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Volumn , Issue 10, 2013, Pages 1950-1962

Regio- and stereoselective olefination of phenol carbamates through C-H bond functionalization

Author keywords

C H activation; Olefination; Protecting groups; Rhodium; Ruthenium

Indexed keywords


EID: 84875418847     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.201201574     Document Type: Article
Times cited : (60)

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    • For details of the optimization studies, see the Supporting Information.
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    • o-Br and o-I carbamates provide dehalogenated complexes of the mixture of mono- (3q-a) and diolefinated (3q-b) products.
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    • At this stage we cannot identify the rate-determining step, because - if the coordination of the carbamoyl group occurs irreversibly - no significant H/D KIE is expected, even if the following C-H activation is rate-limiting. For a related excellent highlight, see:, Angew. Chem. Int. Ed. 2012, 51, 3066 -3072.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.