Transition-state stabilization by a secondary substrate-ligand interaction: A new design principle for highly efficient transition-metal catalysis

Chemistry - A European Journal

Volumn 16, Issue 8, 2010, Pages 2470-2478

  Šmejkal, Tomáš ^a   Gribkov, Denis ^a   Geier, Jens ^a   Keller, Manfred ^a   Breit, Bernhard ^a  

^a UNIVERSITY OF FREIBURG   (Germany)

Author keywords

Enzyme mimics; Guanidine; Homogeneous catalysis, hydroformylation; Molecular recognition

Indexed keywords

CATALYTIC SYSTEM; ENZYME MIMICS; GUANIDINE; GUANIDINIUM; HOMOGENEOUS CATALYSIS; LIGAND INTERACTIONS; MECHANISTIC STUDIES; METAL CATALYSIS; METHYL ESTERS; MONODENTATES; NEW DESIGN; PHOSPHANE LIGANDS; REACTION SITES; REGIO-SELECTIVE; STRUCTURE ACTIVITY RELATIONSHIPS; SUBSTRATE SELECTIVITY; TERMINAL ALKENES; TRANSITION-STATE; UNSATURATED CARBOXYLIC ACIDS;

CARBOXYLATION; CARBOXYLIC ACIDS; CATALYSIS; CATALYST ACTIVITY; ENZYMES; ESTERS; HYDROFORMYLATION; HYDROXYLATION; LIGANDS; MOLECULAR BIOLOGY; MOLECULAR RECOGNITION; OLEFINS; ORGANIC ACIDS; REACTION KINETICS; REGIOSELECTIVITY; STABILIZATION; SULFUR COMPOUNDS; TRANSITION METALS;

CATALYST SELECTIVITY;

ALKENE; LIGAND; ORGANOPHOSPHORUS COMPOUND; TRANSITION ELEMENT;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; STRUCTURE ACTIVITY RELATION;

ALKENES; CATALYSIS; LIGANDS; MOLECULAR STRUCTURE; ORGANOPHOSPHORUS COMPOUNDS; STEREOISOMERISM; STRUCTURE-ACTIVITY RELATIONSHIP; TRANSITION ELEMENTS;

EID: 77049099141     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902553     Document Type: Article

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