoric acid catalyzed transfer hydrogenation of ketimine and α-imino ester using benzothiazoline

Journal of Organic Chemistry

Volumn 78, Issue 8, 2013, Pages 3731-3736

  Shibata, Yukihiro ^a   Yamanaka, Masahiro ^a  

^a RIKKYO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC INDUCTION; ASYMMETRIC TRANSFER HYDROGENATION; CYCLIC TRANSITIONS; ENANTIOSELECTIVE; HIGH ENANTIOSELECTIVITY; REACTION MECHANISM; STERIC INTERACTIONS; TRANSFER HYDROGENATIONS;

CATALYSIS; ESTERIFICATION; ESTERS; HYDROGENATION; PHOSPHORIC ACID; SUBSTITUTION REACTIONS;

ENANTIOSELECTIVITY;

2,2' DIHYDROXY 1,1' BINAPHTHYL; ALPHA IMINO ESTER; AMINE; BENZOTHIAZOLINE DERIVATIVE; ESTER DERIVATIVE; HANTZSCH ESTER; IMINE; KETIMINE DERIVATIVE; PHOSPHORIC ACID; REDUCING AGENT; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CATALYSIS; CATALYST; CHEMICAL INTERACTION; CHEMICAL MODEL; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; HYDROGENATION; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS;

BENZOTHIAZOLES; BIPHENYL COMPOUNDS; CATALYSIS; HYDROGENATION; IMINES; MODELS, MOLECULAR; MOLECULAR STRUCTURE; NITRILES; OXIDATION-REDUCTION; PHOSPHORIC ACIDS; QUANTUM THEORY; STEREOISOMERISM;

EID: 84876534322     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo4002195     Document Type: Article

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